Abstract
Rose-like ZnO/reduced graphene oxide composites are synthesized by a simple, scalable, and facile route without using any surfactants. The well-defined ZnO microstructure has a hexagonal hierarchical rose-like architecture, which is composed of densely packed uniform thin flakes. The N,N-dimethylformamide/water system employed here acts as an organic solvent as well as a reagent, and two competing reactions give rise to the formation of the hexagonal hierarchical rose-like ZnO architecture. Compared with bare ZnO, the rose-like ZnO/reduced graphene oxide composite displays the fluorescence quenching property. Finally, the as-prepared products possess considerable photocatalytic property under visible light for the degradation of methylene blue.
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Gomez JL, Tigli O (2013) Zinc oxide nanostructures: from growth to application. J Mater Sci 48:612–624. doi:10.1007/s10853-012-6938-5
Sang XJ, Li JS, Chen WL, Wang EB (2012) Polyoxometalate-assisted synthesis of the ZnO polyhedra in an alkali solution and their photoelectrical properties. Mater Lett 87:39–42
Li H, Ni YH, Hong JM (2009) Ultrasound-assisted preparation, characterization and properties of flower-like ZnO microstructures. Scripta Mater 60:524–527
Xu LP, Hu YL, Pelligra C, Chen CH, Jin L, Huang H et al (2009) ZnO with different morphologies synthesized by solvothermal methods for enhanced photocatalytic activity. Chem Mater 21:2875–2885
Zhao GX, Wen T, Chen CL, Wang XK (2012) Synthesis of graphene-based nanomaterials and their application in energy-related and environmental-related areas. RSC Adv 2:9286–9303
Herring NP, Almahoudi SH, Olson CR, El-Shall MS (2012) Enhanced photocatalytic activity of ZnO–graphene nanocomposites prepared by microwave synthesis. J Nanopart Res 14:1277–1282
Luo QP, Yu XY, Lei BX, Chen HY, Kuang DB, Su CY (2012) Reduced graphene Oxide-hierarchical ZnO hollow sphere composites with enhanced photocurrent and photocatalytic activity. J Phys Chem C 116:8111–8117
Lu T, Zhang YP, Li HB, Pan LK, Li YL, Sun Z (2010) Electrochemical behaviors of graphene–ZnO and graphene–SnO2 composite films for supercapacitors. Electrochim Acta 55:4170–4173
Lee JM, Pyun YB, Yi J, Choung JW, Park WI (2009) ZnO nanorod-graphene hybrid architectures for multifunctional conductors. J Phys Chem C 113:19134–19138
Zhou X, Shi TJ, Zhou HO (2012) Hydrothermal preparation of ZnO-reduced graphene oxide hybrid with high performance in photocatalytic degradation. Appl Surf Sci 258:6204–6211
Cote LJ, Kim F, Huang JX (2009) Langmuir-blodgett assembly of graphite oxide single layers. J Am Chem Soc 131:1043–1049
Kumar SV, Huang NM, Yusoff N, Lim HN (2013) High performance magnetically separable graphene/zinc oxide nanocomposite. Mater Lett 93:411–414
Yu XL, Zhang GJ, Cao HB, An XQ, Wang Y, Shu ZJ et al (2012) ZnO@ZnS hollow dumbbells–graphene composites as high-performance photocatalysts and alcohol sensors. New J Chem 36:2593–2598
Hu HT, Wang XB, Liu FM, Wang JC, Xu CH (2011) Rapid microwave-assisted synthesis of graphene nanosheets–zinc sulfide nanocomposites: optical and photocatalytic properties. Synth Met 161:404–410
Fu DY, Han GY, Chang YZ, Dong JH (2012) The synthesis and properties of ZnO–graphene nano hybrid for photodegradation of organic pollutant in water. Mater Chem Phys 132:673–681
Sin JC, Lam SM, Lee KT, Mohamed R (2013) Fabrication of erbium-doped spherical-like ZnO hierarchical nanostructures with enhanced visible light-driven photocatalytic activity. Mater Lett 91:1–4
Son DI, Kwon BW, Park DH, Seo WS, Angadi B, Choi WK et al (2012) Emissive ZnO–graphene quantum dots for white-light-emitting diodes. Nat Nanotechnol 7:465–471
Williams G, Kamat PV (2009) Graphene-semiconductor nanocomposites: excited-state interactions between ZnO nanoparticles and graphene oxide. Langmuir 25:13869–13873
Hu P, Zhang X, Han N, Xiang WC, Cao YB, Yuan FL (2011) Solution-controlled self-assembly of ZnO nanorods into hollow microspheres. Cryst Growth Des 11:1520–1526
Krishnamoorthy K, Mohan R, Kim SJ (2011) Graphene oxide as a photocatalytic material. Appl Phys Lett 98:244101–244103
Li BX, Liu TX, Wang YF, Wang ZF (2012) ZnO/graphene-oxide nanocomposite with remarkably enhanced visible-light-driven photocatalytic performance. J Colloid Interface Sci 377:114–121
Lv T, Pan LK, Liu XJ, Sun Z (2012) Enhanced photocatalytic degradation of methylene blue by ZnO-reduced graphene oxide–carbon nanotube composites synthesized via microwave-assisted reaction. Catal Sci Technol 2:2297–2301
Gao B, Chen GZ, Puma GL (2009) Carbon nanotubes/titanium dioxide (CNTs/TiO2) nanocomposites prepared by conventional and novel surfactant wrapping sol-gol methods exhibiting enhanced photocatalytic activity. Appl Catal B Environ 89:503–509
Zhang H, Lv XJ, Li YM, Wang Y, Li JH (2010) P25–graphene composite as a high performance photocatalyst. ACS Nano 4:380–386
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The support of Sichuan Province through a Key Technologies Research and Development Program of Sichuan Province (2011 gz0110) is acknowledged.
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Gong, Y., Zou, C., Yao, Y. et al. A facile approach to synthesize rose-like ZnO/reduced graphene oxide composite: fluorescence and photocatalytic properties. J Mater Sci 49, 5658–5666 (2014). https://doi.org/10.1007/s10853-014-8284-2
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DOI: https://doi.org/10.1007/s10853-014-8284-2