Skip to main content
SpringerLink
Log in

A Binuclear Cadmium(II) Cluster Based on π···π Stacking and Halogen···Halogen Interactions: Synthesis, Crystal Analysis and Fluorescent Properties

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

An interseting binuclear complex [Cd2(tcpa)4(bipy)2] (1) has been hydrothermally synthesized with 3, 5, 6-trichloropyridine phenoxy acetatic acid (Htcpa) and 2, 2′-bipyridine (bipy) coligands. The X-ray single-crystal diffraction analysis shows that the CdII center is situated on unusual triangular prismatic geometry formed by two pyridyl nitrogen atoms of a bipy molecule and four carboxyl oxygen atoms of four different tcpa− ligands. The four tcpa− anions play as bis-monodentate linkers and connect two CdII ions together to form the dimer structure of 1. 1 is further assembled into a 2D layer by the co-effects of π···π stacking and Cl···Cl halogen bonds interactions. Moreover, 1 exhibits intense solid-state luminescence emissions centered at 442 nm at room temperature, which mainly originates from the intraligand π → π* transitions of tcpa−. The CCDC number of 1 is 1,935,091.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Y.-H. Zhou and Y.-P. Tian (2013). J. Chem. Crystallogr.43, 31.

    Article  CAS  Google Scholar 

  2. X. Xu, F. Hu, Y. Ma, J. Gao, and Q. Shuai (2018). New J Chem.42, 4155.

    Article  CAS  Google Scholar 

  3. X. Xu, F. Hu, and Q. Shuai (2017). Dalton Trans.46, 15424.

    Article  CAS  Google Scholar 

  4. Y.-X. Ren, B.-J. Jiao, M.-L. Zhang, X.-M. Gao, and J. Wang (2011). Z. Anorg. Allg. Chem.637, 1612.

    Article  CAS  Google Scholar 

  5. Y.-H. Zhou and Z.-Y. Wang (2015). Transit. Met. Chem.40, 89.

    Article  CAS  Google Scholar 

  6. J. Wu, H. Li, N. Ren, J. Zhang, and S. Wang (2016). J. Rare Earths34, 1083.

    Article  CAS  Google Scholar 

  7. W.-J. Xua, L.-Y. Zhang, G.-H. Pan, P. Liang, W.-M. Tian, and Y. Feng (2014). Synth. React. Inorg. Met.-Org. Chem.44, 1331.

    Article  Google Scholar 

  8. S.-M. Fang, Q. Zhang, M. Hu, X.-G. Yang, L.-M. Zhou, M. Du, and C.-S. Liu (2010). Cryst. Growth Des.10, 4773.

    Article  CAS  Google Scholar 

  9. J. Zhang and J.-X. Li (2016). Z. Naturforsch.71b, 45.

    Article  Google Scholar 

  10. C.-S. Liu, J.-J. Wang, Z. Chang, and L.-F. Yan (2009). Z. Anorg. Allg. Chem.636, 1115.

    Article  Google Scholar 

  11. J. D. Fu, Z. W. Tang, X. Feng, and Y. H. Wen (2010). Sci. China. Chem.53, 1060.

    Article  CAS  Google Scholar 

  12. Y.-Q. Yang, Z.-M. Chen, and Y.-F. Kuang (2013). Chinese. J. Inorg. Chem.29, 185.

    Google Scholar 

  13. H.-J. Hao, X.-H. Yin, C.-W. Lin, and S.-Q. Wei (2011). Bull. Korean. Chem. Soc.32, 3255.

    Article  CAS  Google Scholar 

  14. X. W. Wang, H. Guo, M. J. Liu, X. Y. Wang, and D. S. Deng (2014). Chin. Chem. Lett.25, 243.

    Article  Google Scholar 

  15. D. S. Deng, G. H. Kang, B. M. Ji, H. L. Li, G. R. Qu, and X. S. Fan (2013). Aust. J. Chem.66, 1342.

    Article  CAS  Google Scholar 

  16. J. Wang, C.-Y. Tan, J.-Q. Tao, and X.-J. Xu (2013). J. Clust. Sci.25, 349.

    Article  CAS  Google Scholar 

  17. H.-Y. Ma, C.-H. Su, J. Yin, Y.-W. Li, and X. Shao (2015). J. Clust. Sci.26, 1403.

    Article  CAS  Google Scholar 

  18. L.-Y. Zhao, L. Feng, X.-C. Deng, L.-W. Liu, and L. Ren (2018). J. Clust. Sci.29, 1023.

    Article  CAS  Google Scholar 

  19. J.-X. Li and Z.-X. Du (2010). Z. Kristallogr. NCS225, 795.

    CAS  Google Scholar 

  20. J.-X. Li, Z.-X. Du, H.-Q. An, J.-X. Dong, X.-J. Hu, and W.-P. Huang (2010). Z. Anorg. Allg. Chem.636, 1635.

    Article  CAS  Google Scholar 

  21. J. Li, Z. Du, and W. Huang (2014). Synth. React. Inorg. Met.-Org. Chem.44, 352.

    Article  CAS  Google Scholar 

  22. J.-X. Li, W.-B. Guo, Z.-X. Du, and W.-P. Huang (2011). Inorg. Chim. Acta375, 290.

    CAS  Google Scholar 

  23. J.-X. Li, Z.-X. Du, B.-L. Zhu, H.-Q. An, J.-X. Dong, X.-J. Hu, and W.-P. Huang (2011). Inorg. Chem. Commun.14, 522.

    Article  CAS  Google Scholar 

  24. J.-X. Li, Z.-X. Du, and W.-P. Huang (2011). Z. Naturforsch.66b, 1029.

    Article  Google Scholar 

  25. J.-X. Li and Z.-X. Du (2016). J. Coord. Chem.69, 2563.

    Article  CAS  Google Scholar 

  26. J.-X. Li and Z.-X. Du (2015). Z. Naturforsch.70b, 505.

    Article  Google Scholar 

  27. CrysAlisPRO, Rigaku Oxford Diffraction, Oxford Diffraction Ltd, England, 2016.

  28. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann (2009). J. Appl. Cryst.42, 339.

    Article  CAS  Google Scholar 

  29. G. M. Sheldrick (2015). Acta Crystallogr. A71, 3.

    Article  Google Scholar 

  30. G. M. Sheldrick (2015). Acta Crystallogr. C71, 3.

    Article  Google Scholar 

  31. S. Biju, N. Gopakumar, J. C. Bunzli, R. Scopelliti, H. K. Kim, and M. L. Reddy (2013). Inorg. Chem.52, 8750.

    Article  CAS  Google Scholar 

  32. D.-Y. Ma, H.-F. Guo, L. Qin, Y. Li, Q.-T. Ruan, Y.-W. Huang, and J. Xu (2014). J. Chem. Crystallogr.44, 63.

    Article  CAS  Google Scholar 

  33. C.-S. Liu, C. Wang, M. Hu, and S.-M. Fang (2011). Z. Anorg. Allg. Chem.637, 748.

    Article  CAS  Google Scholar 

  34. Z. Chang, A.-S. Zhang, T.-L. Hu, and X.-H. Bu (2009). Cryst. Growth Des.9, 4840.

    Article  CAS  Google Scholar 

  35. S.-L. Zheng, J.-H. Yang, X.-L. Yu, X.-M. Chen, and W.-T. Wong (2004). Inorg. Chem.43, 830.

    Article  CAS  Google Scholar 

  36. A. Vogler and H. Kunkely (2006). Coord. Chem. Rev.250, 1622.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the Key scientific research projects in Colleges and Universities of Henan province (No. 17A150040), the Foundation for Science and Technology Innovation Talents in Henan province (No. 164100510012), Natural Science Foundation of China (Nos. 21671114 and U1804131) as well as the Tackle Key Problem of Science and Technology Project of Henan Province, China (no. 182102310897).

Author information

Authors and Affiliations

  1. Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471934, Henan Province, People’s Republic of China

    Jun-Xia Li

  2. College of Foods and Drugs, Luoyang Normal University, Luoyang, 471934, Henan Province, People’s Republic of China

    Zhong-Xiang Du

Authors
  1. Jun-Xia Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhong-Xiang Du
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jun-Xia Li.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, JX., Du, ZX. A Binuclear Cadmium(II) Cluster Based on π···π Stacking and Halogen···Halogen Interactions: Synthesis, Crystal Analysis and Fluorescent Properties. J Clust Sci 31, 507–511 (2020). https://doi.org/10.1007/s10876-019-01666-w

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-019-01666-w

Keywords

Search

Navigation