Skip to main content
SpringerLink
Log in

Trajectory and kinetics of relaxation processes during the crystallization of inorganic alloys

  • Published:
Inorganic Materials Aims and scope

Abstract

This paper discusses some problems of physicochemical analysis and examines the possibility of gaining insight into the mechanisms underlying the crystallization behavior of inorganic alloys. As a model, we use a eutectic T-x system with two phase-forming structural components and limited solid solutions based on them. We demonstrate that the supramolecular theory of eutectics and current views of solid-state determined can be helpful in predicting the forming metastable structural states.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Anosov, V.Ya. and Pogodin, S.A., Osnovnye nachala fiziko-khimicheskogo analiza (Principles of Physicochemical Analysis), Moscow: Akad. Nauk SSSR, 1947.

    Google Scholar 

  2. Müller, U., Inorganic Structural Chemistry, Chichester: Wiley, 2006, 2nd ed.

    Book  Google Scholar 

  3. Pervov, V.S., Makhonina, E.V., Zotova, A.E., and Zavrazhnov, A.Y., Metastable states in inorganic systems, Inorg. Mater., 2011, vol. 47, no. 13, pp. 1407–1427.

    Article  CAS  Google Scholar 

  4. Lehn, J.M., Supramolecular Chemistry: Concepts and Perspectives, Weinheim: VCH, 1995.

    Book  Google Scholar 

  5. Zalkin, V.M., Current status of the theory of eutectics, Zh. Fiz. Khim., 1984, vol. 58, pp. 1320–1328.

    CAS  Google Scholar 

  6. Dobrokhotova, Zh.V., Makhonina, E.V., Zvinchuk, R.A., et al., Formation of supramolecular assemblies in eutectic alloys of binary oxide systems, Russ. J. Inorg. Chem., 2005, vol. 50, no. 2, pp. 286–291.

    Google Scholar 

  7. Mehrer, H., Diffusion in Solids, Berlin: Springer, 2007.

    Google Scholar 

  8. Chuvil’deev, V.N., Neravnovesnye granitsy zeren v metallakh. Teoriya i prilozheniya (Nonequilibrium Grain Boundaries in Metals: Theory and Applications), Moscow: Fizmatlit, 2004.

    Google Scholar 

  9. Müller, A., Reuter, H., and Dillinger, S., Supramolecular inorganic chemistry: small guests in small large hosts, Angew. Chem., Int. Ed. Engl., 1995, vol. 34, pp. 2328–2361.

    Article  Google Scholar 

  10. Maier, J., Pushing nanoionics to the limits: charge carrier chemistry in extremely small systems, Chem. Mater., 2014, vol. 26, no. 1, pp. 348–360.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Moscow State University of Mechanical Engineering (MAMI), Bol’shaya Semenovskaya ul. 38, Moscow, 107023, Russia

    V. S. Pervov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. S. Pervov & A. E. Zotova

Authors
  1. V. S. Pervov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. E. Zotova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. S. Pervov.

Additional information

Original Russian Text © V.S. Pervov, A.E. Zotova, 2014, published in Neorganicheskie Materialy, 2014, Vol. 50, No. 8, pp. 917–920.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pervov, V.S., Zotova, A.E. Trajectory and kinetics of relaxation processes during the crystallization of inorganic alloys. Inorg Mater 50, 850–853 (2014). https://doi.org/10.1134/S0020168514080147

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168514080147

Keywords

Search

Navigation