Skip to main content
SpringerLink
Log in

On the Magnetic Analysis of External Magnetic Field Annealing of Co 2 -W Hexagonal Shape Particles

  • Original Paper
  • Published:
Journal of Superconductivity and Novel Magnetism Aims and scope Submit manuscript

Abstract

W-type hexaferrite particles with composition of SrCo2−x (NiZnMg) x/3Fe16 O 27 (x = 0–0.5) were synthesized by a chemical co-precipitation method. The effect of substitution on the structural and magnetic properties of particles was characterized by X-ray diffraction (XRD), Fourier-transformed infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), vibrating sample magnetometer (VSM), and B-H tracer. The synthesized particles were applied under a high magnetic field of 1 T by employing a super high-capacity magnetizer and normal compression stress. The XRD patterns confirmed the existence of hexagonal W-type single phase. The FE-SEM micrographs demonstrate the nucleation of hexagonal particles along with the close view of aspect ratio of hexagonal platelet. The elemental composition estimated from the EDX analysis was in good agreement with the nominal composition. Hysteresis loops for all samples were measured at a room temperature up to a maximum applied field of 24 kOe. The results revealed that with an increase in substitutional cation contents, the values of saturation magnetization decreased from 60.6 to 11.6 emu/g, and the values of coercivity increased from 2255 to 5107 Oe. The B-H curves of field annealed bulk ferrites also display the similar trend.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Nakamura, K.H.T.: Complex permeability of polycrystalline hexagonal ferrites. IEEE Trans. Magn. 36, 3415–3417 (2000)

    Article  ADS  Google Scholar 

  2. Pullar, R.C.: Hexagonal ferrites: a review of the synthesis, properties and applications of hexaferrite ceramics. Prog. Mater. Sci. 57, 1191–1334 (2012)

    Article  Google Scholar 

  3. Stergiou, C., Litsardakis, G.: Preparation and magnetic characterization of Co2-W strontium hexaferrites doped with Ni and La. J. Magn. Magn. Mater. 323, 2362–2368 (2011)

    Article  ADS  Google Scholar 

  4. Khan, I., Sadiq, I., Ashiq, M.N., Rana, M.-U.-D.: Role of Ce–Mn substitution on structural, electrical and magnetic properties of W-type strontium hexaferrites. J. Alloys Compd. 509, 8042–8046 (2011)

    Article  Google Scholar 

  5. Manikandan, A., Durka, M., Arul Antony, S.: One-pot flash combustion synthesis, structural, morphological and opto-magnetic properties of spinel MnxCo1-xAl2O4 (x = 0, 0.3 and 0.5) nano-catalysts. J. Supercond. Nov. Magn. 28, 209–218 (2015)

    Article  Google Scholar 

  6. Manikandan, A., Durka, M., Arul Antony, S.: A novel synthesis, structural, morphological and opto-magnetic characterizations of magnetically separable spinel CoxMn1-xFe2O4 (0 = x =1) nano-catalysts. J. Supercond. Nov. Magn. 27, 2841–2857 (2014)

    Article  Google Scholar 

  7. Manikandan, A., Arul Antony, S., Sridhar, R., Bououdina, M.: A simple combustion synthesis and optical studies of magnetic Zn1-xNixFe2O4 nanostructures for photoelectrochemical applications. J. Nanosci. Nanotechnol. 15, 4948–4960 (2015)

    Article  Google Scholar 

  8. Manikandan, A., Hema, E., Durka, M., Seevakan, K., Alagesan, T., Arul Antony, S.: Room temperature ferromagnetism of magnetically recyclable photocatalyst of Cu1-xMnxFe2O4-TiO2 (0.0 = x = 0.5) nano-composites. J. Supercond. Nov. Magn. 28, 1783–1795 (2015)

    Article  Google Scholar 

  9. Manikandan, A., Durka, M., Arul Antony, S.: Role of Mn2 + doping on structural, morphological and opto-magnetic properties of spinel MnxCo1-xFe2O4 (x = 0.0, 0.1, 0.2, 0.3, 0.4 and 0.5) nano-catalysts. J. Supercond. Nov. Magn. 28, 2047–2058 (2015)

    Article  Google Scholar 

  10. Manikandan, A., Durka, M., Seevakan, K., Arul Antony, S.: A novel one-pot combustion synthesis and opto-magnetic properties of magnetically separable spinel MnxMg1-xFe2O4 (0.0 = x = 0.5) nano-photocatalysts. J. Supercond. Nov. Magn. 28, 1405–1416 (2015)

    Article  Google Scholar 

  11. Ahmad, M., Grössinger, R., Kriegisch, M., Kubel, F., Rana, M.U.: Characterization of Sr-substituted W-type hexagonal ferrites synthesized by sol–gel autocombustion method. J. Magn. Magn. Mater. 332, 137–145 (2013)

    Article  ADS  Google Scholar 

  12. Stergiou, C.A., Litsardakis, G.: Electromagnetic properties of Ni and La doped strontium hexaferrites in the microwave region. J. Alloys Compd. 509, 6609–6615 (2011)

    Article  Google Scholar 

  13. Ümit Özgür, Y.A., Morkoc, H.: Microwave Ferrites Part 1: Fundamental Properties. Virginia Commonwealth University (2009)

  14. Ahmad, M., Ali, I., Grössinger, R., Kriegisch, M., Kubel, F., Rana, M.U.: Effects of divalent ions substitution on the microstructure, magnetic and electromagnetic parameters of Co2W hexagonal ferrites synthesized by sol–gel method. J. Alloys Compd. 579, 57–64 (2013)

    Article  Google Scholar 

  15. Aen, F., Niazi, S.B., Islam, M.U., Ahmad, M., Rana, M.U.: Effect of holmium on the magnetic and electrical properties of barium based W-type hexagonal ferrites. Ceram. Int. 37, 1725–1729 (2011)

    Article  Google Scholar 

  16. Ahmad, M., Aen, F., Islam, M.U., Niazi, S.B., Rana, M.U.: Structural, physical, magnetic and electrical properties of La-substituted W-type hexagonal ferrites. Ceram. Int. 37, 3691–3696 (2011)

    Article  Google Scholar 

  17. Ahmad, M., Ali, I., Aen, F., Islam, M.U., Ashiq, M.N., Atiq, S., Ahmad, W., Rana, M.U.: Effect of sintering temperature on magnetic and electrical properties of nano-sized Co2W hexaferrites. Ceram. Int. 38, 1267–1273 (2012)

    Article  Google Scholar 

  18. Deng, L., Ding, L., Zhou, K., Huang, S., Hu, Z., Yang, B.: Electromagnetic properties and microwave absorption of W-type hexagonal ferrites doped with La3 +. J. Magn. Magn. Mater. 323, 1895–1898 (2011)

    Article  ADS  Google Scholar 

  19. Iqbal, M.A., Tahir, W., Murtaza Rai, G., Noor, N.A., Ali, S., Kubra, K.T.: An investigation of the titanium effect on the structural and magnetic properties of BaNi2 based W-type hexaferrites. Ceram. Int. 38, 3757–3762 (2012)

    Article  Google Scholar 

  20. Ahmed, M.A., Okasha, N., Oaf, M., Kershi, R.M.: The role of Mg substitution on the microstructure and magnetic properties of Ba Co Zn W-type hexagonal ferrites. J. Magn. Magn. Mater. 314, 128–134 (2007)

    Article  ADS  Google Scholar 

  21. Jotania, R.B.K.R.B., Deshpande, A.S., Chauhan, C.C., Kulkarni, B.D.: Physical and magnetic properties of barium calcium hexaferrite nano- particles synthesized by water-in-oil reverse micelle and co-precipitation techniques. Sci. Res. 1, 1–13 (2009)

    Google Scholar 

  22. Herzer, G.: Grain size dependence of coercivity and permeability in nanocrystalline ferromagnet. IEEE Trans. Magn. 36, 1397–1402 (1990)

    Article  MathSciNet  ADS  Google Scholar 

  23. Iqbal, M.J., Khan, R.A., Mizukami, S., Miyazaki, T.: Tailoring of structural, electrical and magnetic properties of BaCo2 W-type hexaferrites by doping with Zr–Mn binary mixtures for useful applications. J. Magn. Magn. Mater. 323, 2137–2144 (2011)

    Article  ADS  Google Scholar 

  24. Stergiou, G.L.C.: Preparation and magnetic characterization of Co2-W strontium hexaferrites doped with Ni and La. Magn. Magn. Mater. 323, 2368–2368 (2011)

    Article  ADS  Google Scholar 

  25. Goldman, A.: Modern Ferrite Technology. Springer (2006)

  26. Sunil Chauhan, M.A., Sati, P.C., Chhoker, S., Katyal, S.C., Kumar, M.: Structural, vibrational, optical, magnetic and dielectric properties of Bi 1 - x Ba x FeO 3 nanoparticles. Ceram. Int. 39, 6399–6405 (2013)

    Article  Google Scholar 

  27. Iqbal, M.J., Khan, R.A., Mizukami, S., Miyazaki, T.: Mössbauer and magnetic study of Mn, Zr and Cd substituted W-type hexaferrites prepared by co-precipitation. Mater. Res. Bull. 46, 1980–1986 (2011)

    Article  Google Scholar 

  28. Iqbal, M.J., Khan, R.A., Mizukami, S., Miyazaki, T.: Mössbauer, magnetic and microwave absorption characteristics of substituted W-type hexaferrites nanoparticles. Ceram. Int. 38, 4097–4103 (2012)

    Article  Google Scholar 

  29. Iqbal, M.J., Khan, R.A., Takeda, S., Mizukami, S., Miyazaki, T.: W-type hexaferrite nanoparticles: A consideration for microwave attenuation at wide frequency band of 0.5–10GHz. J. Alloys Compd. 509, 7618–7624 (2011)

    Article  Google Scholar 

  30. ChungHo Ri, L.L., Qi, Yang: Anisotropy of the electrical conductivity in W-type hexagonal ferrites BaFe18 O 27 and BaCo2Fe16 O 27 from first principles. J. Magn. Magn. Mater. 324, 1498–1502 (2012)

    Article  ADS  Google Scholar 

  31. Imran Sadiq, I.K., Aen, F., Islam, M.U., Rana, M.U.: Influence of rare earth Ce 3+ on structural, electrical and magnetic propertiesof Sr 2+ based W-type hexagonal ferrites. Physica B 407, 1256–1261 (2012)

    Article  ADS  Google Scholar 

  32. Manikandan, A., John Kennedy, L., Bououdina, M., Judith Vijaya, J.: Structural, optical and magnetic properties of Zn1-xCuxFe2O4 nanoparticles prepared by microwave combustion method. J. Mol. Struct. 1035, 332–340 (2013)

    Article  ADS  Google Scholar 

  33. Manikandan, A., John Kennedy, L., Bououdina, M., Judith Vijaya, J.: Microwave combustion synthesis, structural, optical and magnetic properties of Zn1-xSrxFe2O4 nanoparticles. Ceram. Int. 39, 5909–5917 (2013)

    Article  Google Scholar 

  34. Manikandan, A., John Kennedy, L., Bououdina, M., Judith Vijaya, J.: Synthesis, optical and magnetic properties of pure and Co-doped ZnFe2O4 nanoparticles by microwave combustion method. J. Magn. Magn. Mater. 349, 249–258 (2014)

    Article  ADS  Google Scholar 

  35. Manikandan, A., Judith Vijaya, J., Sundararajan, M., Meganathan, C., John Kennedy, L., Bououdina, M.: Optical and magnetic properties of Mg-doped ZnFe2O4 nanoparticles prepared by rapid microwave combustion method. Superlattices Microstruct. 64, 118–131 (2013)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Materials Engineering Department, Malek Ashtar University of Technology, Shahin Shahr, Iran

    Ali Ghasemi

Authors
  1. Ali Ghasemi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ali Ghasemi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ghasemi, A. On the Magnetic Analysis of External Magnetic Field Annealing of Co 2 -W Hexagonal Shape Particles. J Supercond Nov Magn 29, 1601–1610 (2016). https://doi.org/10.1007/s10948-016-3435-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10948-016-3435-0

Keywords

Search

Navigation