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Herbicidal hydroxylamine derivatives

IX. Determination of the energy of the intermolecular hydrogen bond of some O-methylhydroxylamine derivatives of sym-triazines in solution from their infrared absorption spectra

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The energies of the intermolecular hydrogen bonds for five amino derivatives of sym-triazines have been obtained. The energies were calculated from the temperature dependence of the equilibrium constants determined from the change on dilution of the “peak” intensities of the stretching vibrations of free N-H groups and those participating in a hydrogen bond. It has been shown that under the action of the hydrogen bond the compounds studied form cyclic dimers in solution similar to those of the carboxylic acids.

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For part VIII, see [1].

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Tibanov, P.V., Vasil'ev, A.F. & Baskakov, Y.A. Herbicidal hydroxylamine derivatives. Chem Heterocycl Compd 4, 548–550 (1971). https://doi.org/10.1007/BF00486786

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  • DOI: https://doi.org/10.1007/BF00486786

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