Abstract
The metastable ordered phasem-TiBe was discovered in the course of studying liquidquenched Ti-Be and Ti-Be-Zr alloys. m-TiBe forms, together with the α-Ti solid solution, on heating binary (and ternary) metallic glasses to 700°C and is also observed directly in as-quenched alloys lying outside the composition limits for glass formation. This phase has a B2 (CsCl-type) crystal structure. Its existence can be justified in terms of crystal chemical factors leading to the conclusion that TiBe most likely does not appear as an equilibrium phase in normally cooled alloys due to the greater stability of the Laves phase TiBe2.
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Rapidly Quenched Metals, Proc. Second Inter. Conf., N. J. Grant and B. C. Giessen, eds., Section I, M.I.T. Press, Cambridge, Mass., 1976; Section II,Mater. Sci. Eng., 1976, vol. 23, pp. 83-316.
A. K. Sinha, B. C. Giessen, and D. E. Polk:Treatise on Solid State Chemistry, N. B. Hannay, ed., p. 1, Vol. III, Plenum Press, New York, 1976.
T. Masumoto and R. Maddin:Mater. Sci. Eng., 1975, vol. 19, p. 1.
J. J. Gilman:Phys. Today, 1975, vol. 28, p. 46.
B.C. Giessen:Rapidly Quenched Metals, Proc. Second Inter. Conf., Section I, p. 119, M.I.T. Press, Cambridge, Mass., 1976.
R. P. Elliott:Constitution of Binary Alloys, First Supplement, p. 172, McGraw-Hill Book Co., 1965.
L. E. Tanner, R. Ray, and C. F. Cline: U.S. Patent No. 3,989,517, 1976. L. E. Tannerand R. Ray:Scripta Met., 1977, vol. 11, p. 783.
W. B. Pearson:A Handbook of Lattice Spacings and Structures of Metals and Alloys, Pergamon Press, N.Y., vol. 1, 1958, vol. 2, 1967.
W. B. Pearson:The Crystal Chemistry and Physics of Metals and Alloys, Wiley-Interscience, New York, 1972.
M. Hansen:Constitution of Binary Alloys, McGraw-Hill Book Co., New York, 1958.
T.V. Philip and P. A. Beck:Trans. AIME, 1957, vol. 209, p. 1269.
T. B. Massalski:Physical Metallurgy, 2nd Edition, R. W. Cahn, ed., p. 202, North Holland/American Elsevier, New York, 1970.
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Tanner, L.E., Giessen, B.C. Structure and formation of the metastable phase m-TiBe. Metall Trans A 9, 67–69 (1978). https://doi.org/10.1007/BF02647172
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DOI: https://doi.org/10.1007/BF02647172