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A combined experimental and theoretical study on the complexation of Li+ with valinomycin

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Abstract

From extraction experiments in the two-phase water–nitrobenzene system and γ-activity measurements, the stability constant of the valinomycin–lithium complex in nitrobenzene saturated with water was determined. Further, the structure of the resulting complex was indicated by means of the density functional level of theory (DFT) calculations.

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Acknowledgments

The present work was supported by the Czech Ministry of Education, Youth and Sports, projects MSM 4977751303 and MSM 6076137307, and the Academy of Sciences of the Czech Republic, project T400500402.

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Authors and Affiliations

  1. Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic

    Emanuel Makrlík

  2. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Jiří Dybal

  3. Institute of Chemical Technology, Prague, Czech Republic

    Petr Vaňura

Authors
  1. Emanuel Makrlík
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  2. Jiří Dybal
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  3. Petr Vaňura
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Correspondence to Emanuel Makrlík.

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Makrlík, E., Dybal, J. & Vaňura, P. A combined experimental and theoretical study on the complexation of Li+ with valinomycin. Monatsh Chem 140, 251–254 (2009). https://doi.org/10.1007/s00706-008-0003-8

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  • DOI: https://doi.org/10.1007/s00706-008-0003-8

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