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X-ray diffraction study of the clathrate [MnPy4(NO3)2)]·2Py and complex [MnPy3(NO3)2] formed in the pyridine (Py)-manganese nitrate system

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Abstract

A clathrate compound [MnPy4(NO3)2]·2Py was synthesized and studied by single-crystal X-ray diffraction analysis (KM-4 diffractometer, CuKα,ω/2ϑ scan mode,ϑ max=78°). The unit cell is base-centered orthorhombic, space group Ccca, a=12.097(4), b=15.197(4), c=17.213(4) Å, V=3164(2) Å3, Z=4, R=0.072, for 632 reflections and 107 parameters in the least-squares analysis. The host molecule has 222 symmetry. Two monodentate nitrato groups and four pyridine ligands are coordinated to Mn(II) along the symmetry axes (the former via O). The pyridine guest molecules lie in the cavities of the crystal framework. For [MnPy3(NO3)2)], only unit cell parameters were determined: a=12.467(5), b=9.514(2), c=16.383(5) Å,β=108.93(4), V=1838(1) Å3 space group C2/c or Cc (according to extinctions). The pyridine-manganese nitrate system is shown to be analogous to the previously investigated Co, Ni, Cu, Zn, and Cd systems.

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References

  1. D. V. Soldatov and J. Lipkowski,Zh. Strukt. Zhim.,36, 1070–1073 (1995).

    CAS  Google Scholar 

  2. D. V. Soldatov,J. Incl. Phenom.,20, 191–192 (1995).

    Article  Google Scholar 

  3. D. V. Soldatov and J. Lipkowski,Zh. Strukt. Khim.,36, 903–911 (1995).

    Google Scholar 

  4. D. V. Soldatov, E. V. Grachev, and J. Lipkowski, ibid.,37, 764–773 (1996).

    CAS  Google Scholar 

  5. D. V. Soldatov, Yu. A. Dyadin, J. Lipkowski, and A. G. Ogienko,Mendeleev Commun., 11–13 (1997).

  6. J. Lipkowski,Comp. Supr. Chem.,6, 691–714 (1996).

    CAS  Google Scholar 

  7. D. V. Soldatov, V. A. Logvinenko, and Yu. A. Dyadin,Zh. Neorg. Khim.,40, 324–328 (1995).

    CAS  Google Scholar 

  8. Yu. A. Dyadin, D. V. Soldatov, V. A. Logvinenko, and J. Lipkowski,J. Coord. Chem.,37, 63–75 (1996).

    Article  CAS  Google Scholar 

  9. D. V. Soldatov, Yu. A. Dyadin, E. A. Ukraintseva, et al.,J. Incl. Phenom.,26, 269–280 (1996).

    Article  CAS  Google Scholar 

  10. G. M. Sheldrick,Acta Crystallogr.,A46, 467–473 (1990).

    CAS  Google Scholar 

  11. G. M. Sheldrick,ibid.,A49, C53 (1993).

  12. D. V. Soldatov and J. Lipkowski,Zh. Strukt. Khim.,36, 912–918 (1995).

    CAS  Google Scholar 

  13. J. Lipkowski,J. Mol. Struct.,75, 13–28 (1981).

    Article  CAS  Google Scholar 

  14. M. A. Araya, F. A. Cotton, J. H. Matonic, and C. A. Murillo,Inorg. Chem.,34, 5424–5428 (1995).

    Article  CAS  Google Scholar 

  15. K. Bertoncello, G. D. Fallon, and K. S. Murray,Inorg. Chim. Acta,174, 57–60 (1990).

    Article  CAS  Google Scholar 

  16. N. V. Pervukhina, N. V. Podberezskaya, I. V. Davydova, et al.,J. Incl. Phenom.,13, 9–16 (1992).

    Article  CAS  Google Scholar 

  17. D. V. Soldatov and J. Lipkowski,Zh. Strukt. Khim.,36, 1074–1082 (1995).

    CAS  Google Scholar 

  18. D. V. Soldatov, B. A. Kolesov, J. Lipkowski, and Yu. A. Dyadin,Zh. Strukt. Khim.,38, No. 6, 976–987 (1997).

    Google Scholar 

  19. A. F. Waters and A. H. White,Aust. J. Chem.,49, 35–46 (1996).

    CAS  Google Scholar 

  20. G. Beurskens, C. F. Martens, R. J. M. Nolte, et al.,J. Chem. Crystallogr.,25, 425–427 (1995).

    Article  CAS  Google Scholar 

  21. S. Halut-Desportes,Arch Crystallogr.,B33, 599–601 (1977).

    Article  CAS  Google Scholar 

  22. M. Philoche-Levisalles and S. Halut-Desportes,C. R. Acad. Sci. Paris,C284, 183–185 (1977).

    Google Scholar 

  23. M. Selkti, C.-C. Ling, and A. Navaza,J. Incl. Phenom.,17, 127–135 (1994).

    Article  CAS  Google Scholar 

  24. P. B. Durand and E. M. Holt,Acta Crystallogr.,C51, 850–852 (1995).

    CAS  Google Scholar 

  25. M. Ito, T. Shibata, and Y. Saito, ibid.,C40, 2041–2043 (1984).

    CAS  Google Scholar 

  26. A. F. Cameron, D. W. Taylor, and R. H. Nuttall,J. Chem. Soc., Dalton Trans., 1603–1608 (1972).

  27. A. F. Cameron, D. W. Taylor, and P. H. Nuttall,ibid., 1608–1611 (1972).

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Authors
  1. D. V. Soldatov
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  2. J. Lipkowski
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Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Institute of Physical Chemistry, Polish Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 2, pp. 292–299, March–April, 1998.

This work was supported by the Federal Program “State Support for Integration of Higher Education and Fundamental Science for 1997–2000” (project No. 274).

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Soldatov, D.V., Lipkowski, J. X-ray diffraction study of the clathrate [MnPy4(NO3)2)]·2Py and complex [MnPy3(NO3)2] formed in the pyridine (Py)-manganese nitrate system. J Struct Chem 39, 238–243 (1998). https://doi.org/10.1007/BF02873624

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  • DOI: https://doi.org/10.1007/BF02873624

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