Skip to main content
SpringerLink
Log in

LDH–Ferrite–Biochar–Polymeric Composites for Enhanced Adsorption–Desorption of Acid Blue 41 and Real Textile Wastewater Purification: A Batch and Column Study

  • Research
  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

One major cause of to environmental pollution is industrial dye wastewater. The main purpose of current work was synthesis and investigation of effectiveness of LDH–Ferrite–Biochar–Polymeric composites for removal of anionic dye (Acid blue 41) from wastewater. The co-precipitation technique is used to synthesize Zn–Al Layered double hydroxide-Manganese ferrite–Egg Shell biochar–Starch (Zn–Al–MnFe2O4–ESB–Sta), Cu–Al Layered double hydroxide–Cadmium ferrite–Eucalyptus bark biochar–Chitosan (Cu–Al–CdFe2O4–EBB–Cs), Cd–Al Layered double hydroxide–Cobalt ferrite–Jujube wood biochar–Sodium alginate (Cd–Al–CoFe2O4–JWB–Na–Alg), Mn–Al Layered double hydroxide–Copper ferrite–Mulberry Stem Biochar–Starch (Mn–Al–CuFe2O4–MSB–Sta) and Co–Al Layered double hydroxide–zinc ferrite-peanut shell biochar–carboxymethyl cellulose (Co–Al–ZnFe2O4–PSB–CMC). According to findings of recent studies, Zn–Al–MnFe2O4–ESB-Sta (40.1 mg/g), Cu–Al–CdFe2O4–EBB–Cs (35.6 mg/g), Cd–Al–CoFe2O4–JWB–Na–Alg (28.1 mg/g), Mn–Al–CuFe2O4–MSB-Sta (37.3 mg/g) and Co–Al–ZnFe2O4–PSB–CMC (31.2 mg/g) has adsorption capacity for acid blue 41 dye. All composites achieved maximum adsorption effectiveness in acidic range (2–5), eliminating AB-41 dye in 45 min at optimal dose 0.05 g and 150 mg/l initial dye concentration was optimum. After 30 °C, adsorption potential decreased, indicating exothermic mechanisms. The efficiency was still adequate after five cycles of regeneration. The Pseudo 2nd order Kinetics and Freundlich isotherm model were successfully implemented among the applied models. The aforementioned composites are deemed the most cost-effective, energy-efficient, ecologically friendly, and biologically renewable materials for treating wastewater containing AB-41 dye. The results indicate that Zn–Al–MnFe2O4–ESB–Sta is the most effective synthetic composite for water remediation among all others. Furthermore, it was discovered in a column study that the ideal bed height, flow rate, and inlet concentration of dye were 3 cm, 3.6 ml/min, and 50 mg/l, respectively, for achieving the highest adsorption of AB-41 dye.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16

Similar content being viewed by others

Data Availability

Data will be made available on reasonable request.

References

  1. R.K. Mishra, Br. J. Multidiscip. Adv. Stud. 4, 1–78 (2023)

    Article  CAS  Google Scholar 

  2. A.M.M. Irfeey, B.A. Alotaibi, M.M. Najim, A.A. Shah, Water 15, 3105 (2023)

    Article  Google Scholar 

  3. M. Munsamy, A. Telukdarie, P. Matjuta, Procedia Comput. Sci. 217, 699–708 (2023)

    Article  Google Scholar 

  4. Y. Zhang, J. Deng, B. Qin, G. Zhu, Y. Zhang, E. Jeppesen, Y. Tong, Fundamental Research 3, 265–273 (2023)

    Article  CAS  Google Scholar 

  5. M.A. Ahmed, M.A. Ahmed, A.A. Mohamed, RSC Adv. 13, 5337–5352 (2023)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  6. M.D. Khan, A. Singh, M.Z. Khan, S. Tabraiz, J. Sheikh, J. Water Process Eng. 53, 103579 (2023)

    Article  Google Scholar 

  7. I. Saad, N. Ralha, M.R. Abukhadra, W. AlZoubi, Y.G. Ko, J. Water Process Eng. 52, 103572 (2023)

    Article  Google Scholar 

  8. R. Khan, S. Shukla, M. Kumar, A. Zuorro, A. Pandey, Chem. Eng. J. 471, 144495 (2023)

    Article  CAS  Google Scholar 

  9. U.M. Nisha, D. Venkatesh, S. Arulmurugan, A. Kistan, P. Rajeswaran, P.S. Karthik, Inorg. Chem. Commun. 160, 111942 (2024)

    Article  Google Scholar 

  10. Z. Ren, X. Yang, W. Zhang, Z. Zhao, J. Mol. Struct. 1274, 134407 (2023)

    Article  CAS  Google Scholar 

  11. V. Halysh, O. Sevastyanova, S. Pikus, G. Dobele, B. Pasalskiy, V.M. Gun’ko, M. Kartel, Cellulose 27, 8181–8197 (2020)

    Article  CAS  Google Scholar 

  12. M. Negarestani, S. Reisi, M. Sohrabi, H. Shayesteh, H. Farimaniraad, A. Mollahosseini, M. Hosseinzadeh, S. Tavassoli, Journal of Water Process Engineering 57, 104657 (2024)

    Article  Google Scholar 

  13. G. Zhou, S. Li, Q. Meng, C. Niu, X. Zhang, Q. Wang, Surfaces and Interfaces 36, 102637 (2023)

    Article  CAS  Google Scholar 

  14. I. Elsayed, G.T. Schueneman, E.M. El-Giar, E.B. Hassan, Gels 9, 154 (2023)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  15. A.S. Giri, V. Kumar, S. Chakma, Application of Metallic Nanoparticles for Industrial Wastewater Treatment, Advanced Application of Nanotechnology to Industrial Wastewater, pp. 33-52, Springer 2023.

  16. Y. Xie, F. Kong, Z. Mi, H. Huang, C. Xia, Z. Ma, S. Li, Q. Zhang, Z. Meng, Journal of Water Process Engineering 52, 103502 (2023)

    Article  Google Scholar 

  17. R. Tabatabaeian, M. Dinari, H.M. Aliabadi, Carbohydrate Polymers 257, 117628 (2021)

    Article  CAS  PubMed  Google Scholar 

  18. M. Negarestani, S. Kazemi, H. Shayesteh, S. Javanshir, H. Ghiasinejad, E. Jamshidi, Separation and Purification Technology 304, 122362 (2023)

    Article  Google Scholar 

  19. D. Zhai, J. Wen, Q. Ding, Y. Feng, W. Yang, International Journal of Hydrogen Energy 48, 10108–10117 (2023)

    Article  CAS  Google Scholar 

  20. Y. Huang, C. Liu, L. Qin, M. Xie, Z. Xu, Y. Yu, Molecules 28, 4538 (2023)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  21. M. Zubair, H.A. Aziz, I. Ihsanullah, M.A. Ahmad, M.A. Al-Harthi, Chemosphere 307, 136054 (2022)

    Article  CAS  PubMed  Google Scholar 

  22. N. Ghanbari, H. Ghafuri, Environ. Technol. Innov. 26, 102377 (2022)

    Article  CAS  Google Scholar 

  23. D. Chen, Y. Yin, Y. Xu, C. Liu, J. Water Process Eng. 51, 103445 (2023)

    Article  Google Scholar 

  24. Y. Luo, Y. Wang, F. Hua, M. Xue, X. Xie, Y. Xie, S. Yu, L. Zhang, Z. Yin, C. Xie, J. Hazard. Mater. 443, 130300 (2023)

    Article  CAS  PubMed  Google Scholar 

  25. R. Sarkhel, P. Ganguly, P. Das, A. Bhowal, S. Sengupta, Environ. Qual. Manag. 32, 313–323 (2023)

    Article  Google Scholar 

  26. A. Abbasi, F. Khatoon, S. Ikram, Int. J. Biol. Macromol. 231, 123240 (2023)

    Article  CAS  PubMed  Google Scholar 

  27. M. Asyraf, K. Hazrati, D.D.C.V. Sheng, M. Rafidah, W. Ashraf, E. Madenci, Y.O. Özkılıç, C. Aksoylu, N. Nurazzi, Fibers Polym. 1–15 (2023).

  28. Sonia, H. Kumari, Suman, S. Chahal, S. Devi, S. Kumar, S. Kumar, P. Kumar, A. Kumar, Appl. Phys. A 129, 91 (2023)

    Article  CAS  Google Scholar 

  29. K. Solanki, S. Sharma, S. Yadav, B. Kaushik, P. Rana, R. Dixit, R. Sharma, Small, 2300394 (2023).

  30. M.E. Mahmoud, S.M. El-Bahy, S.M. Elweshahy, Bioresour. Technol. 342, 126029 (2021)

    Article  CAS  PubMed  Google Scholar 

  31. A. Akram, S. Muzammal, M.B. Shakoor, S.R. Ahmad, A. Jilani, J. Iqbal, A.G. Al-Sehemi, A. Kalam, S.F.O. Aboushoushah, Catalysts 12, 431 (2022)

    Article  CAS  Google Scholar 

  32. A.S. Yusuff, L.T. Popoola, A.I. Igbafe, Chem. Eng. Res. Des. 182, 592–603 (2022)

    Article  CAS  Google Scholar 

  33. M.I. Al-Wabel, M. Ahmad, M.I. Rafique, M.A. Akanji, A.R. Usman, A.S. Al-Farraj, Molecules 26, 4674 (2021)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  34. M. Liang, S. Xu, Y. Zhu, X. Chen, Z. Deng, L. Yan, H. He, Int. J. Environ. Res. Public Health 17, 676 (2020)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  35. H.A. Murad, M. Ahmad, J. Bundschuh, Y. Hashimoto, M. Zhang, B. Sarkar, Y.S. Ok, Environ. Res. 204, 112125 (2022)

    Article  CAS  PubMed  Google Scholar 

  36. D. Brahma, H. Saikia, Chem. Thermodyn. Thermal Anal. 7, 100067 (2022)

    Article  Google Scholar 

  37. S. Gillani, R. Munir, K. Ali, M.Z. Bashir, U.H. Siddiqua, S. Noreen, Clean Technol. Environ. Policy, 1-20 (2023).

  38. J. Panwar, S. Gupta, Environ. Sci. Pollut. Res. 30, 61541–61561 (2023)

    Google Scholar 

  39. J. Iqbal, N.S. Shah, M. Sayed, N.K. Niazi, M. Imran, J.A. Khan, Z.U.H. Khan, A.G.S. Hussien, K. Polychronopoulou, F. Howari, J. Hazard. Mater. 403, 123854 (2021)

    Article  CAS  PubMed  Google Scholar 

  40. P.K. Obulapuram, T. Arfin, F. Mohammad, S.K. Khiste, M. Chavali, A.N. Albalawi, H.A. Al-Lohedan, Polymers 13, 3490 (2021)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  41. N. Tahir, H.N. Bhatti, M. Iqbal, S. Noreen, Int. J. Biol. Macromol. 94, 210–220 (2017)

    Article  CAS  PubMed  Google Scholar 

  42. A. Muhammad, A.-u-H.A. Shah, S. Bilal, G. Rahman, Materials 12, 1764 (2019)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  43. P. Kumbhar, D. Narale, R. Bhosale, C. Jambhale, J.-H. Kim, S. Kolekar, J. Environ. Chem. Eng. 10, 107893 (2022)

    Article  CAS  Google Scholar 

  44. A. Jabeen, H.N. Bhatti, Environ. Technol. Innov. 23, 101685 (2021)

    Article  CAS  Google Scholar 

  45. J. Mittal, J. Environ. Manag. 295, 113017 (2021)

    Article  CAS  Google Scholar 

  46. S. Noreen, S. Ismail, S.M. Ibrahim, H.S. Kusuma, A. Nazir, M. Yaseen, M.I. Khan, M. Iqbal, Zeitschrift Für Physikalische Chemie 235, 1055–1075 (2021)

    Article  CAS  Google Scholar 

  47. M. Sajid, I. Ihsanullah, Sci. Total Environ. 880, 163299 (2023)

    Article  CAS  PubMed  Google Scholar 

  48. L. Zafar, A. Khan, U. Kamran, S.-J. Park, H.N. Bhatti, Surf. Interfaces 31, 101897 (2022)

    Article  CAS  Google Scholar 

  49. A. Ashraf, R. Munir, G. Albasher, M. Ghamkhar, A. Muneer, M. Yaseen, T. Murtza, S. Noreen, J. Environ. Sci. Health Part A, 1–21 (2023).

  50. H. Moussout, H. Ahlafi, M. Aazza, H. Maghat, Karbala Int. J. Mod. Sci. 4, 244–254 (2018)

    Article  Google Scholar 

  51. A. Amanullah, R. Munir, M.Z. Bashir, M.Y. Naz, S. Shukrullah, M. Yaseen, A. Muneer, S. Noreen, Int. J. Environ. Anal. Chem. (2023). https://doi.org/10.1080/03067319.2023.2215165

    Article  Google Scholar 

  52. R. Munir, K. Ali, S.A.Z. Naqvi, M.A. Maqsood, M.Z. Bashir, S. Noreen, Sep. Purif. Technol. 306, 122527 (2023)

    Article  CAS  Google Scholar 

  53. L. Dhar, M.S. Rahman, S. Hossain, S.B. Quraishi, K. Saha, F. Rahman, U.K. Sarker, M.T. Rahman, J. Iran. Chem. Soc. 19, 1319–1328 (2022)

    Article  CAS  Google Scholar 

  54. D. Brahma, H. Nath, D. Borah, M. Debnath, H. Saikia, Inorg. Chem. Commun. 144, 109878 (2022)

    Article  CAS  Google Scholar 

  55. E. Binaeian, S.B. Zadvarzi, D. Yuan, Int. J. Biol. Macromol. 162, 150–162 (2020)

    Article  CAS  PubMed  Google Scholar 

  56. K.H. Chu, M.A. Hashim, J. Mol. Liquids 371, 121122 (2023)

    Article  CAS  Google Scholar 

  57. U. Kamran, H.N. Bhatti, S. Noreen, M.A. Tahir, S.-J. Park, Chemosphere 291, 132796 (2022)

    Article  CAS  PubMed  Google Scholar 

  58. S. Abid, R. Munir, M. Sayed, R. Nadeem, A. Muneer, M. Zahid, M. Yaseen, U.H. Siddiqua, S. Noreen, Catal. Surv. Asia 50, 1–17 (2023)

    Google Scholar 

  59. S. Noreen, H.N. Bhatti, S. Nausheen, S. Sadaf, M. Ashfaq, Ind. Crops Prod. 50, 568–579 (2013)

    Article  CAS  Google Scholar 

  60. B.K. Bhangi, S.K. Ray, Int. J. Biol. Macromol. 144, 801–812 (2020)

    Article  CAS  PubMed  Google Scholar 

  61. S. Biswas, S.S. Mohapatra, U. Kumari, B.C. Meikap, T.K. Sen, J. Environ. Chem. Eng. 8, 103637 (2020)

    Article  CAS  Google Scholar 

  62. L. Das, S. Sengupta, P. Das, A. Bhowal, C. Bhattacharjee, Surf. Interfaces 23, 100985 (2021)

    Article  CAS  Google Scholar 

  63. M.M. Khan, A. Khan, H.N. Bhatti, M. Zahid, S. Alissa, Y.A. El-Badry, E.E. Hussein, M. Iqbal, J. Mater. Res. Technol. 15, 2016–2025 (2021)

    Article  CAS  Google Scholar 

  64. S. Perveen, R. Nadeem, F. Nosheen, L. Tongxiang, T. Anwar, Appl. Nanosci. 12, 1491–1505 (2022)

    Article  CAS  Google Scholar 

  65. J. Pérez-Calderón, M.V. Santos, N. Zaritzky, Can. J. Chem. Eng. 12, 1491–1505 (2023)

    Google Scholar 

  66. M. Zubair, H.A. Aziz, I. Ihsanullah, M.A. Ahmad, M.A. Al-Harthi, Environ. Res. 209, 112861 (2022)

    Article  CAS  PubMed  Google Scholar 

  67. D. Guimarães, N.C. da Rocha, R.A. de Morais, A.D.-L.B. Resende, R.M. Lima, G.M. da Costa, V.A. Leao, J. Environ. Chem. Eng. 7, 102815 (2019)

    Article  Google Scholar 

  68. S. Li, Y. Yang, S. Huang, Z. He, C. Li, D. Li, B. Ke, C. Lai, Q. Peng, Appl. Clay Sci. 188, 105414 (2020)

    Article  CAS  Google Scholar 

  69. M. Zubair, H.A. Aziz, I. Ihsanullah, M.A. Ahmad, M.A. Al-Harthi, Environ. Technol. Innov. 23, 101614 (2021)

    Article  CAS  Google Scholar 

  70. F.B. DallaNora, V.V. Lima, M.L. Oliveira, A. Hosseini-Bandegharaei, T.A. de LimaBurgo, L. Meili, G.L. Dotto, J. Environ. Chem. Eng. 8, 103913 (2020)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors would like to extend their sincere appreciation to the acknowledgment; research supporting project (RSP- 2024/95, King Saud University, Riyadh, Saudi Arabia).

Funding

This research did not receive any funding.

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Agriculture, Faisalabad, 38000, Pakistan

    Misbah Maqbool, Ruba Munir, Raziya Nadeem, Muhammad Zahid & Saima Noreen

  2. School of Environmental Science and Engineering, Shandong University, Qingdao, 266237, China

    Fazila Younas

  3. Department of Physics, Government College Women University, Faisalabad, 38000, Pakistan

    Amna Muneer

  4. Qingdao Key Laboratory of Ecological Protection and Restoration, School of Life Science, Shandong University, Qingdao, 266237, China

    Muhammad Fahad Sardar

  5. Department of Physics, University of Agriculture, Faisalabad, 38000, Pakistan

    Muhammad Yaseen

  6. Department of Zoology, College of Science, King Saud University, Riyadh, Saudi Arabia

    Gadah Albasher

Authors
  1. Misbah Maqbool
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ruba Munir
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Fazila Younas
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Amna Muneer
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Muhammad Fahad Sardar
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Raziya Nadeem
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Muhammad Zahid
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Muhammad Yaseen
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Gadah Albasher
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. Saima Noreen
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

Misbah Maqbool: Methodology, Conceptualization, Writing- original draft, Saima Noreen: Supervision, Conceptualization, Writing- Reviewing and Editing, Ruba Munir: Writing- Reviewing and Editing, Investigation, Conceptualization, Fazila Younas: Conceptualization, Investigation, Amna Muneer: Data curation, Writing-review& editing, Muhammad Fahad Sardar: Formal analysis, Writing- Reviewing and Editing, Raziya Nadeem: Formal analysis, Writing- Reviewing and Editing, Muhammad Zahid: Formal analysis, Writing- Reviewing and Editing, Gadah Albasher: Resources, Writing-review& editing, Muhammad Yaseen: Investigation, Writing-review& editing,

Corresponding author

Correspondence to Saima Noreen.

Ethics declarations

Competing Interests

The authors declare no competing interests.

Ethical Approval

Not applicable.

Consent for Publication

All authors have read and approved this manuscript.

Consent to Participate

Not applicable.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 12894 KB)

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Maqbool, M., Munir, R., Younas, F. et al. LDH–Ferrite–Biochar–Polymeric Composites for Enhanced Adsorption–Desorption of Acid Blue 41 and Real Textile Wastewater Purification: A Batch and Column Study. J Inorg Organomet Polym (2024). https://doi.org/10.1007/s10904-024-03050-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10904-024-03050-2

Keywords

Search

Navigation