Abstract
The authors report13C,87Rb,39K, and133Cs nuclear magnetic resonance (NMR) measurements of lineshapes, Knight shifts, and spin-lattice relaxation rates in the normal and superconducting states of M3C60, where M3 = Rb3, K3, Rb2K, RbK2, Rb2Cs, and RbCs2. Measurements are used as a guide to a new ammonia solvent synthesis technique. Temperature dependence of the superconducting state electron spin susceptibility is found to follow BCS weak coupling predictions. The issue of the Hebel-Slichter coherence peak is addressed.
Similar content being viewed by others
References
D. E. MacLaughlin, inSolid State Physics, Vol. 31, H. Ehrenreich, F. Seitz, and D. Turnball, eds. (Academic, New York, 1976).
K. Asayama, Y. Kitaoka, and Y. Kohori,J. Magn. Magn. Mater. 76, 77, 449 (1988).
C. H. Pennington and C. P. Slichter, inPhysical Properties of High-Temperature Superconductors, Vol. II, D. M. Ginsberg, ed. (World Scientific, Singapore, 1990).
J. A. Martindale, S. E. Barrett K. E. O'Hara, C. P. Slichter, W. C. Lee, and D. M. Ginsberg,Phys. Rev. B 47, 9155 (1993).
J. A. Martindale, S. E. Barrett, C. A. Klug, K. E. O'Hara, S. M. DeSoto, C. P. Slichter, T. A. Friedmann, and D. M. Ginsberg,Phys. Rev. Lett. 68, 698 (1992).
M. Takigawa, J. L. Smith, and W. L. Hults,Phys. Rev. B 44, 7764 (1991).
R. E. Walstedt, D. W. Murphy, and M. Rosseinsky,Nature (London) 362, 3754 (1993).
D. W. Murphy, M. J. Rosseinsky, R. M. Fleming, R. Tycko, A. P. Ramirez, R. C. Haddon, T. Siegrist, G. Dabbagh, J. C. Tully, and R. E. Walstedt,J. Phys. Chem. Solids 53, 1321–1332 (1992).
H. H. Wang, A. M. Kini, B. M. Savall, K. D. Carlson, J. M. Williams, K. R. Lykke, P. Wurz, D. H. Parker, M. J. Pelling, D. M. Gruen, U. Welp, W. K. Kwok, S. Fleshler, and G. W. Crabtree,Inorg. Chem. 30, 2838–2839 (1991).
H. H. Wang, A. M. Kini, B. M. Savall. K. D. Carlson, J. M. Williams, M. W. Lathrop, K. R. Lykke, D. H. Parker, P. Wurz, M. J. Pellin, D. M. Gruen, U. Welp, W. K. Kwok, S. Fleshler, G. W. Crabtree, J. Schirber, and D. L. Overmyer,Inorg. Chem. 30, 2962–2963 (1991).
D. R. Buffinger, R. P. Ziebarth, V. A. Stenger, C. H. Recchia, and C. H. Pennington,J. Am. Chem. Soc. 115, 9267 (1993).
A. Abragam,Principles of Nuclear Magnetism, (Clarendon Press, Oxford 1989).
R. Tycko, G. Dabbagh, M. J. Rosseinsky, D. W. Murphy, A. P. Ramirez, and R. M. Fleming,Phys. Rev. Lett. 68, 1912 (1992).
R. Tycko, R. C. Haddon, G. Dabbagh, S. H. Glarum, D. C. Douglass, and A. M. Mujsce,J. Phys. Chem. 95, 518 (1991).
R. Tycko, G. Dabbagh, R. M. Fleming, R. C. Haddon, A. V. Makhija, and S. M. Zahurak,Phys. Rev. Lett. 67, 1886 (1991).
R. Tycko, G. Dabbagh, M. J. Rosseinsky, D. W. Murphy, R. M. Fleming, A. P. Ramirez, and J. C. Tully,Science 253, 884 (1991).
C. S. Yannoni, R. D. Johnson, G. Meijer, D. S. Bethune, and J. R. Salem,J. Phys Chem. 95, 9 (1991).
S. E. Barrett and R. Tycko,Phys. Rev. Lett. 69, 3754 (1992).
R. M. Fleming, A. P. Ramirez, M. J. Rosseinsky, D. W. Murphy, R. C. Haddon, S. M. Zahurak, and A. V. Makhija,Nature (London) 352, 223–225 (1992).
P. W. Stephens, L. Mihaly, P. L. Lee, R. L. Whetten, S. M. Huang, R. Kaner, F. Deiderich, K. Holczer,Nature (London) 351, 611–613 (1993).
K. Yosida,Phys. Rev. 110, 769 (1958).
C. P. Slichter,Principles of Magnetic Resonance (Springer-Verlag, New York, 1989).
A fuller account of this experiment has been submitted toPhys. Rev. B Rapid Commun. V. A. Stenger, C. Recchia, J. Vance, C. H. Pennington, D. R. Buffinger, and R. P. Ziebarth (1993).
L. Degiorgi, P. Wachter, G. Gruner, S.-M. Huang, J. Wilen, and R. B. Kaner,Phys. Rev. Lett. 69, 2987–2990 (1992).
Z. Zhang, C. Chen, S. P. Kelty, H. Dai, and C. M. Lieber,Nature (London) 353, 333 (1991).
L. C. Hebel and C. P. Slichter,Phys. Rev. 113, 1504 (1959).
Leon Cooper Nobel Prize address, inTheory of Superconductivity by J. R. Schrieffer (Addison-Wesley, Reading, Massachusetts 1964).
V. A. Stenger, C. H. Recchia, J. E. Vance, C. H. Pennington, D. R. Buffinger, and R. P. Ziebarth,Phys. Rev. B 48, 9942 (1994).
W. H. Wong, M. E. Hanson, W. G. Clark, G. Gruner, J. D. Thompson, R. L. Whetten, S. M. Huang, R. B. Kaner, F. Diederich, P. Petit, J. J. Andre, and K. Holczer,Europhys. Lett. 18, 79 (1992).
R. F. Kiefl, W. A. MacFarlane, K. H. Chow, S. Dunsiger, T. L. Duty, T. M. S. Johnston, J. W. Schneider, J. Sonier, L. Brard, R. M. Strongin, J. E. Fischer, and A. B. Smith III,Phys. Rev. Lett. 70, 3987 (1993).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Stenger, V.A., Recchia, C., Pennington, C.H. et al. NMR studies of alkali C60 superconductors. J Supercond 7, 931–936 (1994). https://doi.org/10.1007/BF00732274
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00732274