Abstract
On an amalgamated rotating copper disk electrode in an alkaline methanol solution in the presence of mixed Ti(OH)3−Mo(III) hydroxide, dinitrogen is shown to be selectively electroreduced to hydrazine in the potential range −1.6 to −1.9 V (with respect to the saturated calomel electrode).
Abstract
Показано, что на амальгамированном медном вращающемся дисковом электроде в присутствии смешанной гидроокиси Ti(OH)3−Mo(III) в интервале потенциалов −1,6+ −1,9 в (относительно насьщенного каломельного электрода) происходит селективное электровосстановление азота до гидразина.
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References
G.V. Nikolaeva, O.N. Efimov, A.E. Shilov, Kh.M.A. Brickenstein: React. Kinet. Catal. Lett.,6, 349 (1977).
A.V. Gorodyskii, V.V. Danilin, O.N. Efimov, N.E. Nechaeva, V.N. Tsarev: React. Kinet. Catal. Lett.,11, 337 (1979).
S.I. Kulakovskaya, O.N. Efimov: React. Kinet. Catal. Lett.,14, 181 (1980).
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Gorodyskii, A.V., Danilin, V.V., Nechaeva, N.E. et al. Selective electroreduction of dinitrogen on a rotating copper amalgam electrode. React Kinet Catal Lett 15, 373–375 (1980). https://doi.org/10.1007/BF02098718
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DOI: https://doi.org/10.1007/BF02098718