Abstract
We have investigated and analysed the stability of superconducting y1Ba2Cu3O7−x material at 925° C in the normal atmosphere. The material decomposes to BaCO3, CuO, and Y2O3 due to the action of moisture and atmospheric gases. The decomposed materials surround grains of the superconducting phase. The decomposed boundary layer appears to be a limiting factor for grain growth and densification. The superconducting materials also develop defects such as stacking faults and/or twins due to prolonged heat treatment.
Similar content being viewed by others
References
M. K. Wu, J. R. Ashburn, C. J. Torng, P. H. Hor, R. L. Meng, L. Gao, J. Huang, Y. Q. Wang andC. W. Chu,Phys. Rev. Lett. 58 (1987) 908.
B. Kumar, J. D. Wolf andS. R. Smith,J. Mater. Sci. Lett. 7 (1988) 149.
K. G. Frase, E. G. Liniger andD. R. Clark,Adv. Ceram. Mater. 2 (3B) (1987) 698.
A. Barkatt, H. Hojaji andK. A. Michael,ibid. 3(3b) (1987) 701.
B. G. Hyde, J. G. Thompson, R. L. Withers, J. G. Fitzgerald, A. M. Stewart, D. J. M. Benan, J. S. Anderson, J. Bitmead andM. S. Paterson,Nature 327 (1987) 402.
A. Reller, J. D. Bednorz andK. A. Muller, preprint, Berkeley Conference on Superconductivity (1987).
P. K. Gallagher, H. M. O'Bryan, S. A. Sunshine andD. W. Murphy,Mater. Res. Bull. 22 (1987) 995.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kumar, B., Harmer, R.S., Wittberg, T.N. et al. Stability of superconducting Y1Ba2Cu3O7−x phase at 925° C in air. J Mater Sci 23, 3879–3883 (1988). https://doi.org/10.1007/BF01106808
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01106808