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New selective “on-off” fluorescence chemosensor based on carbazole Schiff base for Fe3+ detection

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Chemistry of Heterocyclic Compounds Aims and scope

A new double Schiff base, carbazole, and diaminomaleonitrile-based chemosensor for Fe3+ with high sensitivity and selectivity was designed and synthesized. Addition of only Fe3+ ions induced the fluorescence quenching of the chemosensor in DMF solution. The chemosensor formed a 1:1 complex with Fe3+ with the high binding constant of 7.98·10–6 M–1. The chemosensor displayed low detection limit (3.75·10–8 M) and fast response time (15 s) to Fe3+.

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Acknowledgements

This work was supported by the Research Fund for the Doctoral Program of Higher Education of China (20120043110007).

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130025, P. R. China

    Yi He

  2. Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China

    Jun Yin & Guang Wang

Authors
  1. Yi He
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  2. Jun Yin
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  3. Guang Wang
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Correspondence to Yi He.

Additional information

Supplementary information file containing 1H and 13C NMR, MS, emission, fluorescence and spectrophotometric titration spectra of compound 1 is available at the journal website at http://link.springer.com/journal/10593.

Published in Khimiya Geterotsiklicheskikh Soedinenii, 2018, 54(2), 146–152

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He, Y., Yin, J. & Wang, G. New selective “on-off” fluorescence chemosensor based on carbazole Schiff base for Fe3+ detection. Chem Heterocycl Comp 54, 146–152 (2018). https://doi.org/10.1007/s10593-018-2246-6

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  • DOI: https://doi.org/10.1007/s10593-018-2246-6

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