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A combined experimental and theoretical study on the complexation of the ammonium cation with valinomycin

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Abstract

From extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, the stability constant of the valinomycin–ammonium complex in nitrobenzene saturated with water was determined. Further, the structure of the resulting complex was derived by means of density functional theory (DFT) calculations.

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Acknowledgments

The present work was supported by the Academy of Sciences of the Czech Republic (project T 400500402) and by the Czech Ministry of Education, Youth, and Sports (projects MSM 4977751303 and MSM 6046137307).

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Authors and Affiliations

  1. Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic

    Emanuel Makrlík

  2. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Jiří Dybal

  3. Faculty of Chemical Engineering, Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Czech Republic

    Petr Vaňura

Authors
  1. Emanuel Makrlík
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  2. Jiří Dybal
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  3. Petr Vaňura
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Correspondence to Emanuel Makrlík.

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Makrlík, E., Dybal, J. & Vaňura, P. A combined experimental and theoretical study on the complexation of the ammonium cation with valinomycin. Monatsh Chem 141, 1191–1194 (2010). https://doi.org/10.1007/s00706-010-0395-0

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  • DOI: https://doi.org/10.1007/s00706-010-0395-0

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