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Chemical characterization of Cretan clays for the design of restoration mortars

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Abstract.

Three clays and a marly-limestone from the West of Chania, Crete, fired at temperatures ranging from 200 to 1200 °C, were characterized by XRD, FTIR, EDXRF and wet chemical analyses. The aim of this study was to assess the pozzolanic and hydraulic properties of these materials for potential use as binders in the design of restoration mortars. The mineralogical composition of the clays is quartz, illite, calcite, plagioclase, kaolinite and hematite. The identification of larnite and gehlenite in the calcined marly-limestone established it as potential cementious binder. Among the clays, one with low amount of calcite and considerable kaolinite content exhibited the best pozzolanic activity upon heating at 600 °C. Therefore, it can be considered as an appropriate material for restoration purposes. It is deduced that the pozzolanic activity of fired clays is greatly dependent on the firing temperature and is enhanced in clays containing low calcite and high kaolinite amounts.

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References

  • A H P Maurenbrecher (2004) ArticleTitleMortars for repair of masonry Pract Period Struct Des Constr 9 62 Occurrence Handle10.1061/(ASCE)1084-0680(2004)9:2(62)

    Article  Google Scholar 

  • G Lynch (1994) Brickwork, history, technology and practice Donhead Publishing Ltd. London

    Google Scholar 

  • A D Cowper (2000) Lime and lime mortars Donhead Publishing Ltd. Dorset

    Google Scholar 

  • F M Lea (1940) ArticleTitleInvestigation on pozzolans: technical paper Build Res 27 1

    Google Scholar 

  • B B Sabir S Wild J Bai (2001) ArticleTitleMetakaolin and calcined clays as pozzolans for concrete: a review Cem Concr Compos 23 441 Occurrence Handle10.1016/S0958-9465(00)00092-5 Occurrence Handle1:CAS:528:DC%2BD3MXmt1yisLc%3D

    Article  CAS  Google Scholar 

  • J Konta (1995) ArticleTitleClay and man: clay raw materials in the service of man Appl Clay Sci 10 275 Occurrence Handle10.1016/0169-1317(95)00029-4 Occurrence Handle1:CAS:528:DyaK2MXptlCgsLw%3D

    Article  CAS  Google Scholar 

  • H H Murray (1991) ArticleTitleOverview-clay mineral applications Appl Clay Sci 5 379 Occurrence Handle10.1016/0169-1317(91)90014-Z Occurrence Handle1:CAS:528:DyaK3MXkvFOnu7c%3D

    Article  CAS  Google Scholar 

  • L Sujeong Y J Kim H Moon (1999) ArticleTitlePhase transformations sequence from kaolinite to mullite investigated by an energy-filtering transmission electron microscope J Am Ceram Soc 82 2841

    Google Scholar 

  • A Bakolas E Aggelakopoulou A Moropoulou S Anagnostopoulou (2006) ArticleTitleEvaluation of pozzolanic activity and physico-mechanical characteristics in metakaolin-lime pastes J Therm Anal Cal 84 157 Occurrence Handle10.1007/s10973-005-7262-y Occurrence Handle1:CAS:528:DC%2BD28XjsVOmsb8%3D

    Article  CAS  Google Scholar 

  • E Badogiannis G Kakali S Tsivilis (2005) ArticleTitleMetakaolin as supplementary cementitous material, optimization of kaolin to metakaolin conversion J Therm Anal Cal 81 457 Occurrence Handle10.1007/s10973-005-0806-3 Occurrence Handle1:CAS:528:DC%2BD2MXnslyqtrk%3D

    Article  CAS  Google Scholar 

  • Farmer V C (1974) The infrared spectra of minerals. Mineral Soc Monogr London Mineralog Soc, vol. 4, p 312

  • G E Benedetto R De Laviano L Sabbatini P G Zambonin (2002) ArticleTitleInfrared spectroscopy in the mineralogical characterization of ancient pottery J Cultural Heritage 3 177 Occurrence Handle10.1016/S1296-2074(02)01178-0

    Article  Google Scholar 

  • InstitutionalAuthorNameASTM C25 (1993) Standard test methods for chemical analysis of limestone, quicklime, and hydrated lime Natl Inst Standard Testing Bethesda, MD

    Google Scholar 

  • M P Luxán F Madruga J Savedra (1989) ArticleTitleRapid evaluation of pozzolanic activity of natural products by conductivity measurement Cem Concr Res 19 63 Occurrence Handle10.1016/0008-8846(89)90066-5

    Article  Google Scholar 

  • UNI 11087 Protocol (2003) Cultural heritage – natural and artificial stones – determination of soluble salts content

  • K Callebaut J Elsen K Van Balen W Viaene (2001) ArticleTitleNineteenth century hydraulic restoration mortars in the Saint Michael’s church (Leuven, Belgium) – natural hydraulic lime or cement? Cem Concr Res 31 397 Occurrence Handle10.1016/S0008-8846(00)00499-3 Occurrence Handle1:CAS:528:DC%2BD3MXivFWqs7w%3D

    Article  CAS  Google Scholar 

  • D N Papadopoulou M Lalia-Kantouri N Kantiranis J A Stratis (2006) ArticleTitleThermal and mineralogical contribution to the ancient ceramics and natural clays characterization J Therm Anal Cal 84 39 Occurrence Handle10.1007/s10973-005-7173-y Occurrence Handle1:CAS:528:DC%2BD28XjsVOntbg%3D

    Article  CAS  Google Scholar 

  • A Moropoulou A Bakolas P Moundoulas A S Cakmak (1998) ArticleTitleCompatible restoration mortars, preparation and evaluation for Hagia Sophia earthquake protection PACT 56 79

    Google Scholar 

  • I Papayianni (2006) ArticleTitleThe longevity of old mortars Appl Physics A 83 685 Occurrence Handle10.1007/s00339-006-3523-2 Occurrence Handle1:CAS:528:DC%2BD28Xkslemtrg%3D

    Article  CAS  Google Scholar 

  • G Baronio L Binda (1997) ArticleTitleStudy of the pozzolanicity of some bricks and clays Construct Building Mater 11 41 Occurrence Handle10.1016/S0950-0618(96)00032-3

    Article  Google Scholar 

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Authors and Affiliations

  1. Mechanical Engineering Department, Izmir Institute of Technology, Izmir, Turkey

    Meral Budak

  2. Ministry of Culture, 25th Ephorate of Prehistoric and Classical Antiquities, Chania, Greece

    Pagona Maravelaki-Kalaitzaki

  3. Analytical and Environmental Chemistry Lab, Technical University of Crete, Chania, Greece

    Nikolaos Kallithrakas-Kontos

Authors
  1. Meral Budak
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  2. Pagona Maravelaki-Kalaitzaki
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  3. Nikolaos Kallithrakas-Kontos
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Corresponding author

Correspondence to Nikolaos Kallithrakas-Kontos.

Additional information

Correspondence: Nikolaos Kallithrakas-Kontos, Analytical and Environmental Chemistry Lab, Technical University of Crete, 73100 Chania, Greece

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Budak, M., Maravelaki-Kalaitzaki, P. & Kallithrakas-Kontos, N. Chemical characterization of Cretan clays for the design of restoration mortars. Microchim Acta 162, 325–331 (2008). https://doi.org/10.1007/s00604-007-0927-4

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  • DOI: https://doi.org/10.1007/s00604-007-0927-4

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