Abstract
An exact analytical expression for the condensation energy \(E_{\text{cond}} \left( T \right)\) of a phonon-driven superconductor for all absolute temperatures \(T\) and for any coupling strength is introduced so as to calculate the Helmholtz free energy difference \(F_{s} \left( T \right) - F_{n} \left( T \right)\) between superconducting \(\left( s \right)\) and normal \(\left( n \right)\) states. This is achieved via a boson–fermion ternary gas theory—called the generalized Bose–Einstein condensation (GBEC) theory—which includes two-hole Cooper pairs, two-electron ones as well as single, free/unbound electrons. The GBEC formalism turns out to be quite useful in dealing with nonzero \(T\) values of \(E_{\text{cond}} \left( T \right)\) and reproduces several well-known experimental results. An expression for the condensation energy per atom is also calculated and applied to aluminum and niobium, and both results are compared with experimental data.
Similar content being viewed by others
References
V.V. Tolmachev, Phys. Lett. A 266, 400 (2000)
S.K. Adhikari, M. de Llano, F.J. Sevilla, M.A. Solís, J.J. Valencia, Physica C 453, 37 (2007)
M. Grether, M. de Llano, V.V. Tolmachev, Int. J. Quantum Chem. 112, 3018 (2012)
M. de Llano, V.V. Tolmachev, Phys. A 317, 546 (2003)
M. de Llano, V.V. Tolmachev, Ukr. J. Phys. 55, 79 (2010)
L.N. Cooper, Phys. Rev. 104, 1189 (1956)
A.P. Drozdov, M.I. Eremets, I.A. Troyan, V. Ksenofontov, S.I. Shylin, Nature 525, 73 (2015)
A.P. Drozdov, P.P. Kong, V.S. Minkov, S.P. Besedin, M.A. Kuzovnikov, S. Mozaffari, L. Balicas, F.F. Balakirev, D.E. Graf, V.B. Prakapenka, E. Greenberg, D.A. Knyazev, M. Tkacz, M.I. Eremets, Nature 569, 528 (2019)
H. Liu, I.I. Naumov, R. Hoffmann, N.W. Ashcroft, R.J. Hemley, Proc. Natl. Acad. Sci. 114, 6990 (2017)
M. Somayazulu, M. Ahart, A.K. Mishra, Z.M. Geballe, M. Baldini, Y. Meng, V.V. Struzhkin, and R.J. Hemley. arXiv: 1808.07695 [Cond Mat] (2018)
J. Bardeen, L.N. Cooper, J.R. Schrieffer, Phys. Rev. 108, 1175 (1957)
C. Kittel, Introduction to Solid State Physics (Wiley, New York, 2005)
J.F. Annett, Superconductivity, Superfluids, and Condensates (Oxford University Press, Oxford, 2004)
Y. Wada, Phys. Rev. 135, A1481 (1964)
J. Bardeen, M. Stephen, Phys. Rev. 136, A1485 (1964)
G.M. Eliashberg, Sov. Phys. JETP 11, 696 (1960)
G.M. Eliashberg, Sov. Phys. JETP 16, 780 (1963)
Y. Nambu, Phys. Rev. 117, 648 (1960)
J. Ranninger, R. Micnas, S. Robaszkiewicz, Ann. Phys. 13, 455 (1988)
R. Friedberg, T.D. Lee, Phys. Rev. B 40, 6745 (1989)
Y. Bar-Yam, Phys. Rev. B 43, 359 (1991)
R. Friedberg, T.D. Lee, H.C. Ren, Phys. Rev. B 45, 10732 (1992)
J. Ranninger, J.M. Robin, M. Eschrig, Phys. Rev. Lett. 74, 4027 (1995)
V.B. Geshkenbein, L.B. Ioffe, A.I. Larkin, Phys. Rev. B 55, 3173 (1997)
T. Domanski, J. Ranninger, Phys. Rev. B 63, 134505 (2001)
I. Chávez, M. Grether, M. de Llano, J. Supercond. Nov. Magn. 28, 309 (2015)
M. Girardeau, J. Math. Phys. 1, 516 (1960)
W.J. Mullin, A.R. Sakhel, J. Low Temp. Phys. 166, 125 (2012)
M.V.D. Berg, J.T. Lewis, J.V. Pulé, Helv. Phys. Acta 59, 1271 (1986)
V.A. Zagrebnov, J.B. Bru, Phys. Rep. 350, 291 (2001)
T.A. Mamedov, M. de Llano, J. Phys. Soc. Jpn. 79, 044706 (2010)
T.A. Mamedov, M. de Llano, J. Phys. Soc. Jpn. 80, 074718 (2011)
T.A. Mamedov, M. de Llano, Philos. Mag. 93, 2896 (2013)
T.A. Mamedov, M. de Llano, Philos. Mag. 94, 4102 (2014)
R.M. Carter, M. Casas, J.M. Getino, M. de Llano, A. Puente, H. Rubio, D.M. van der Walt, Phys. Rev. B 52, 16149 (1995)
M. Casas, J.M. Getino, M. de Llano, A. Puente, R.M. Quick, H. Rubio, D.M. van der Walt, Phys. Rev. B 50, 15945 (1994)
N.N. Bogoliubov, J. Phys. URSS 11, 23 (1947)
N.N. Bogoliubov, Il Nuovo Cim. 7, 794 (1958)
A.L. Fetter, J.D. Walecka, Quantum Theory of Many-Particle Systems (McGraw-Hill, New York, 1971)
C.P. Poole, Superconductivity (Academic Press, Amsterdam, 2007)
F.J. Blatt, Modern Physics (McGraw-Hill, New York, 1992)
V.Z. Kresin, S.A. Wolf, Rev. Mod. Phys. 81, 481 (2009)
M.L. Kulić, Phys. Rep. 338, 1 (2000)
A.P. Drozdov, V.S. Minkov, S.P. Besedin, P.P. Kong, M.A. Kuzovnikov, D.A. Knyazev, and M.I. Eremets, arXiv: 180807039 [Cond-Mat] (2018)
Acknowledgements
We thank T.A. Mamedov for bringing Ref. [14] to our attention and acknowledge the support of UNAM-DGAPA-PAPIIT (Mexico) Grant IN102417. FZ acknowledges funding from CONACYT Grant No. 358174/291001.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Ortega, J., Zúñiga, F. & de Llano, M. Condensation Energy in a Superconductor for All Temperatures. J Low Temp Phys 201, 489–499 (2020). https://doi.org/10.1007/s10909-020-02514-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10909-020-02514-2