Abstract
TiO2 nanotubes were fabricated from TiF4 precursors within the pore channels of the linen fiber templates, resulting in crystalline fabricated titanate nanotubes (f-TNTs) upon removal by calcination at 500–600 °C. The f-TNTs were formed by the aggregation of TiO2 nanoparticles (NPs) with a diameter of 80 nm; the wall thickness and size of the f-TNTs can be controlled by adjusting the concentration of the TiF4 precursor, time, temperature, and the size of the linen fibers respectively. After that, palladium (Pd(0)) NPs were coated on the surface of the f-TNTs (Pd/f-TNTs) by the chemical reduction method, using NaBH4 as a reducing agent. The size of the Pd(0) NPs is about 10–13 nm. The Pd/f-TNT nanocomposite is systematically characterized by X-ray diffraction, high-resolution transmission electron microscopy, and field emission scanning electron microscopy. The Pd/f-TNT nanocomposite-modified glassy carbon electrodes exhibited excellent electrocatalytic activity as well as amperometric determination of hydrazine, ascorbic acid, and dopamine; these electrochemical applications were carried out by cyclic voltammetry.
Similar content being viewed by others
References
Golabi SM, Zare HR (1999) J Electroanal Chem 465:168–176
Vernot EH, MacEwen JD, Bruner RH, Haus CC, Kinkead ER (1985) Fundam Appl Toxicol 5:1050–1064
Arrigoni RO, Tullio CD (2002) Biochem Biophys Acta 1:1569–1578
O’Neill RD (1994) Analyst 119:767–779
Goyal RN, Kaur D, Pandey AK (2010) Chem Biomed Methods J 3:115–122
Perez RT, Martinez LC, Tomas V, Fenol J (2001) Analyst 126:1436–1439
Roe JH (1961) J Biol Chem 236:1611–1613
Farajzadeh MA, Nagizadeh S (2003) J Anal Chem 58:927–932
Yebra MC, Cespon RM, Moreno CA (2001) Anal Chim Acta 448:157–164
Emadi KP, Verjee Z, Levin AV, Adeli K (2005) Clin Biochem 38:450–456
Silva FO (2005) Food Control 16:55–58
Onelli E, Mosca A (1994) Life Chem Rep 110:189–198
Thiagarajan S, Tsai TH, Chen SM (2009) Biosens Bioelectron 24:2712–2715
Strohm H, Lobmann P (2004) J Mater Chem 14:2667–2673
Zhang J, Wang S, Wang Y, Zhu B, Xia H, Guo X, Zhang S, Huang W, Wu S (2009) Sensors Actuators B 135:610–617
Jun Z, Shurong W, Yan W, Mijuan X, Huijuan X, Shoumin Z, Weiping H, Xianzhi G, Shihua W (2009) Sensors Actuators B 139:411–417
Wu HQ, Wei XW, Shao MW, Gu JS, Qu MZ (2002) Chemical Phys Lett 364:152–156
Satishkumar BC, Govindaraj A, Vogl EM, Basumallick L, Rao CNR (1997) J Mater Res 12:604–606
Hiroaki I, Manabu M, Kazuhiko S, Hiroshi H (2000) J Mater Chem 10:2005–2006
Hiroaki I, Yuko T, Kazuhiko S, Manabu M (1999) J Mater Chem 9:2971–2972
Chen J, Xia N, Zhou T, Tan S, Jiang F, Yuan D (2009) Int J Electrochem Sci 4:1063–1073
Laura TM, Lapkina AA, Bavykin DV, Walsh FC, Wilson K (2007) J Catal 245:272–278
Bavykin DV, Walsh FC (2009) Eur J Inorg Chem 8:977–997
Bavykin DV, Friedrich JM, Walsh FC (2006) Adv Mater 18:2807–2824
Qingfeng Y, Wenqiang Y (2009) Microchim Acta 165:381–386
Yu J, Liu W, Yu H (2008) Crystal Growth Des 8:930–934
Ibusuki T, Takeuchi K (1994) J Mol Catal 88:93–102
Hagfeldt A, Graetzel M (1995) Chem Rev 95:49–68
Chu SZ (2007) Electrochim Acta 53:92–99
Mmuriciano LT, Lapkin A (2007) J Catal 245:272–278
Lee CR, Lee HK, Lee JS, Cairns EJ (2001) J Power Sources 102:172–177
Qingfeng Y, Wengiang Y, Gang ZX (2009) Micro Chim Acta 165:381–386
Wang YZ, Gang ZX (2004) Electrochim Acta 49:1957–1962
Jing B, Bin Q (2009) Microporous Mesoprous Mater 119:193–199
Bao SJ, Li CM, Zang JF, Cui XQ, Qiao Y, Guo J (2008) Adv Funct Mater 18:591–599
Wang M, Guo DJ, Li H (2005) J Solid State Chem 178:1996–2000
Li G, Gray KA (2007) Chem Phys 339:173–187
Diculescu VC, Chiorcea-Paquim AM, Corduneanu O, Oliveira-Brett AM (2007) J Solid State Electrochem 11:887–898
Lukaszewski M, Kedra T, Czerwinski A (2009) Electrochem Commun 11:978–982
Lukaszewski M, Czerwinski A (2003) Electrochim Acta 48:2435–2445
Luo H, Park S, Yeung H, Chan H, Weaver MJ (2000) J Phys Chem B 104:8250–8258
Safavi A, Maleki N, Tajabadi F, Farjami E (2007) Electrochem Commun 9:1963–1968
Bard AJ (1963) Anal Chem 35:1602–1607
Guo DJ, Li HL (2005) J Colloid Interf Sci 286:274–279
Sathish R, Kumara Swamy BE, Chandra U, Sherigara BS (2010) Int J Electrochem Sci 5:10–17
Colleran JJ, Bresli CB (2012) J Electroanal Chem 667:30–37
Liu A, Wei M, Honma I, Zhou H (2006) Adv Funct Mater 16:371–376
Rajendra NG, Davinder K, Ashish KP (2010) Chem Biomed Methods J 3:115–122
Acknowledgments
This work was financially supported by the Council of Scientific and Industrial Research (CSIR) in New Delhi, India. The FESEM and HRTEM facilities were provided by the National Centre for Nanoscience and Nanotechnology, University of Madras, Chennai, Tamil Nadu, India.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Alexander, M., Pandian, K. Linen fiber template-assisted preparation of TiO2 nanotubes: palladium nanoparticle coating and electrochemical applications. J Solid State Electrochem 17, 1117–1125 (2013). https://doi.org/10.1007/s10008-012-1981-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-012-1981-3