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Selective oxidation of organic compounds using pyridinium-1-sulfonate fluorochromate, C5H5NSO3H [CrO3F] (PSFC)

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Abstract

Efficient selective oxidation of primary, secondary, and benzylic alcohols to the corresponding carbonyl compounds by a new chromium oxidizing reagent, pyridinium-1-sulfonate fluorochromate, C5H5NSO3H [CrO3F] (PSFC) is reported. Various cholesterol derivatives were easily converted to related oxocholesterol from allylic oxidation at lower temperature in comparison to other general oxidants. This oxidation procedure is simple and affords good yields.

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Authors and Affiliations

  1. Department of Medicinal Chemistry, Mazandaran University of Medical Sciences, Sari, Mazandaran, Iran

    Ahmad R. Bekhradnia & Forohe Zahir

  2. Department of Chemistry, University of Payame Noor, Behshahr, Iran

    Sattar Arshadi

Authors
  1. Ahmad R. Bekhradnia
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  2. Forohe Zahir
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  3. Sattar Arshadi
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Corresponding author

Correspondence to Ahmad R. Bekhradnia.

Additional information

Correspondence: Ahmad R. Bekhradnia, Department of Medicinal Chemistry, Mazandaran University of Medical Sciences, Sari, Mazandaran, Iran.

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Bekhradnia, A., Zahir, F. & Arshadi, S. Selective oxidation of organic compounds using pyridinium-1-sulfonate fluorochromate, C5H5NSO3H [CrO3F] (PSFC). Monatsh Chem 139, 521–523 (2008). https://doi.org/10.1007/s00706-007-0720-4

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  • DOI: https://doi.org/10.1007/s00706-007-0720-4

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