Abstract
NiFe2O4 and Li2NiFe2O4/NiFe2O4 nanocomposite samples are prepared using citric acid and urea assisted combustion process. The prepared pristine and nanocomposite samples are characterized by using powder X-ray diffraction, Fourier transform infrared spectroscopy (FTIR) and field emission scanning electron microscopy techniques. The effect of Li2NiFe2O4 on the Li2NiFe2O4/NiFe2O4 crystallite size and associated strain is calculated using Williamson–Hall plot. The effect of Li2NiFe2O4 on the electrical and dielectric properties of the composite samples are analyzed using AC-impedance spectroscopy. The prepared composite materials exhibit mixed electrical conduction behavior, and the conduction is due to lithium ion migration as well as electron hopping between Fe2+ and Fe3+ ions in the spinel structure. The conductivity gradually increases and attains maximum upon lithium ion inclusion in the composite. The further increment of lithium ion doping decreases the conductivity.
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Acknowledgements
IP acknowledges SASTRA University for providing research facilities and TRR research grant offered by SASTRA University to do research. Authors also acknowledge Prof. N. Satyanarayana, Department of Physics, Pondicherry University for providing Impedance measurement facilities.
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Balamurugan, S., Manimekalai, S. & Prakash, I. Synthesis, characterization and electrical properties of Li2NiFe2O4/NiFe2O4 nanocomposites. J Mater Sci: Mater Electron 28, 18610–18619 (2017). https://doi.org/10.1007/s10854-017-7810-9
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DOI: https://doi.org/10.1007/s10854-017-7810-9