Abstract
Information about quantitative OH concentrations and temperature during the combustion process is important for the development of combustion kinetics and understanding of combustion chemistry. In this work, we perform simultaneous measurements of the averaged temperature, H2O concentration, and OH concentration using a single telecommunication-fiber-coupled tunable diode laser near 1.477 μm. A 1f-normalized wavelength modulation spectroscopy with a second-harmonic (2f) detection scheme is employed to improve the sensitivity and remove the influence of the transmission variation. According to the validation experiments performed in a well-controlled heated static cell and the combustion exhaust on a burner, the uncertainties for the measurements of OH concentration, H2O concentration, and temperature are 6.61%, 3.35%, and 3.77%, respectively. The measured vertical profiles for the temperatures, H2O concentrations, and OH concentrations above the burner illustrate the potential of the system in a variety of combustion applications. This work is beneficial to the development of a low-cost sensor for combustion diagnosis.
Similar content being viewed by others
References
A. Hofzumahaus, F. Rohrer, K. Lu, B. Bohn, T. Brauers, C.C. Chang, H. Fuchs, F. Holland, K. Kita, Y. Kondo, X. Li, S. Lou, M. Shao, L. Zeng, A. Wahner, Y. Zhang, Amplified trace gas removal in the troposphere. Science 324(5935), 1702–1704 (2009)
L. Jaeglé, D.J. Jacob, W.H. Brune, I. Faloona, D. Tan, B.G. Heikes, Y. Kondo, G.W. Sachse, B. Anderson, G.L. Gregory, H.B. Singh, R. Pueschel, G. Ferry, D.R. Blake, R.E. Shetter, Photochemistry of HOx in the upper troposphere at northern midlatitudes. J. Geophys. Res. Atmos. 105(D3), 3877–3892 (2000)
R. Atkinson, Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes. Atmos. Chem. Phys. 3(6), 2233–2307 (2003)
N. Hansen, J.A. Miller, S.J. Klippenstein, P.R. Westmoreland, K. Kohse-Höinghaus, Exploring formation pathways of aromatic compounds in laboratory-based model flames of aliphatic fuels. Combust. Explo. Shock 48(5), 508–515 (2012)
M.J. Dyer, D.R. Crosley, Two-dimensional imaging of OH laser induced fluorescence in a flame. Opt. Lett. 7, 382–384 (1982)
J.M. Seitzman, R.K. Hanson, P.A. DeBarber, C.F. Hess, Application of quantitative two line OH planar laser-induced fluorescence for temporally resolved planar thermometry in reacting flows. Appl. Opt. 33, 4000–4012 (1994)
C.F. Kaminski, J. Hult, M. Alden, High repetition rate planar laser induced fluorescence of OH in a turbulent non-premixed flame. Appl. Phys. B. 68, 757–760 (1999)
B.B. Dally, A.N. Karpetis, R.S. Barlow, Structure of turbulent non-premixed jet flames in a diluted hot coflow. Proc. Combust. Inst. 29, 1147–1154 (2002)
S. Singh, M.P. Musculus, R.D. Reitz, Mixing and flame structures inferred from OH-PLIF for conventional and low-temperature diesel engine combustion. Combust. Flame. 156, 1898–1908 (2009)
A.M. Steinberg, I. Boxx, C.M. Arndt, J.H. Frank, W. Meier, Experimental study of flame-hole reignition mechanisms in a turbulent non-premixed jet flame using sustained multi-kHz PIV and crossed-plane OH PLIF. Proc. Combust. Inst. 33(1), 1663–1672 (2011)
J.P. Maillard, J. Chauville, A.W. Mantz, High-resolution emission spectrum of OH in an oxyacetylene flame from 3.7 to 0.9 μm. J. Mol. Spectrosc. 63, 120–141 (1976)
J. Kojima, Y. Ikeda, T. Nakajima, Spatially resolved measurement of OH*, CH*, and C2* chemiluminescence in the reaction zone of laminar methane/air premixed flames. Proc. Combust. Inst. 28, 1757–1764 (2000)
B. Higgins, M.Q. McQuay, F. Lacas, J.C. Rolon, N. Darabiha, S. Candel, Systematic measurements of OH chemiluminescence for fuel-lean, high-pressure, premixed, laminar flames. Fuel 80, 67–74 (2001)
M. De Leo, A. Saveliev, L.A. Kennedy, S.A. Zelepouga, OH and CH luminescence in opposed flow methane oxy-flames. Combust. Flame. 149, 435–447 (2007)
R. Stützer, M. Oschwald, The hyperfine structure of the OH* emission spectrum and its benefits for combustion analysis, in proceedings of the 8th european conference for aeronautics and space sciences. 8th european conference for aeronautics and space sciences EUCASS (2019).
K.C. Lück, F.J. Müller, Simultaneous determination of temperature and OH-concentration in flames using high-resolution laser-absorption spectroscopy. J. Quant. Spectrosc. Radiat. Transf. 17(3), 403–409 (1977)
R.K. Hanson, S. Salimian, G. Kychakoff, R.A. Booman, Shock tube absorption measurements of OH using a remotely located dye laser. Appl. Opt. 22, 641–643 (1983)
S.S. Vasu, D.F. Davidson, Z. Hong, V. Vasudevan, R.K. Hanson, n-Dodecane oxidation at high-pressures: measurements of ignition delay times and OH concentration time-histories. Proc. Combust. Inst. 32, 173–180 (2009)
S. Wang, D.F. Davidson, R.K. Hanson, Rate constants of long, branched, and unsaturated aldehydes with OH at elevated temperatures. Proc. Combust. Inst. 36, 151–160 (2017)
S. Wang, R.K. Hanson, “High-sensitivity 3086-nm laser absorption diagnostic optimized for OH measurement in shock tube combustion studies. Appl. Phys. B 124(3), 37 (2018)
X. Yang, Z. Peng, Y. Ding, Y. Du, Temperature and OH concentration measurements by ultraviolet broadband absorption of OH(X) in laminar methane/air premixed flames. Fuel 288, 119666 (2021)
R.F. Curl, F.K. Tittel, Tunable infrared laser spectroscopy. Annu. Rep. Prog. Chem Sect. C: Phys. Chem. 98, 219–272 (2002)
M.G. Allen, Diode laser absorption sensors for gas-dynamic and combustion flows. Measur. Sci. Technol. 9(4), 545–562 (1998)
V. Ebert, T. Fernholz, C. Giesemann, H. Pitz, H. Teichert, J. Wolfrum, H. Jaritz, Simultaneous diode-laser-based in situ detection of multiple species and temperature in a gas-fired power plant. Proc. Combust. Inst. 28, 423–430 (2000)
B.L. Upschulte, D.M. Sonnenfroh, M.G. Allen, Measurements of CO, CO2, OH, and H2O in room-temperature and combustion gases by use of a broadly current-tuned multisection InGaAsP diode laser. Appl. Opt. 38(9), 1506–1512 (1999)
T. Aizawa, T. Kamimoto, T. Tamaru, Measurements of OH radical concentration in combustion environments by wavelength-modulation spectroscopy with a 1.55-µm distributed-feedback diode laser. Appl. Opt. 38(9), 1733–1741 (1999)
T. Aizawa, Diode-laser wavelength-modulation absorption spectroscopy for quantitative in situ measurements of temperature and OH radical concentration in combustion gases. Appl. Opt. 40(27), 4894–4903 (2001)
R. Peeters, G. Berden, G. Meijer, Near-infrared cavity enhanced absorption spectroscopy of hot water and OH in an oven and in flames. Appl. Phys. B 73(1), 65–70 (2001)
L. Rutkowski, A.C. Johansson, D. Valiev, A. Khodabakhsh, A. Tkacz, F.M. Schmidt, A. Foltynowicz, Detection of OH in an atmospheric flame at 1.5 um using optical frequency comb spectroscopy. Photonics Lett. Pol. 8, 110–112 (2016)
T.R.S. Hayden, N. Malarich, D.J. Petrykowski, P.M. Siddharth, J.D. Christopher, C. Lapointe, N.T. Wimer, P.E. Hamlington, G.B. Rieker, OH radical measurements in combustion environments using wavelength modulation spectroscopy and dual-frequency comb spectroscopy near 1491 nm. Appl. Phys. B 125, 226 (2019)
T.R.S. Hayden, D.J. Petrykowski, A. Sanchez, S.P. Nigam, C. Lapointe, J.D. Christopher, N.T. Wimer, A. Upadhye, M. Strobel, P.E. Hamlington, G.B. Rieker, Characterization of OH, H2O, and temperature profiles in industrial flame treatment systems interacting with polymer films. Proc. Combust. Inst. 37(2), 1571–1578 (2019)
J.J. Scherer, D. Voelkel, D.J. Rakestraw, Infrared cavity ringdown laser absorption spectroscopy (IR-CRLAS) in low pressure flames. Appl. Phys. B 64, 699–705 (1997)
J.J. Scherer, K.W. Aniolek, N.P. Cernanscky, D.J. Rakestraw, Determination of methyl radical concentrations in a methane/air flame by infrared cavity ringdown laser absorption spectroscopy. J. Chem. Phys. 107, 6196–6203 (1997)
A. Farooq, J.B. Jeffries, R.K. Hanson, Sensitive detection of temperature behind reflected shock waves using wavelength modulation spectroscopy of CO2 near 2.7 μm. Appl. Phys. B 96, 161–173 (2009)
T. Cai, G. Gao, M. Wang, G. Wang, Y. Liu, X. Gao, Simultaneous measurements of temperature and CO2 concentration employing diode laser absorption near 2.0 μm. Appl. Phys. B 118(3), 471–480 (2015)
R. Cui, L. Dong, H. Wu, S. Li, L. Zhang, W. Ma, W. Yin, L. Xiao, S. Jia, F.K. Tittle, Highly sensitive and selective CO sensor using a 233 μm diode laser and wavelength modulation spectroscopy. Opt. Express 26(19), 24318–24328 (2018)
P. Kluczynski, Å.M. Lindberg, O. Axner, Wavelength modulation diode laser absorption signals from doppler broadened absorption profiles. J. Quant. Spectrosc. Radiat. Transf. 83(3–4), 345–360 (2004)
B.K. Alsberg, A.M. Woodward, M.K. Winson, J. Rowland, D.B. Kell, Wavelet denoising of infrared spectra. Analyst (Lond.) 122(7), 645–652 (1997)
G.Z. Gao, T. Zhang, G. Zhang, X. Liu, T.D. Cai, Simultaneous and interference-free measurements of temperature and C2H4 concentration using a single tunable diode laser at 1.62 μm. Opt. Express 2(17), 887–904 (2019)
G. Zhang, G.Z. Gao, T. Zhang, X. Liu, C.D. Peng, T.D. Cai, Absorption spectroscopy of ethylene near 162 μm at high temperatures. J. Quant. Spectrosc. Radiat. Transf. 241, 106748 (2020)
Funding
Funding for this work comes from the National Natural Science Foundation of China (No. 61875079, No. 61805110, No. 61475068, and No. 11104237), Science and Technology Program of Jiangsu Province (No. BE2021634), and the Science and Technology Program of Xuzhou City (No. KC19202).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Gao, Z., Gao, G. & Cai, T. A simple sensor for simultaneous measurements of OH, H2O, and temperature in combustion environments using a single tunable diode laser near 1.477 μm. Appl. Phys. B 127, 158 (2021). https://doi.org/10.1007/s00340-021-07710-w
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00340-021-07710-w