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Complexation of the thallium cation with dibenzo-30-crown-10: extraction and theoretical study

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Abstract

From extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, we determined the stability constant of the dibenzo-30-crown-10·Tl+ complex species dissolved in nitrobenzene saturated with water. By using quantum–mechanical calculations, we then predicted the most probable structure of this complex species.

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Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society”, by the Czech Ministry of Education, Youth, and Sports (Project MSM 6046137307), and by the Czech Science Foundation (Project P 205/10/2280). The computer time at the Meta Centrum (Project LM 2010005), as well as at the Institute of Physics (computer Luna/Apollo), Academy of Sciences of the Czech Republic, is gratefully acknowledged.

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Czech Republic

    Emanuel Makrlík

  2. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Petr Toman

  3. Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Czech Republic

    Petr Vaňura

Authors
  1. Emanuel Makrlík
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  2. Petr Toman
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  3. Petr Vaňura
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Corresponding author

Correspondence to Emanuel Makrlík.

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Makrlík, E., Toman, P. & Vaňura, P. Complexation of the thallium cation with dibenzo-30-crown-10: extraction and theoretical study. Monatsh Chem 144, 919–923 (2013). https://doi.org/10.1007/s00706-013-0953-3

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  • DOI: https://doi.org/10.1007/s00706-013-0953-3

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