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Peculiarities of the crystal structure and packing of the host and guest molecules in the [M(4-McPy)4(NCS)2]·0.67(4-McPy)·0.33 H2O Clathrates (M = Cu(II), Mn(II); 4-MePy = 4-Methylpyridine)

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Abstract

The crystal structures of the two clathrates with the composition [M(4-MePy)4(NCS)2]·0.67(4-McPy)·0.33 H2O (M=Cu(II), Mn(II); 4-MePy=4-methylpyridine) have been determined. These compounds are trigonal, with the [M(4-MePy)4(NCS)2] host molecules being centrosymmetric. The parameters of the unit cells area = 27.365(7) and 27.738(6),c = 11.303(9) and 11.250(8) Å,V = 7325(2) and 7493(2) Å3, space group R\(\bar 3\), R = 0.053 and 0.109 for M = Cu(II) and Mn(II), respectively. ForZ = 9d calcd is equal to 1.271 and 1.225 g/cm3, andd measd is equal to 1.252(2) and 1.213(2) g/cm3 for the Cu and Mn clathrates, respectively. The coordination environment of the metal atoms in these compounds is an irregular octahedron, while in the Mn compound these distortions are rather small (Mn-NMePy 2.30, 2.34 Å, Mn-NNCS 2.18 Å, and Cu-NMePy 2.06 Å, Cu-NNCS 1.98 Å and Cu-NMePy 2.50 Å).

The molecular packing in the structures is such that the channels of variable diameter are formed along the short cell dimension (the maximum diameter is ≅ 10 Å, the minimum being ≅ 6 Å) where the guest 4-MePy and H2O molecules are placed.

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References

  1. W. D. Schaeffer, W. S. Dorsey, D. A. Skinner and C. G. Christian: J. Am. Chem. Soc. 79, 5870 (1957).

    Google Scholar 

  2. W. Kemula, D. Sybilska: Nature 185, 237 (1960).

    Google Scholar 

  3. D. Sybilska, K. Malinovska, M. Siekierska and J. Bylina: Chem. Analityc. 17, 1031 (1972).

    Google Scholar 

  4. J. Lipkowski: in Inclusion Compounds, Vol. 1 (Eds. J. L. Atwood, J. E. D. Davies and D. D. MacNicol) pp. 59–103, Academic Press, London (1984).

    Google Scholar 

  5. N. V. Pervukhina, N. V. Podberezskaya, V. V. Bakakin, N. V. Kislykh, G. N. Chekhova and Yu. A. Dyadin: Zh. Struct. Khim. 26, 120 (1985); Chem. Abstr. 104, 139681g (1986).

    Google Scholar 

  6. N. V. Kislykh, Yu. A. Dyadin, N. V. Pervukhina, I. V. Davydova and N. V. Podberezskya: Izv. Sib. Otd. Akad. Nauk. SSSR, Ser. Khim. Nauk 3, 76 (1989); Chem. Abstr. 111, 141646n (1989).

    Google Scholar 

  7. E. A. Ukraintseva, N. V. Kislykh, Yu. A. Dyadin, V. A. Logvinenko: Izv. Sib. Otd. Akad. Nauk. SSSR, Ser. Khim. Nauk 5, 69 (1989); Chem. Abstr. 112, 171059m (1990).

    Google Scholar 

  8. Yu. A. Dyadin, N. V. Kislykh, G. N. Chekhova, N. V. Podberezskaya, N. V. Pervukhina, V. A. Logvinenko, I. M. Oglezneva: J. Incl. Phenom. 2, 333 (1984).

    Google Scholar 

  9. G. V. Gavrilova, N. V. Kislykh, V. A. Logvinenko: J. Therm. Anal. 33, 229 (1988).

    Google Scholar 

  10. R. T. Gerr, A. I. Yanovskii and Yu. T. Struchkov: Kristallografiya, 28, 1029 (1983).

    Google Scholar 

  11. J. Lipkowski: J. Mol. Struct. 75, 13 (1981).

    Google Scholar 

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  1. Institute of Inorganic Chemistry, Novosibirsk, U.S.S.R.

    N. V. Pervukhina, N. V. Podberezskaya, I. V. Davydova, N. V. Kislykh & Yu. A. Dyadin

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  1. N. V. Pervukhina
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  2. N. V. Podberezskaya
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  3. I. V. Davydova
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  4. N. V. Kislykh
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  5. Yu. A. Dyadin
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Pervukhina, N.V., Podberezskaya, N.V., Davydova, I.V. et al. Peculiarities of the crystal structure and packing of the host and guest molecules in the [M(4-McPy)4(NCS)2]·0.67(4-McPy)·0.33 H2O Clathrates (M = Cu(II), Mn(II); 4-MePy = 4-Methylpyridine). J Incl Phenom Macrocycl Chem 13, 9–16 (1992). https://doi.org/10.1007/BF01076666

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  • DOI: https://doi.org/10.1007/BF01076666

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