Abstract
A carbon-sulfur cathode was prepared by precipitating a suspension of acetylene black and dissolved sulfur from ethanol. The morphology of the cathode material was investigated using scanning and transmission electron microscopy. The diameter of commercial sulfur particles is between 20 and 50 μm, while this value for the precipitated sulfur was ca. order of magnitude lower (between 2 and 5 μm). Electrochemical properties of Li│S cells were investigated by cyclic voltammetry, galvanostatic discharging, and electrochemical impedance spectroscopy. Galvanostatic discharging curves of the Li│S system may be divided into three regions. At the beginning, the discharging undergoes at an approximately constant voltage (faradaic process) to switch into a pseudocapacitive process (two discharging regions characterized by linearly decreasing voltage). The hybrid discharging faradaic-pseudocapacitive nature implies the description of the total process by two types of capacities: in coulombs (faradaic process) and in farads (pseudocapacitive regions). The calculated experimental specific energy density (free enthalpy change) during the discharging process was ca. 1063 Wh kg−1, approximately twofold higher in comparison with such cathodes as LiFePO4 or LixMn2O4. These results show that the sulfur-carbon precipitated from ethanol can serve as a promising cathode for Li│S primary cells.
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Introduction
The lithium-sulfur Li│S battery is a promising electrochemical system characterized by a high theoretical specific capacity of 1675 mAh g−1 and energy density of 2600 Wh kg−1 [1,2,3]. In addition, sulfur is an attractive material due to its large reserves and low cost. The most stable allotrope of sulfur at room temperature is cyclic octasulfur. It reacts reversibly with metallic lithium:
Despite the many advantages of the abovementioned Li│S cell, there may also be certain disadvantages. The main disadvantage of such a cathode is connected with solubility of long-chain polysulfides formed by the reduction of pure sulfur and/or by oxidation of short chain polysulfides [4]. Another problem is the insulating nature of sulfur. Therefore, additives are needed to increase electronic conductivity of the cathode. Modifications of the Li│S batteries are designed to improve stability of the electrode structure and the utilization of sulfur in the cathode. This may be mostly achieved by a modification of the sulfur-based composite cathode material. Sulfur-carbon composites are attractive because they improve sulfur utility as an active mass and prevent diffusion of polysulfides to the electrolyte solution. Hence, this reduces the phenomenon, which significantly limits the capacity of sulfur cathodes [2, 5]. Such materials as mesoporous carbons [6], carbon nanotubes [7, 8], activated carbons [9], and graphene [10, 11] have been used. Ball-milling or mixing sulfur powder and carbon materials have been used in conventional sulfur electrodes [2]. Sulfur was also injected into the pores of carbon fibers [9] or deposited on multiwalled carbon nanotubes [7, 8]. A carbon cloth/sulfur cathode also demonstrated very good electrochemical performance [12]. The original studies of the lithium-sulfur batteries have been summarized in a number of review papers. Generally, it is assumed that the discharging process is of faradaic nature. [2, 3, 5, 13,14,15,16,17,18,19].
The general aim of the present study was to prepare and characterize a new cathode utilizing precipitated sulfur as an active material.
Experimental
Materials
Elemental sulfur (99.98%, powder, Aldrich), lithium foil (0.75 mm thick, Aldrich), acetylene black (AB, Alfa Aesar), poly(vinylidene fluoride) (PVdF, Fluka), N-methyl-2-pyrrolidinone (NMP, Fluka), ethyl alcohol (99.8%, anhydrous, POCh), and liquid electrolyte 1 M LiPF6 solution in EC + DMC (Aldrich) were used as received. Water was purified with reverse osmosis (conductivity < 1 μS).
Composite carbon/sulfur cathode and counter electrode preparation
Saturated sulfur (2 g) suspension in ethanol (20 g) was stirred for 2 h at 45 °C. After sulfur sedimentation, the transparent colorless solution was decanted. Carbon material was added to the stirred sulfur solution in ethanol. The suspension of carbon material in the sulfur solution was stirred and water was slowly added, which resulted in a gray precipitate. Water + ethanol was initially evaporated at room temperature from the carbon/sulfur precipitate. The precipitate was finally dried at 40 °C for 4 h. The sulfur content in the carbon/sulfur was monitored by weight (weight of the carbon before and after coprecipitation with sulfur). The cathode composite (AB-PS) was mixed with PVdF (10 wt%), and the suspension in NMP was deposited on a gold counter current collector (discs with the surface area of 0.785 cm2). Cathodes deposited on current collectors were dried at 50 °C for 48 h.
Measurements
Cells were assembled in a dry argon atmosphere in a glove box (MBraun, UniLabPlus). A round-shaped lithium anode (surface area of 0.785 m2, Li mass of ca. 40 mg) was cut off from metallic lithium foil. Electrodes were separated by a glass microfiber separator (GF/A, Whatman) soaked with the electrolyte and placed in an adapted 0.5″ Swagelok® connecting tube. The electrochemical characteristic of cathodes was investigated using cyclic voltammetry (CV), galvanostatic discharging tests, and electrochemical impedance spectroscopy (Multichannel System Gamry, USA). Impedance spectra were obtained using a frequency response analyzer at a frequency range of 100 kHz–10 mHz at the open circuit potential and amplitude of 10 mV. After electrochemical measurements, the cells were disassembled and electrodes were washed with DMC and dried in vacuum at room temperature. X-ray diffraction of the composite cathode active material was investigated using Bruker AXS D8 apparatus. The morphology of the carbon/sulfur cathodes (pristine and after electrochemical cycling) was observed under a scanning electron microscope, SEM (Zeiss EVO 40), and TEM (Jeol JEM 1200 EXII, USA).
Results and discussion
Morphology of composite cathode (XRD, TGA, SEM, and TEM)
X-ray diffraction of the composite cathode active material (S + AB) is typical of elemental sulfur due to very low intensity of carbon material (shown in Fig. 1). The deposited composite contained between 80 and 60 wt.% of sulfur, depending on amount of acetylene black suspended in sulfur solution in C2H5OH. Differential thermal analysis is shown in Fig. 2, for a composite containing ca. 60 wt.% of sulfur indicates that the mass loss occurs between 250 and 350 °C (sulfur sublimation). Scanning electron microscopy (SEM) images of the commercial 99.98% powder and precipitated sulfur (PS) are displayed in Figs. 3 and 4, respectively. It can be seen that the diameter of commercial sulfur particles is between 20 and 50 μm, while this value for the precipitated sulfur is ca. one order of magnitude lower (ca. 5 μm). This effect is probably due to a relatively short time of sulfur crystals growth. On the other hand, TEM images (Fig. 5) suggest that small carbon black particles (density of ca. 80–120 g/L) exist in a form of agglomerates of diameter of ca. 50–100 nm.
SEM images of the acetylene black/precipitated sulfur composite cathode (AB-PS-PVdF) are displayed in Fig. 6. The mapping image of the freshly prepared cathode (Fig. 6b) shows uniformly deposited carbon black particles on precipitated sulfur. As it can be observed, freshly prepared AB-PS-PVdF particles are below 2 μm in diameter and they resemble a flake-like morphology (Fig. 6a). However, after discharging (Fig. 6b), the cathode material based on sulfur is converted into polysulfides (AB-(LiS)x-PVdF with 4 < x < 8 [20]) of a different morphology—small flake particle agglomerates.
Cyclic voltammetry
The electrochemical reaction mechanism of the carbon black–precipitated sulfur–PVdF (AB-PS-PVdF) cathode was more clearly revealed using cyclic voltammetry (CV). The CV scan was performed on the AB-PS-PVdF cathode between 1.2 and 2.8 V using 0.1 mV s−1 scan rate (Fig. 7). Typically, for a sulfur cathode, a three-stage redox process has been noticeably observed. In the case of the reduction process, one peak (1) was observed at a higher potential (2.2 V), and it may be related to the open ring reduction of cyclic S8 to the long chain lithium polysulfides, while the a pair of peaks (2 and 3) was observed at a lower potentials (1.6–1.7 V), which corresponds to the reduction process of polysulfides to Li2S2 and Li2S. [21,22,23].
Generally, the potential ranges of peaks are lower than with the classic sulfur electrode. This situation is observed when sulfur is trapped in the structure of the carbon material [8, 12]. A reduction in the size of the peaks in subsequent cycles was observed (not shown in Fig. 7 for the sake of clarity). This is due to the lack of reversibility of the oxidation and reduction process of the sulfur electrode.
Galvanostatic charging and discharging
Figure 8 shows the voltage (∆V) profile of the discharging process of the Li│AB-PS-PVdF system, at a constant current of 10 mA g−1. The curve may be divided into three regions. After the system polarization, the potential drops from ca. 3.2 to ca. 2.5 V and then remains approximately constant (region 1) during ca. 1.2 × 105 s (33.3 h). Due to the constant voltage, this region of the curve suggests a faradaic process of elementary sulfur ring opening and further reduction to lithium polysulfides [13] (this process may also be seen at the cyclic voltammetry curves, Fig. 7, reduction peak 1). Then the potential constantly drops (regions 2 and 3), indicating the pseudocapacitive nature of subsequent processes (which can also be seen in the voltammetry curves—peaks 2 and 3). These regions of the discharging curve (regions 2 and 3) reflect reduction of polysulfides [13].
Capacity determination: classical approach
Usually, galvanostatic discharging curves are plotted as the dependence of the voltage on capacity. A point of intersection of the plot with a cutoff voltage is accepted as a capacity of the system. The value of cutoff voltage, which can be found in the literature for Li│S systems, varies between 1.8 and 0.8 V [13, 17, 20, 24,25,26,27,28,29]. In the present work, the voltage drop starts at ca. 1.2 V, which leads to the capacity value of ca. 1100 Wh kg−1. However, it is difficult to calculate energy (work) delivered during discharging process due to voltage changes. In addition, charging of the discharged cathode led to very low capacity values (of ca. 100–150 Wh kg−1) indicating their practical irreversibility.
Delivered energy determination—hybrid faradaic/pseudocapacitive approach
Capacity q of the faradaic, process which takes place in region 1, may be approximated by the product of constant current I and time t:
Hence, according to Fig. 5: q1 = 10 mA g−1 × 33.3 h = 330 mAh g−1 = 1188 C g−1.
The capacity of the system in the pseudocapacitive regions cannot be expressed in coulombs (or Ah) but rather in farads and calculated from the equation valid for capacitors, taking into account the slope of discharging curves dVi/dt:
The slope of the curve in region 2 is 7.44 × 10−6 V s−1 with voltage difference of ∆V = 2.5 V − 1.6 V = 0.9 V, while in region 3, dV/dt = 2.54 × 10−6 V s−1 with ∆V = 1.6 V − 1.2 V = 0.4 V. This leads to specific capacities C2 = 1344 F and C3 = 3937 F. However, a capacitance comparison of Li-ion systems working at constant or linearly changing voltage is impossible. Instead, the energy ∆E delivered (electric work Wel done by the system during discharging or free enthalpy change) in regions 1–3 can be calculated as ∆E = Wel = ΣWi. The faradaic process in region 1 leads to the following energy (free enthalpy) change:
while in pseudocapacitive regions 2 and 3, it is described by the following equation (adopted from the classical capacitors theory):
The energy change in regions 1, 2, and 3 is ∆E1 = 1188 C g−1 × 2.5 V = 2970 J g−1, ∆E2 = (1344 F g−1 × 0.92 V2)/2 = 544 Jg−1, and ∆E3 = (3937 F g−1 × 0.42 V2)/2 = 314 J g−1, respectively. Consequently, the electric work done by the system during the discharging process equals a value of W = 3828 J g−1 = 1063 Wh kg−1. This value is ca. twofold higher in comparison with the corresponding values characteristic of such cathode materials as LiFePO4 (q = 170 mAh g−1, ∆V = 3.5 V, and ∆E = 2142 J g−1) or LixMn2O4 (q = 150 mAh g−1, ∆V = 3.6 V, and ∆E = 1944 J g−1). However, theoretical energy density calculated according to the reduction of elemental sulfur to lithium sulfide is as high as 9360 J g−1 (2600 kWh kg−1 [13]). Much lower energy density observed in experimental systems is mainly due to dissolution of lithium polysulfides and their possible diffusion to lithium anode [12, 13]. On the other hand, energy density of cathode based on commercial sulfur was only 1140 J g−1 (calculated according to Eq. (5)).
Impedance spectroscopy (EIS)
Figure 9 shows the impedance spectrum of a pristine sulfur electrode after its assembling (Li│S cell) and after discharging. It can be seen that both curves consist of a semicircle and a straight line at lower frequencies. EIS curves were deconvoluted according to the Randles equivalent circuit, consisting of series resistance Rs, charge transfer resistance Rct (in series), and a constant phase element CPE in parallel to Rct and the Warburg diffusion element. The ohmic resistance of the fresh cathode was 3.7 Ω, while after discharging, it increased to a comparable value of ca. 4.0 Ω. This indicates that the system series resistance is low and stable (with the geometric surface area of the cathode below of 1 cm2). The charge transfer resistance of the Li│S system was ca. 100 Ω, while after discharging (Li│Li2S) somewhat higher: 178 Ω.
Conclusions
These results show that sulfur-carbon precipitated from ethanol can serve as a promising cathode for Li│S primary cells. The diameter of commercial sulfur particles is between 20 and 50 μm, while this value for the precipitated sulfur is ca. one order of magnitude lower (between ca. 2 and 5 μm). Galvanostatic discharging curves of the Li│S system may be divided into three regions. At the beginning, the discharging undergoes at an approximately constant voltage (faradaic process) to switch into a pseudocapacitive process (two discharging regions characterized by linearly decreasing voltage). The hybrid discharging faradaic-pseudocapacitive nature implies the description of the total process by two types of capacities: in coulombs (faradaic) and in farads (pseudocapacitive regions). The calculated specific energy density (free enthalpy change) during the discharging process) was 1063 Wh kg−1 (3800 J g−1).
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This work was supported by the Polish Ministry of Science and Higher Education, grant 03/31/ 0377.
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Swiderska-Mocek, A., Rudnicka, E. & Lewandowski, A. Precipitated sulfur cathode—a hybrid faradaic and pseudocapacitive discharging process. J Solid State Electrochem 24, 1157–1164 (2020). https://doi.org/10.1007/s10008-020-04610-5
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DOI: https://doi.org/10.1007/s10008-020-04610-5