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Phase Equilibria and Phase Transformations at High Temperatures in Ternary Alloys of the Ni–Ti–Zr System at 50–100 Ni at.%

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Powder Metallurgy and Metal Ceramics Aims and scope

Alloys of the ternary Ni–Ti–Zr system containing 50 to 100 at.% Ni that were annealed at subsolidus temperatures were examined by scanning electron microscopy, electron microprobe analysis, and differential thermal analysis. The solidus surface was constructed in this composition range. A new ternary phase of composition Ni69.2Ti12.5Zr18.3 was found.

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References

  1. T. Sawaguchi, M. Sato, and A. Ishida, “Grain-size effect on shape-memory behavior of Ti35.0Ni49.7Zr15.4 thin films,” Metall. Mater. Trans. A, 35A, 111–119 (2004).

  2. M. Zarinejad, Y. Liu, and Y. Tong, “Transformation temperature changes due to second phase precipitation in NiTi-based shape memory,” Intermetallics, 17, 914–919 (2009).

    Article  Google Scholar 

  3. P. Sadoc, J.Y. Kim, and K.F. Kelton, “Local atomic structure of icosahedral quasicrystals and 1/1 approximant in the Ti–Ni–Zr alloy system,” Mater. Sci. Eng., 294–296, 348–350 (2000).

    Article  Google Scholar 

  4. L. Wang and C. Li, “Formation of Zr70Ni23Ti7 glassy alloy and phase transformation upon annealing,” J. Mater. Res., 17, 693–696 (2002).

    Article  Google Scholar 

  5. D. Louzguine-Luzgin, T. Shimada, and A. Inoue, “A study of glass-formation, formation of the supercooled liquid and devitrification behavior of Ni-based bulk glass-forming alloys,” Mater. Sci. Eng. A, 449–451, 198–202 (2007).

    Article  Google Scholar 

  6. J. Bhatt and B.S. Murty, “On the conditions for the synthesis of bulk metallic glasses by mechanical alloying,” J. Alloys Compd., 459, 135–141 (2008).

    Article  Google Scholar 

  7. V.N. Eremenko, E.L. Semenova, and L.A. Tretyachenko, “Constitution of Ti–Zr–Ni alloys at 0–50% Ni at 700°C,” Dokl. Akad. Nauk USSR. Ser. A, 2, 79–143 (1988).

    Google Scholar 

  8. V.N. Eremenko, E.L. Semenova, L.A. Tretyachenko, and Z.G. Domatyrko, “Constitution of Ti–Zr–Ni alloys in the TiNi–ZrNi section,” Metallovedenie, 6, 85–88 (1989).

    Google Scholar 

  9. V.V. Molokanov, V.N. Chebotnikov, Yu.K. Kovneristy, and E.B. Rubina, “Structure and properties of Тi–Zr–Ni alloys in the Ti2Ni–Zr2Ni section in amorphous and crystalline states,” Izv. Akad. Nauk USSR. Neorg. Mater., 25, No. 1, 61–65 (1989).

    Google Scholar 

  10. V.N. Eremenko, E.L. Semenova, and L.A. Tretyachenko, “Solidus surface of the Тi–Zr–Ni system in the Ti–TiNi–ZrNi–Zr region,” Metally, 6, 191–196 (1990).

    Google Scholar 

  11. V.N. Eremenko, E.L. Semenova, and L.A. Tretyachenko, “Liquidus surface and solidification scheme for alloys of the system Ti–Zr–Ni containing up to 50% Ni,” Powder Metall. Met. Ceram., 30, No. 8, 664–668 (1991).

    Article  Google Scholar 

  12. V.N. Eremenko, E.L. Semenova, and L.A. Tretyachenko, “Solidus surface and reactions in crystallization of Ti–Zr–Ni alloys in the Ti–TiNi–ZrNi–Zr region,” Metally, 6, 138–143 (1992).

    Google Scholar 

  13. T. Tokunaga, S. Matsumoto, H. Ohtani, and M. Hasebe, “Thermodynamic calculation of phase equilibria in the Nb–Ni–Ti–Zr quaternary system,” Mater. Trans., 48, No. 2, 89–96 (2007).

    Article  Google Scholar 

  14. M.-C. Yeh, J.L. Li, P.J. Lo, and K.-C. Hsieh, “Phase equilibrium in the Ni–Ti–Zr system at 800°C,” J. Phase Equilib., 35, No. 2, 157–162 (2014).

    Article  Google Scholar 

  15. X.J. Liu, S.Y. Yang, Y.X. Huang, J.B. Zhang, J. Li, J. H. Zhu, H.X. Jiang, and P.C. Wang, “Experimental investigation of isothermal sections (1000, 1200°C) in the Ni–Ti–Zr system,” J. Phase Equilib., 36, No. 5, 414–421 (2015).

    Article  Google Scholar 

  16. T.Ya. Velikanova, A.A. Bondar, L.V. Artyukh, M.A. Turchanin, O.I. Dovbenko, V.M. Petyukh, A.M. Storchak-Fedyuk, O.S. Fomichov, Yu.M. Podrezov, M.V. Remez, S.O. Bilous, N.I. Tsyganenko, and V.M. Voblikov, “Experimental study of the Fe–Ta, Al–Fe–Ta, Al–Ta–Ti, and Ni–Ti–Zr systems for thermodynamic description,” in: Report on Studying the Stability of Phases and Phase Transformations in Multicomponent Systems Formed by Titanium, Chromium, and d-Metals in Group VIII with Aluminum, Tin, and Rare Earth and Other Elements as Scientific Fundamentals for Developing New Light High-Temperature Creep-Resistant Alloys and Functional Materials with Special Properties [in Ukrainian], Inst. Probl. Materialoznav. NAN Ukrainy, Kyiv (2012), Vol. 5, State Registration No. 0110U002347, p. 214.

  17. J.L. Murray, “Ni–Ti (nickel–titanium),” in: P. Nash (ed.), Phase Diagrams of Binary Nickel Alloys, ASM International, Materials Park, Ohio (1991), pp. 342–355.

    Google Scholar 

  18. P. Bellen, H. Kumar, and P. Wollants, “Thermodynamic assessment of the Ni–Ti phase diagram,” Z. Metallkd., 87, No. 12, 972–978 (1996).

    Google Scholar 

  19. T.V. Massalski, P.R. Subramanian, H. Okomoto, and L. Kasprzak (eds.), Binary Alloy Phase Diagrams: Handbook, in 3 Vols., 2nd ed., ASM International, Materials Park, Ohio (1990), p. 3589.

  20. J.H. Glimois, P. Forey, R. Guillen, and J.L. Feron, “Structural study of the ternary alloys (TixZr1–x)Ni3,” J. Less-Common Met., 134, 221–228 (1987).

    Article  Google Scholar 

  21. P. Nash, Phase Diagrams of Binary Nickel Alloys, ASM International, Materials Park, Ohio (1991).

    Google Scholar 

  22. Yu.A. Kocherzhynski, E.A. Shishkin, and V.I. Vasilenko, “DTA unit with a thermocouple sensor to 2200°C,” in: N.V. Ageev and O.S. Ivanova, Phase Diagrams of Metallic Systems [in Russian], Nauka, Moscow (1971), pp. 245–249.

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Acknowledgments

The authors are grateful to V.B. Sobolev (Technical Center of the National Academy of Sciences of Ukraine) for technical support in the experiments.

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Correspondence to A. M. Storchak.

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Translated from Poroshkova Metallurgiya, Vol. 58, Nos. 3–4 (526), pp. 111–123, 2019.

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Storchak, A.M., Velikanova, T.Y., Artyukh, L.V. et al. Phase Equilibria and Phase Transformations at High Temperatures in Ternary Alloys of the Ni–Ti–Zr System at 50–100 Ni at.%. Powder Metall Met Ceram 58, 210–221 (2019). https://doi.org/10.1007/s11106-019-00066-z

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  • DOI: https://doi.org/10.1007/s11106-019-00066-z

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