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A Novel Coordination Polymer Based on Cd2O2 Clusters: Synthesis, Structure and Physical Property

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Abstract

A novel coordination polymer [Cd(bpda)(btx)·H2O]n (1) (H2bpda = 4,4′-carbonyldibenzoic acid, btx = 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene) has been synthesized under hydrothermal condition and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction. The crystal structure of complex 1 shows a novel three-dimensional framework based on Cd2O2 clusters with three-fold interpenetrated 6-connected net with point symbol of {412.63}. The photoluminescence of 1 in the solid state has also been investigated.

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Acknowledgments

This work was supported by the Natural Science Fund for colleges and universities in Jiangsu Province (No. 11KJD150006).

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Authors and Affiliations

  1. Department of Chemistry, Yancheng Teachers’ College, Yancheng, 224002, People’s Republic of China

    Jun Wang, Chun-Yun Tan, Jian-Qing Tao & Xiao-Juan Xu

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  1. Jun Wang
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  2. Chun-Yun Tan
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  3. Jian-Qing Tao
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  4. Xiao-Juan Xu
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Correspondence to Jun Wang.

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Wang, J., Tan, CY., Tao, JQ. et al. A Novel Coordination Polymer Based on Cd2O2 Clusters: Synthesis, Structure and Physical Property. J Clust Sci 25, 349–356 (2014). https://doi.org/10.1007/s10876-013-0613-0

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  • DOI: https://doi.org/10.1007/s10876-013-0613-0

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