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Anion-directed assembly of two novel cadmium(II) complexes containing 2,2’-(1,4-propylene)bis(1H-benzimidazole) ligand

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Abstract

Two novel inorganic-organic hybrids, {[Cd(C3BIm)(Bdc)] ∙ H2O}n (I) and {[Cd(C3BIm)(Btc)] ∙ 4H2O} n (II) {H2C3BIm = 2,2′-(1,3-propylene)bis(1H-benzimidazole), H2Bdc = benzene-1,3-dicarboxylic acid, and H3Btc = benzene-1,3,5-tricarboxylic acid}, have been prepared under specific reaction temperature and ratio of reactants. Their characterization included IR, TGA, and single-crystal X-ray diffraction analysis (CIF files CCDC. nos. 801661 (I), 801662 (II)). Both complexes I and II exhibit two-dimensional puckered hexagonal (6,3) sheets structurally, whose 3-connecting nodes are provided by H2C3BIm, H2Bdc, Cd2+ (I) and H2C3BIm, H2Btc, Cd2+ (II), respectively. Furthermore, both compounds show intense luminescence at room temperature.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Baoji University of Arts and Science, Baoji, Shaanxi, 721013, P.R. China

    Y. Wang

  2. School of Chemical Engineering, Northwest University for Nationalities, Lanzhou, 730030, P.R. China

    L. L. An

Authors
  1. Y. Wang
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  2. L. L. An
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Correspondence to Y. Wang.

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Wang, Y., An, L.L. Anion-directed assembly of two novel cadmium(II) complexes containing 2,2’-(1,4-propylene)bis(1H-benzimidazole) ligand. Russ J Coord Chem 42, 502–508 (2016). https://doi.org/10.1134/S1070328416080066

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  • DOI: https://doi.org/10.1134/S1070328416080066

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