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Supramolecular assembly of three d10 metal coordination polymers based on the naphthalene-1,8-dicarboxylate ligand: Syntheses, structures and luminescent properties

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Abstract

Three d10 tetranuclear complexes, [Cd4(1,8-nap)4(2,2′-bipy)4(H2O)8]·6H2O (1,8-nap = naphthalene-1,8-dicarboxylate and 2,2′-bipy = 2,2′-bipyridine) (1), [Cd4(1,8-nap)4(2,2′-bipy)4(H2O)8]·6H2O (2) and [Zn4(1,8-nap)4(2,2′-bipy)4(H2O)4]·2H2O (3), have been synthesized under hydrothermal conditions and characterized by elemental analyses, IR and X-ray diffraction techniques. Complexes 1 and 2 are isomers showing one-dimensional ribbon-like structures connected by O-H…O hydrogen bonds, and the one-dimensional ribbons are further linked into the three-dimensional network by π-π stacking. In complex 3, the intramolecular O-H…O hydrogen bonds just exist in the inner of the single molecule ring to consolidate its structure, and the single molecules are further linked into a two-dimensional layer structure by the π-π stacking interactions. The luminescent properties reveal that all the complexes display luminescent properties in the violet region.

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Authors and Affiliations

  1. Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces; Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, 321004, China

    JunDan Fu, ZhiWei Tang, Xia Feng & YiHang Wen

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  1. JunDan Fu
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  2. ZhiWei Tang
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  3. Xia Feng
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  4. YiHang Wen
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Correspondence to YiHang Wen.

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Fu, J., Tang, Z., Feng, X. et al. Supramolecular assembly of three d10 metal coordination polymers based on the naphthalene-1,8-dicarboxylate ligand: Syntheses, structures and luminescent properties. Sci. China Chem. 53, 1060–1067 (2010). https://doi.org/10.1007/s11426-010-0052-9

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  • DOI: https://doi.org/10.1007/s11426-010-0052-9

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