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Effect of Ca substitution on microwave dielectric properties of BaV2O6 ceramics

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Abstract

Effects of Ca substitution for Ba on the phase composition, microstructure, sintering behavior and microwave dielectric properties of nominal ceramics Ba1-xCaxV2O6 (0.2 ≤ x ≤ 0.5) were investigated. The XRD, Raman and SEM results revealed that BaV2O6 and CaV2O6 composite ceramics were formed. Nominal ceramics Ba1-xCaxV2O6 could be well densified at about 550 °C via a solid-state reaction method. The microwave dielectric properties exhibited strong dependence on the composition and microstructure. Typically, the Ba0.7Ca0.3V2O6 ceramics sintered at 550 °C exhibited excellent microwave dielectric properties: εr = 10.9, Qxf = 17,100 GHz (at 9.9 GHz), and τf = 4 ppm/°C. Meanwhile, Ba0.7Ca0.3V2O6 ceramics also showed good chemical compatibility with Al electrode. These results indicated that the Ba0.7Ca0.3V2O6 ceramics could be a promising candidate for the ULTCC technology.

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Acknowledgements

This work is supported by the National Natural Science Foundation of China (Grants No. 51402235). China’s Post-doctoral Science Fund (Grant No. 2015 M582696), and by Shaanxi Province Postdoctoral Science Foundation.

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Authors and Affiliations

  1. Institute of Photonics & Photon-Technology, Northwest University, Xi’an, 710069, China

    Guoguang Yao & Zhaoyu Ren

  2. School of Science, Xi’an University of Posts and Telecommunications, Xi’an, 710121, China

    Guoguang Yao

  3. College of Physics and Information Technology, Shaanxi Normal University, Xi’an, 710062, China

    Peng Liu

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  1. Guoguang Yao
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Correspondence to Guoguang Yao.

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Yao, G., Ren, Z. & Liu, P. Effect of Ca substitution on microwave dielectric properties of BaV2O6 ceramics. J Electroceram 40, 144–149 (2018). https://doi.org/10.1007/s10832-018-0113-6

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  • DOI: https://doi.org/10.1007/s10832-018-0113-6

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