Abstract
Synthesis, X-ray diffraction, and photoluminescence (PL) investigations of SrZnO2 doped with Eu3+ were carried out in order to characterize the material. The emission spectra showed a broad band emission at 525 nm attributed to oxygen defect centers in the host matrix, along with peaks corresponding to the 5D0 → 7F j (j = 1, 2) transitions of Eu ion under 250 nm excitation. PL decay time studies were done to confirm these investigations. Time-resolved emission spectrometric (TRES) study was carried out to extract the emission spectra of the Eu ion which was buried under the broad band emission. After giving suitable delay times and by choosing a proper time gate, transitions due to 5D0 → 7F j (j = 0, 1, 2, 3, and 4) could be observed. Judd–Ofelt intensity parameters and other radiative properties for the system were evaluated from this emission spectrum and decay time data by adopting standard procedure. The color coordinates of the system were also evaluated and plotted on a standard CIE index diagram. The observations showed that the SrZnO2:Eu3+material has near white light emission (also considering the emission from host) whereas, the extracted emission spectrum due to only Eu ions has a near red emission.
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Blasse G (1989) Chem Mater 1:294
He X-H, Lian N, Sun J-H, Guan M-Y (2009) J Mater Sci 44:4763. doi:10.1007/s10853-009-3668-4
Wang H, Yu J, Li J, Cheng X, Huang Z (2010) J Mater Sci 45:1237. doi:10.1007/s10853-009-4072-9
Shan Z, Chen D, Yu Y, Huang P, Lin H, Wang Y (2010) J Mater Sci 45:2775. doi:10.1007/s10853-010-4266-1
Taikar DR, Joshi CP, Moharil SV, Muthal PL, Dhopte SM (2010) J Lumin 130:1690
Kubota S, Oyama T, Yamane H, Shimada M (2003) Chem Mater 15:3403
He XH, Zhou J, Li WH, Zhou QF (2006) Chin J Inorg Chem 22:1706
He XH, Zhou J, Bi CL, Li WH (2007) J Synth Cryst 36:1408
Khatkar SP, Taxak VB, Kumar D, Han SD, Han CH, Sharma G (2006) J Korean Phys Soc 48:1355
Yu X, Xu X, Zhou P, Peng X, Yang S (2005) Mater Lett 59:1178
Yang L, Yu X, Yang S, Zhou C, Zhou P, Gao W, Ye P (2008) Mater Lett 62:907
Wang Y, Gao H (2006) J Solid State Chem 179:1870
Yu X, Xu X, Zhou C, Tang J, Peng X, Yang S (2006) Mater Res Bull 41:1578
von Schnering HG, Hoppe R (1960) Naturwissenschaften 47:467
von Schnering HG, Hoppe R (1961) Z Anorg Allg Chem 312:87
Chen XY, Liu GK (2005) J Solid State Chem 178:419
Zhang LL, Guo CX, Zhao JJ, Hu JT (2005) Chin Phys Lett 22:1225
Judd BR (1962) Phys Rev 127:750
Ofelt GS (1962) J Chem Phys 37:511
Sarakha L, Forano C, Boutinaud P (2009) Opt Mater 31:562
Liu L, Chen X (2007) Nanotechnol 18:255704
Werts MHV, Jukes RTF, Verhoeven JW (2002) Phys Chem Chem Phys 4:1542
Shipeng W, Xiaoping Z, Shui H, Liqun Z, Li L (2008) J Rare Earths 26:787
Malta OL, Brito HF, Menezes JFS, Goncalves e silva FR, Alves S Jr, Farias FS Jr, De Andrade AVM Jr (1997) J Lumin 75:255
Malta OL, Couto dos Santos MA, Thompson LC, Ito NK (1996) J Lumin 69:77
Larsen ES, Berman H (1934) The microscopic determination of the non-opaque minerals, 2nd edn. U.S. Geological Survey Bulletin, Washington, DC, p 848
Dean JA (ed) (1973) LANGE’s handbook of chemistry, 11th edn, 10.258. McGraw-Hill Book Company, New York
Heidepriem HE, Ehrt D (1996) J Non-Cryst Solids 208:205
Weber MJ, Varitimos TE, Matsinger BH (1973) Phys Rev B 8:47
Carnall WT, Fields PR, Rajnak K (1968) J Chem Phys 49:4450
Kuboniwa S, Hoshina T (1972) J Phys Soc Jpn 32:1059
Carnall WT, Fields PR, Wybourne BG (1965) J Chem Phys 42:3797
Publication CIE No. 7.4 (1987) International Lighting Vocabulary. Central Bureau of the Commission Internationale de L’Éclairage, Vienna, Austria
Publication CIE No. 15.2 (1986) Colorimetry, 2nd edn. Central Bureau of the Commission Internationale de L’Éclairage, Vienna, Austria
Zaccaria S, Casarin M, Speghini A, Ajo D, Bettinelli M (1999) Spectrochim Acta A 55:171
Andresen Ä, Bahar AN, Conradi D, Oprea II, Pankrath R, Voelker U, Betzler K, Wöhlecke M, Caldiño U, Martín E, Jaque D, Solé JG (2008) Phys Rev B 77:214102
Capobianco JA, Proulx PP, Bettinelli M, Negrisolo F (1990) Phys Rev B 42:5936
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Purohit, P.J., Mohapatra, M., Natarajan, V. et al. Synthesis and photoluminescence properties of Eu3+-activated SrZnO2 . J Mater Sci 46, 2030–2035 (2011). https://doi.org/10.1007/s10853-010-5034-y
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DOI: https://doi.org/10.1007/s10853-010-5034-y