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Cycloalkylation of compounds in the series of phosphorus-substituted derivatives of acetic acid

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

1-Phosphoryl-substituted cyclopropanes, cyclobutanes, and cyclopentanes were obtained by the reaction of phosphoryl-substituted esters and nitriles of acetic acid with α,ω-dihaloalkanes. The influence of the CH-acidity of the starting compounds and electrophilicity of the alkylating agent on the reaction rate was examined.

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Authors and Affiliations

  1. D. I. Mendeleev Moscow Chemical Engineering Institute, USSR

    P. V. Kazakov, I. L. Odinets, A. P. Laretina, T. M. Shcherbina, P. V. Petrovskii, L. V. Kovalenko & T. A. Mastryukova

  2. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    P. V. Kazakov, I. L. Odinets, A. P. Laretina, T. M. Shcherbina, P. V. Petrovskii, L. V. Kovalenko & T. A. Mastryukova

Authors
  1. P. V. Kazakov
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  2. I. L. Odinets
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  3. A. P. Laretina
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  4. T. M. Shcherbina
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  5. P. V. Petrovskii
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  6. L. V. Kovalenko
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  7. T. A. Mastryukova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1873–1880, August, 1990.

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Kazakov, P.V., Odinets, I.L., Laretina, A.P. et al. Cycloalkylation of compounds in the series of phosphorus-substituted derivatives of acetic acid. Russ Chem Bull 39, 1702–1708 (1990). https://doi.org/10.1007/BF00961505

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  • DOI: https://doi.org/10.1007/BF00961505

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