Abstract
Li-doped high surface area of activated carbon (LHSAC) for Li ion capacitor (LIC) has been prepared by controlling the LiOH amounts for surface modification. The main purpose is the controlling of Li amounts by easy insertion-disinsertion reaction with magnetic field between cathode and anode. The physical properties of the sample were analyzed by the XRD, EIS, SEM, TEM, EDS, and Raman spectroscopy. The surface functional group analysis indicated the final sample had hydrophilic groups or the hydrophilicity that leads to improve the permeability of the electrolyte through the working electrode (WE). The electrochemical activity and the reusability of the xLHSAC were evaluated through a cyclic voltammetry (CV) test under different scan rates (mV/s) and magnetic core treatments (0.07 T and 0.14 T). The CV curves, the profile, and the redox current density of each sample were varied depending on the active sites, the surface, and the ion transfer way of the WE. The prepared working electrodes were stable during long-term recycling experiments, and the electrochemical properties of xLHSAC were significantly increased by magnetic core processing. In addition, the 3LYP80F sample performed better than other samples, which confirms that the material is a promising electrode material for high-performance LIC.
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Acknowledgements
This research was supported by Korea Electrotechnology Research Institute (KERI) Primary research program through the National Research Council of Science & Technology (NST) funded by the Ministry of Science and ICT (MSIT) (No. 22A01001) and the Technology Innovation Program (20016795, Development of manufacturing technology independence of advanced activated carbons and application for high performance supercapacitor) funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea).
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Otgonbayar, Z., Yang, S., Kim, IJ. et al. Magnetic field effect and controlling of Li amounts of cathode material for high performance in LIC. J Solid State Electrochem 26, 2841–2859 (2022). https://doi.org/10.1007/s10008-022-05292-x
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DOI: https://doi.org/10.1007/s10008-022-05292-x