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Experimental and theoretical study on the interaction of the pyridinium cation with a hexaarylbenzene-based receptor

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Abstract

Extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements were used to determine the stability constant of a hexaarylbenzene-based receptor/pyridinium complex dissolved in nitrobenzene saturated with water. Further, applying quantum mechanical calculations, the most probable structure of this “asymmetrical” cationic complex was derived.

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Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society”, and by the Czech Ministry of Education, Youth, and Sports (Project MSM 6046137307). The authors of this study thank Dr. Petr Toman from Prague for some theoretical calculations. Finally, R.R. thanks the National Science Foundation for financial support.

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Czech Republic

    Emanuel Makrlík

  2. Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Czech Republic

    Petr Vaňura

  3. Department of Chemistry, Marquette University, Milwaukee, WI, USA

    Rajendra Rathore

Authors
  1. Emanuel Makrlík
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  2. Petr Vaňura
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  3. Rajendra Rathore
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Correspondence to Emanuel Makrlík.

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Makrlík, E., Vaňura, P. & Rathore, R. Experimental and theoretical study on the interaction of the pyridinium cation with a hexaarylbenzene-based receptor. Monatsh Chem 146, 521–525 (2015). https://doi.org/10.1007/s00706-014-1370-y

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  • DOI: https://doi.org/10.1007/s00706-014-1370-y

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