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An efficient selective oxidation of alcohols with iron zirconium phosphate under solvent-free conditions

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Abstract

Iron zirconium phosphate nanoparticles have been used as an efficient catalyst for the selective oxidation of a wide range of alcohols to their corresponding ketones or aldehydes using H2O2 as an oxidizing agent without any organic solvent or additive. The steric factors associated with the substrates had a significant influence on the reaction conditions. The results showed that this method can be applied for chemoselective oxidation of benzyl alcohols in the presence of aliphatic alcohols. The catalyst used in the current study was characterized by ICP-OES, XRD, N2 adsorption–desorption, NH3-TPD, Py-FTIR, SEM, and TEM.

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References

  1. Gan H, Zhao X, Song B, Guo L, Zhang R, Chen C, Chen J, Zhu W, Hou Z (2014) Chin J Catal 35:1148

    Article  CAS  Google Scholar 

  2. Sun L, Boo WJ, Sue HJ, Clearfield A (2007) New J Chem 31:39

    Article  CAS  Google Scholar 

  3. Hajipour AR, Karimi H (2014) Mater Lett 116:356

    Article  CAS  Google Scholar 

  4. Sun Z, Liu Z, Xu L, Yang Y, He Y (2004) Stud Surf Sci Catal 154:1060

    Article  Google Scholar 

  5. Shi QS, Tan SZ, Ouyang YS, Yang QH, Chen AM, Li WR, Shu XL, Feng J, Feng J, Chen YB (2011) Adv Mater Res 150:852

    Google Scholar 

  6. Khare S, Chokhare R (2012) J Mol Catal A: Chem 353–354:138

    Article  Google Scholar 

  7. Wang Q, Yu J, Liu J, Guo Z, Umar A, Sun L (2013) Sci Adv Mater 5:469

    Article  CAS  Google Scholar 

  8. Clearfield A, Kalnins JM (1978) J Inorg Nucl Chem 40:1933

    Article  CAS  Google Scholar 

  9. Gawande M, Deshpande S, Sonavane S, Jayaram R (2005) J Mol Catal A: Chem 241:151

    Article  CAS  Google Scholar 

  10. Khare S, Chokhare R (2011) J Mol Catal A: Chem 344:83

    CAS  Google Scholar 

  11. Giannoccaro P, Gargano M, Fanizzi A, Ferragina C, Aresta M (2005) Appl Catal A 284:77

    Article  CAS  Google Scholar 

  12. Cai X, Dai G-J, Tan S-Z, Ouyang Y, Ouyang Y-S, Shi Q-S (2012) Mater Lett 67:199

    Article  CAS  Google Scholar 

  13. Yang Y, Dai G, Tan S, Liu Y, Shi Q, Ouyang Y (2011) J Rare Earths 29:308

    Article  CAS  Google Scholar 

  14. Dai G, Yu A, Cai X, Shi Q, Ouyang Y, Tan S (2012) J Rare Earths 30:820

    Article  CAS  Google Scholar 

  15. Zhang QR, Du W, Pan BC, Pan BJ, Zhang WM, Zhang QJ, Xu ZW, Zhang QX (2008) J Hazard Mater 152:469

    Article  CAS  Google Scholar 

  16. Costantino U, Szirtes L, Kuzmann E, Megyeri J, Lázár K (2001) Solid State Ionics 141–142:359

    Article  Google Scholar 

  17. Gobechiya ER, Kabalov YK, Orlova AI, Trubach IG, Bykov DM, Kurazhkovskaya VS (2004) Crystallogr Rep 49:390

    Article  CAS  Google Scholar 

  18. Wang XY, Hua WM, Yue YH, Gao Z (2013) Chem J Chin Univ 34:1913

    CAS  Google Scholar 

  19. Barhon Z, Saffaj N, Albizane A, Azzi M, Mamouni R, El Haddad M (2012) J Mater Environ Sci 3:879

    CAS  Google Scholar 

  20. Pylinina A, Mikhalenko I (2013) Russ J Phys Chem 87:372

    Article  CAS  Google Scholar 

  21. Pylinina A, Mikhalenko I (2011) Russ J Phys Chem 85:2109

    Article  CAS  Google Scholar 

  22. Hajipour A, Karimi H, Karimzadeh M (2014) Monatsh Chem 145:1461

    Article  CAS  Google Scholar 

  23. Hajipour AR, Karimi H (2014) Chin J Catal 35:1529

    Article  CAS  Google Scholar 

  24. Hajipour AR, Karimi H (2014) Chin J Catal 35:1982

    Article  CAS  Google Scholar 

  25. Ahmad JU, Räisänen MT, Leskelä M, Repo T (2012) Appl Catal A 411–412:180

    Article  Google Scholar 

  26. Hu Z, Kerton FM (2012) Appl Catal A 413–414:332

    Article  Google Scholar 

  27. Wang P, Cai J, Yang J, Sun C, Li L, Hu H, Ji M (2013) Tetrahedron Lett 54:533

    Article  CAS  Google Scholar 

  28. Hosseinzadeh R, Tajbakhsh M, Khaledi H (2008) J Chin Chem Soc 55:239

    Article  CAS  Google Scholar 

  29. Rao PSN, Rao KTV, Sai Prasad PS, Lingaiah N (2011) Chin J Catal 32:1719

  30. Liu L, Ji LY, Wei YY (2008) Monatsh Chem 139:901

    Article  CAS  Google Scholar 

  31. Ali SR, Chandra P, Latwal M, Jain SK, Bansal VK, Singh SP (2011) Chin J Catal 32:1844

    Article  CAS  Google Scholar 

  32. Zhang H, Liu Y, Zhang X (2011) Chin J Catal 32:1693

    Article  CAS  Google Scholar 

  33. Zhang H, Fu L, Zhong H (2013) Chin J Catal 34:1848

    Article  CAS  Google Scholar 

  34. Zhou X, Ji H (2012) Chin J Catal 33:1906

    Article  CAS  Google Scholar 

  35. Atashin H, Malakooti R (2014) J Chin Chem Soc 61:1039

    Article  CAS  Google Scholar 

  36. Su H, Yang C (2014) Chin J Catal 35:1224

    Article  CAS  Google Scholar 

  37. Zou X, Goswami A, Asefa T (2013) J Am Chem Soc 135:17242

    Article  CAS  Google Scholar 

  38. Zhou C, Liu Y (2010) Chin J Catal 31:656

    CAS  Google Scholar 

  39. Mahdavi V, Hasheminasab HR, Abdollahi S (2010) J Chin Chem Soc 57:189

    Article  CAS  Google Scholar 

  40. Villa A, E-chan-thaw C, Schiavoni M, Campisi S, Wang D, Prati L (2014) Chin J Catal 35:945

    Article  CAS  Google Scholar 

  41. Ghorbani-Vaghei R, Veisi H, Amiri M (2007) J Chin Chem Soc 54:1257

    Article  CAS  Google Scholar 

  42. Ma L, Jia L, Guo X, Xiang L (2014) Chin J Catal 35:108

    Article  CAS  Google Scholar 

  43. Azarifar D, Najminejad Z, Khosravi K (2013) J Iran Chem Soc 10:979

    Article  CAS  Google Scholar 

  44. Chatel G, Monnier C, Kardos N, Voiron C, Andrioletti B, Draye M (2014) Appl Catal A 478:157

    Article  CAS  Google Scholar 

  45. Rahimi R, Ghoreishi SZ, Dekamin MG (2012) Monatsh Chem 143:1031

    Article  CAS  Google Scholar 

  46. Shaabani A, Farhangi E, Rahmati A (2008) Monatsh Chem 139:905

    Article  CAS  Google Scholar 

  47. Khazaei A, Raiatzadeh A, Rostami A (2007) J Chin Chem Soc 54:465

    Article  CAS  Google Scholar 

  48. Karimi B, Rostami FB, Khorasani M, Elhamifar D, Vali H (2014) Tetrahedron 6114

  49. Liu X, Xia Q, Zhang Y, Chen C, Chen W (2013) J Org Chem 78:8531

    Article  CAS  Google Scholar 

  50. Babu SG, Priyadarsini PA, Karvembu R (2011) Appl Catal A 392:218

    Article  CAS  Google Scholar 

  51. Mirjalili BF, Zolfigol MA, Bamoniri A, Zarei A (2004) J Chin Chem Soc 51:509

    Article  CAS  Google Scholar 

  52. Chen C, Liu B, Chen W (2013) Synthesis 45:3387

    Article  CAS  Google Scholar 

  53. Mojtahedi MM, Saidi MR, Bolourtchian M, Shirzi JS (2001) Monatsh Chem 132:655

    Article  CAS  Google Scholar 

  54. Ali Zolfigol M, Hajjami M, Ghorbani-Choghamarani A (2012) J Iran Chem Soc 9:13

  55. Zhu J, Wang PC, Lu M (2014) Appl Catal A 477:125

    Article  CAS  Google Scholar 

  56. Bekhradnia AR, Zahir F, Arshadi S (2008) Monatsh Chem 139:521

    Article  CAS  Google Scholar 

  57. Rautiainen S, Simakova O, Guo H, Leino AR, Kordás K, Murzin D, Leskelä M, Repo T (2014) Appl Catal A 485:202

    Article  CAS  Google Scholar 

  58. Pathan S, Patel A (2013) Appl Catal A 459:59

    Article  CAS  Google Scholar 

  59. Bahramian B, Mirkhani V, Moghadam M, Amin AH (2006) Appl Catal A 315:52

    Article  CAS  Google Scholar 

  60. Özgün B, Yaylaoglu A, Şendil K (2007) Monatsh Chem 138:161

    Article  Google Scholar 

  61. Lou JD, Gao CL, Li L, Fang ZG (2006) Monatsh Chem 137:1071

    Article  CAS  Google Scholar 

  62. Moriyama K, Takemura M, Togo H (2014) J Org Chem 79:6094

    Article  CAS  Google Scholar 

  63. Ghorbani-Choghamarani A, Azadi G (2011) J Iran Chem Soc 8:1082

    Article  CAS  Google Scholar 

  64. Zhu C, Ji L, Wei Y (2010) Monatsh Chem 141:327

    Article  CAS  Google Scholar 

  65. Lou J-D, Zhu L-Y, Wang L-Z (2004) Monatsh Chem 135:31

    Article  CAS  Google Scholar 

  66. Laila A (2013) Monatsh Chem 144:307

    Article  CAS  Google Scholar 

  67. Liu L, Liu D, Xia Z, Gao J, Zhang T, Ma J, Zhang D, Tong Z (2013) Monatsh Chem 144:251

    Article  CAS  Google Scholar 

  68. Tajbakhsh M, Ghaemi M, Sarabi S, Ghassemzadeh M, Heravi MM (2000) Monatsh Chem 131:1213

    Article  CAS  Google Scholar 

  69. Geißlmeir D, Jary WG, Falk H (2005) Monatsh Chem 136:1591

    Article  Google Scholar 

  70. Bugarcěić Z, Novokmet S, Senić Z, Bugarcěić Z (2000) Monatsh Chem 131:799

    Article  Google Scholar 

  71. Heravi MM, Kiakoojori R, Mirza-Aghayan M, Tabar-Hydar K, Bolourtchian M (1999) Monatsh Chem 130:481

    CAS  Google Scholar 

  72. Zhu J, Wang PC, Lu M (2013) Monatsh Chem 144:1671

    Article  CAS  Google Scholar 

  73. Hajipour AR, Karimi H (2014) Appl Catal A 482:99

    Article  CAS  Google Scholar 

  74. Hajipour AR, Karimi H (2014) Chin J Catal 35:1136

    Article  CAS  Google Scholar 

  75. Bingham PA, Hannant OM, Reeves-Mclaren N, Stennett MC, Hand RJ (2014) J Non-Cryst Solids 387:47

    Article  CAS  Google Scholar 

  76. Pandit AA, Shitre AR, Shengule DR, Jadhav KM (2005) J Mater Sci 40:423

    Article  CAS  Google Scholar 

  77. Sing KS (1985) Pure Appl Chem 57:603

    Article  CAS  Google Scholar 

  78. Corma A (1995) Chem Rev 95:559

    Article  CAS  Google Scholar 

  79. Tyagi B, Chudasama CD, Jasra RV (2006) Appl Clay Sci 31:16

    Article  CAS  Google Scholar 

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Acknowledgments

We gratefully acknowledge the funding support received for this project from the Isfahan University of Technology (IUT), IR, Iran.

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Authors and Affiliations

  1. Department of Neuroscience, Medical School, Madison, University of Wisconsin, Madison, WI, 53706-1532, USA

    Abdol Reza Hajipour

  2. Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan, IR, Iran

    Abdol Reza Hajipour, Hirbod Karimi & Amir Masti

Authors
  1. Abdol Reza Hajipour
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  2. Hirbod Karimi
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  3. Amir Masti
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Correspondence to Abdol Reza Hajipour.

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Hajipour, A.R., Karimi, H. & Masti, A. An efficient selective oxidation of alcohols with iron zirconium phosphate under solvent-free conditions. Monatsh Chem 147, 413–423 (2016). https://doi.org/10.1007/s00706-015-1499-3

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  • DOI: https://doi.org/10.1007/s00706-015-1499-3

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