Abstract
Ion doping is the effective strategy for enhancing the multiferroic performance of BiFeO3 (BFO) ceramics. In this work, the preparation of Bi1−xSrxFe1−yCoyO3 (0 ≤ x ≤ 0.05, 0 ≤ y ≤ 0.05) powders was successfully carried out by self-propagating combustion technology. The Sr, Co as the dopants exhibited significant effect on the microstructure and multiferroic performance of BFO ceramic. The substitution of Sr, Co ions for A and B sites suppressed the grain growth and reduced the leakage current. The leakage current of BSFO was two orders of magnitude smaller than pure BFO. The large 2Pr (4.470 μC/cm2), Ec (24.36 kV/cm), and Ms (5.330 emu/g) for Bi1−xSrxFe1−yCoyO3 samples were obtained, revealing superior multiferroic and magnetic properties.
Similar content being viewed by others
References
Spaldin, N.A., Ramesh, R.: Advances in magnetoelectric multiferroics. Nat. Mater. 18, 203–212 (2019)
Bibes, M., Barthélémy, A.: Towards a magnetoelectric memory. Nat. Mater. 7, 425–426 (2008)
Lisnevskaya, I.V., Myagkaya, K.V., Butova, V.V., Shapovalov, V.V., Rusalev, Y.V., Zahran, H.Y., Yahia, I.S., Soldatov, A.V.: Preferences of the end members of the lanthanide series for A and B sites in BiFeO3. Ceram. Int. 46, 6333–6341 (2020)
Chauhan, S., Kumar, M., Yousuf, A., Rathi, P., Sahni, M., Singh, S.: Effect of Na/Co co-substituted on structural, magnetic, optical and photocatalytic properties of BiFeO3 nanoparticles. Mater. Chem. Phys. 263, 124402 (2021)
Li, J., Yan, D.Z.: Low-temperature synthesis of pure BiFeO3 phase and variation in its morphology with temperature. Ceram. Int. 44, 18271–18278 (2018)
Rong, Q.Y., Xiao, W.Z., Cheng, C.P., Wang, L.L.: Magnetism and ferroelectricity in BiFeO3 doped with Ga at Fe sites. J. Alloy. Compd. 797, 117–121 (2019)
Das, S., Rana, S., Mursalin, S.M., Rana, P., Sen, A.: Sonochemically prepared nanosized BiFeO3 as novel SO2 sensor. Sens. Actuators B Chem. 218, 122–127 (2015)
Scott, J.F.: Applications of magnetoelectrics. J. Mater. Chem. 22, 4567–4574 (2012)
Chowdhury, S.S., Kamal, A.H.M., Hossain, R., Hasan, M., Islam, M.F., Ahmmad, B., Basith, M.A.: Dy doped BiFeO3: a bulk ceramic with improved multiferroic properties compared to nano counterparts. Ceram. Int. 43, 9191–9199 (2017)
Bai, X., Bugnet, M., Frontera, C., Gemeiner, P., Guillot, J., Lenoble, D., Infante, I.C.: Crystal growth mechanisms of BiFeO3 nanoparticles. Inorg. Chem. 58, 11364–11371 (2019)
Suresh, P., Srinath, S.: Effect of synthesis route on the multiferroic properties of BiFeO3: a comparative study between solid state and sol–gel methods. J. Alloy. Compd. 649, 843–850 (2015)
Castro, A., Martins, M.A., Ferreira, L.P., Godinho, M., Vilarinho, P.M., Ferreira, P.: Multifunctional nanopatterned porous bismuth ferrite thin films. J. Mater. Chem. C 7, 7788–7797 (2019)
Castillo, M.E., Shvartsman, V.V., Gobeljic, D., Gao, Y., Landers, J., Wende, H., Lupascu, D.C.: Effect of particle size on ferroelectric and magnetic properties of BiFeO3 nanopowders. Nanotechnology 24, 355701 (2013)
Park, T.J., Papaefthymiou, G.C., Viescas, A.J., Moodenbaugh, A.R., Wong, S.S.: Size-dependent magnetic properties of single-crystalline multiferroic BiFeO3 nanoparticles. Nano Lett. 7, 766–772 (2007)
Sando, D., Barthélémy, A., Bibes, M.: BiFeO3 epitaxial thin films and devices: past, present and future. J. Phys. Condens. Matter 26, 473201 (2014)
Nan, C.W., Bichurin, M.I., Dong, S., Viehland, D., Srinivasan, G.: Multiferroic magnetoelectric composites: historical perspective, status, and future directions. J. Appl. Phys. 103, 031101 (2008)
Wang, Y., Nan, C.W.: Enhanced ferroelectricity in Ti-doped multiferroic BiFeO3 thin films. Appl. Phys. Lett. 89, 052903 (2006)
Wen, Z., Hu, G., Fan, S., Yang, C., Wu, W., Zhou, Y., Chen, X., Cui, S.: Effects of annealing process and Mn substitution on structure and ferroelectric properties of BiFeO3 films. Thin Solid Films 517, 4497–4501 (2009)
Kumar, A., Singh, P., Choudhary, R.J., Pandey, D.: Effect of Mn-doping on the low temperature magnetic phase transitions of BiFeO3. J. Alloy. Compd. 825, 154148 (2020)
Karpinsky, D.V., Troyanchuk, I.O., Bushinsky, M.V., Gavrilov, S.A., Silibin, M.V., Franz, A.: Crystal structure and magnetic properties of Bi1−xCaxFe1−xMn(Ti)xO3 ceramics across the phase boundary. J. Mater. Sci. 51, 10506–10514 (2016)
Lin, F., Yu, Q., Deng, L., Zhang, Z., He, X., Liu, A., Shi, W.: Effect of La/Cr codoping on structural transformation, leakage, dielectric and magnetic properties of BiFeO3 ceramics. J. Mater. Sci. 52, 7118–7129 (2017)
Yang, R., Sun, H., Li, J., Li, Y.A.: Structural, magnetic and photocatalytic properties of Sr2+ doped BiFeO3 nanofibres fabricated by electrospinning. Ceram. Int. 44, 14032–14035 (2018)
Zhang, Q., Zhu, X., Xu, Y., Gao, H., Xiao, Y., Liang, D., Zhu, J., Zhu, J., Xiao, D.: Effect of La3+ substitution on the phase transitions, microstructure and electrical properties of Bi1−xLaxFeO3 ceramics. J. Alloy. Compd. 546, 57–62 (2013)
Yuan, X., Shi, L., Zhao, J., Zhou, S., Li, Y., Xie, C., Guo, J.: Sr and Pb co-doping effect on the crystal structure, dielectric and magnetic properties of BiFeO3 multiferroic compounds. J. Alloy. Compd. 708, 93–98 (2017)
Khajonrit, J., Wongpratat, U., Kidkhunthod, P., Pinitsoontorn, S., Maensiri, S.: Effects of Co doping on magnetic and electrochemical properties of BiFeO3 nanoparticles. J. Magn. Magn. Mater. 449, 423–434 (2018)
Wani, W.A., Kundu, S., Ramaswamy, K., Venkataraman, H.: Structural, morphological, optical and dielectric investigations in cobalt doped bismuth ferrite nanoceramics prepared using the sol-gel citrate precursor method. J. Alloy. Compd. 846, 156334 (2020)
Puhan, A., Bhushan, B., Satpathy, S., Meena, S.S., Nayak, A.K., Rout, D.: Facile single phase synthesis of Sr, Co co-doped BiFeO3 nanoparticles for boosting photocatalytic and magnetic properties. Appl. Surf. Sci. 493, 593–604 (2019)
Hasan, M., Hakim, M.A., Basith, M.A., Hossain, M.S., Ahmmad, B., Zubair, M.A., Hussain, A., Islam, M.F.: Size dependent magnetic and electrical properties of Ba-doped nanocrystalline BiFeO3. AIP Adv. 6, 035314 (2016)
Dhir, G., Uniyal, P., Verma, N.K.: Multiferroic properties of Sr-doped BiFeO3 nanoparticles. Physica B 531, 51–57 (2018)
Srihari N.V., Vinayakumar, K.B., Nagaraja, K.K.: Magnetoelectric coupling in bismuth ferrite—challenges and perspectives. Coatings 10, 1221–1240 (2020)
Zhang, Y., Qi, J., Wang, Y., Tian, Y., Zhang, J., Hu, T., Wei, M., Liu, Y., Yang, J.: Tuning magnetic properties of BiFeO3 thin films by controlling Mn doping concentration. Ceram. Int. 44, 6054–6061 (2018)
Liu, S., Luo, H., Yan, S., Yao, L., He, J., Li, Y., He, L., Huang, S., Deng, L.: Effect of Nd-doping on structure and microwave electromagnetic properties of BiFeO3. J. Magn. Magn. Mater. 426, 267–272 (2017)
Mao, W., Chen, W., Wang, X., Zhu, Y., Ma, Y., Xue, H., Chu, L., Yang, J., Li, X.A., Huang, W.: Influence of Eu and Sr co-substitution on multiferroic properties of BiFeO3. Ceram. Int. 42,12838–12842 (2016)
Kar, B.S., Goswami, M.N., Jana, P.C.: Effects of lanthanum dopants on dielectric and multiferroic properties of BiFeO3–BaTiO3 ceramics. J. Alloy. Compd. 861, 157960 (2021)
Samantray, N.P., Choudhary, R.N.P.: Studies of structural, dielectric and impedance spectroscopy of Ca/Zr modified BiFeO3 ceramics. Mater. Chem. Phys. 260, 124115 (2021)
Anwar, A., Yousuf, M.A., Zulfiqar, S., Agboola, P.O., Shakir, I., Al-Khalli, N.F., Warsi, M.F.: The impact of highly paramagnetic Gd3+ cations on structural, spectral, magnetic and dielectric properties of spinel nickel ferrite nanoparticles. J. Saudi Chem. Soc. 25, 101306 (2021)
Ray, A., Basu, T., Behera, B., Kumar, M., Thapa, R., Nayak, P.: Role of Gd-doping in conduction mechanism of BFO-PZO nanocrystalline composites: experimental and first-principles studies. J. Alloy. Compd. 768, 198–213 (2018)
Zhu, W.M., Ye, Z.G.: Effects of chemical modification on the electrical properties of 0.67BiFeO3–0.33PbTiO3 ferroelectric ceramics. Ceram. Int. 30, 1435–1442 (2004)
Uniyal, P., Yadav, K.L.: Study of dielectric, magnetic and ferroelectric properties in Bi1−xGdxFeO3. Mater. Lett. 62, 2858–2861 (2008)
Jia, D.C., Xu, J.H., Ke, H., Wang, W., Zhou, Y.: Structure and multiferroic properties of BiFeO3 powders. J. Eur. Ceram. Soc. 29, 3099–3103 (2009)
Gowrishankar, M., Babu, D.R., Saravanan, P.: Room temperature multiferroism in La and Ti Co-substituted BiFeO3 nanoparticles. Mater. Lett. 171, 34–37 (2016)
Maleki, H.: Photocatalytic activity, optical and ferroelectric properties of Bi0.8Nd0.2FeO3 nanoparticles synthesized by sol-gel and hydrothermal methods. J. Magn. Magn. Mater. 458, 277–284 (2018)
Turchenko, V., Kostishin, V.G., Trukhanov, S., Damay, F., Balasoiu, M., Bozzo, B., Fina, I., Burkhovetsky, V.V., Polosan, S., Zdorovets, M.V., Kozlovskiy, A.L., Astapovich, K.A., Trukhanov, A.: Structural features, magnetic and ferroelectric properties of SrFe10.8In1.2O19 compound. Mater. Res. Bullet. 138, 111236 (2021)
Phan, T.L., Yu, S.C., Vincent, R., Bui, H.M., Thanh, T.D., Lam, V.D., Lee, Y.P.: Influence of Mn doping on structural, optical, and magnetic properties of Zn1−xMnxO nanorods. J. Appl. Phys. 108, 044910 (2010)
Basith, M.A., Billah, A., Jalil, M.A., Yesmin, N., Sakib, M.A., Ashik, E.K., Yousuf, S.E.H., Chowdhury, S.S., Hossain, M.S., Firoz, S.H., Ahmmad, B.: The 10% Gd and Ti co-doped BiFeO3: a promising multiferroic material. J. Alloy. Compd. 694, 792–799 (2017)
Tomczyk, M., Mahajan, A., Tkach, A., Vilarinho, P.M.: Interface-based reduced coercivity and leakage currents of BiFeO3 thin films: a comparative study. Mater. Des. 160, 1322–1334 (2018)
Makhdoom, A.R., Akhtar, M.J., Rafiq, M.A., Hassan, M.M.: Investigation of transport behavior in Ba doped BiFeO3. Ceram. Int. 38, 3829–3834 (2012)
Wang, T., Song, S.H., Ma, Q., Tan, M.L., Chen, J.J.: Highly improved multiferroic properties of Sm and Nb co-doped BiFeO3 ceramics prepared by spark plasma sintering combined with sol-gel powders. J. Alloy. Compd. 795, 60–68 (2019)
Xu, D., Zhao, W., Cao, W., Li, W., Fei, W.: Electrical properties of Li and Nb modified BiFeO3 ceramics with reduced leakage current. Ceram. Int. 47, 4217–4225 (2021)
Mao, W., Yao, Q., Fan, Y., Wang, Y., Wang, X., Pu, Y., Li, X.A.: Combined experimental and theoretical investigation on modulation of multiferroic properties in BiFeO3 ceramics induced by Dy and transition metals co-doping. J. Alloy. Compd. 784, 117–124 (2019)
Hu, H., Krupanidhi, S.B.: Current-voltage characteristics of ultrafine-grained ferroelectric Pb(Zr, Ti)O3 thin films. J. Mater. Res. 9, 1484–1498 (1994)
Qian, F.Z., Jiang, J.S., Guo, S.Z., Jiang, D.M., Zhang, W.G.: Multiferroic properties of Bi1−xDyxFeO3 nanoparticles. J. Appl. Phys. 106, 084312 (2009)
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of Interest
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Han, F., Gao, J. & Meng, X. The Binary Ion Substitution Bi1−xSrxFe1−yCoyO3 for Boosting Multiferroic Performance. J Supercond Nov Magn 36, 975–985 (2023). https://doi.org/10.1007/s10948-023-06532-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10948-023-06532-5