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Complexation of Li+ with antamanide: an experimental and theoretical study

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Abstract

From extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, we determined the stability constant of the antamanide—Li+ cationic complex dissolved in nitrobenzene saturated with water. By using quantum mechanical calculations, the most probable structure of this complex species was derived.

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Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society”, and by the Czech Ministry of Education, Youth, and Sports (Project MSM 6046137307).

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Czech Republic

    Emanuel Makrlík

  2. Institute of Chemical Technology, Prague, Czech Republic

    Stanislav Böhm & Petr Vaňura

  3. Institute of Biomolecular Chemistry of CNR, Padua Unit, Padua, Italy

    Paolo Ruzza

Authors
  1. Emanuel Makrlík
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  2. Stanislav Böhm
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  3. Petr Vaňura
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  4. Paolo Ruzza
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Correspondence to Emanuel Makrlík.

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Makrlík, E., Böhm, S., Vaňura, P. et al. Complexation of Li+ with antamanide: an experimental and theoretical study. Monatsh Chem 145, 1051–1054 (2014). https://doi.org/10.1007/s00706-014-1165-1

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  • DOI: https://doi.org/10.1007/s00706-014-1165-1

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