Skip to main content
Log in

Processing, physico-chemical and functional properties of carob molasses and powders

  • Original Paper
  • Published:
Journal of Food Measurement and Characterization Aims and scope Submit manuscript

Abstract

Tunisian carob pods were used to produce molasses and powders, which were then analyzed for their composional and functional properties. Molasses were made from carob juice by boiling until three different concentrations (60, 70 and 80 °Brix), while powders were prepared by microwave drying of the by-product derived from carob molasses processing at three power levels (100, 300 and 600 W). Results showed that the processed carob products exhibited interesting characteristics. Carob molasses were characterized by important reducing sugars content, dark color and functional properties with high antioxidant activity and emulsifying capacity. On the other hand, carob powders were characterized by high levels of dietary fibers, brown color and water/oil retention capacity. This study provides, for the first time, a potential valorization of the carob by-product into powder and highlights some functional properties of carob products required by food industry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. M. Afif, N. Ben Fadhel, M.L. Khoudja, M. Boussaid, Genetic diversity in Tunisian Ceratonia siliqua L. (Caesalpinioideae) natural populations. Genet. Resour. Crop. Evol, 53, 1501–1511 (2006)

    Article  Google Scholar 

  2. H.R. Oziyci, N. Tetik, I. Turhan, E. Yatmaz, K. Ucgun, H. Akgul, H. Gubbuk, M. Karhan, Mineral composition of pods and seeds of wild and grafted carob (Ceratonia siliqua L.) fruits. Sci. Hort. 167, 149–152 (2014)

    Article  CAS  Google Scholar 

  3. A.K. Yousif, H.M. Alghzawi, Processing and characterization of carob powder. Food Chem. 69, 283–287 (2000)

    Article  CAS  Google Scholar 

  4. N. Bouzouita, A. Khaldi, S. Zgoulli, L. Chebil, M. Chaabouni, P. Thonart, The analysis of crude and purified locust bean gum: a comparison of samples from different carob tree populations in Tunisia. Food Chem. 101, 1508–1515 (2007)

    Article  CAS  Google Scholar 

  5. K. Dhaouadi, M. Belkhir, I. Akinocho, F. Raboudi, D. Pamies, E. Barrajón, C. Estevan, S. Fattouch, Sucrose supplementation during traditional carob syrup processing affected its chemical characteristics and biological activities. LWT-Food Sci. Technol. 57, 1–8 (2014)

    Article  CAS  Google Scholar 

  6. N. Tetik, I. Turhan, H.R. Oziyci, M. Karhan, Determination of d-pinitol in carob syrup. Int. J. Food Sci. Nutr. 62, 572–576 (2011)

    Article  CAS  Google Scholar 

  7. F.A. Ayaz, H. Torun, R.H. Glew, Z.D. Bak, L.T. Chuang, J.M. Presly, R. Andrews, Nutrient content of carob pod (Ceratonia siliqua L.) flour prepared commercially and domestically. Plant Food Hum. Nutr. 64, 286–292 (2009)

    Article  CAS  Google Scholar 

  8. R. Abi Azar, Milk protein complexation by green carob pods extract: Technological properties of obtained coagulums. PhD thesis, AgroParisTech, France (2007)

  9. H. Bozkurt, F. Göğüs, S. Eren, Non-enzymatic browning reactions in boiled grape juice and its models during storage. Food Chem. 64, 89–93 (1999)

    Article  CAS  Google Scholar 

  10. O.S. Toker, M. Doganc, N.B. Ersöz, M.T. Yilmaz, Optimization of the content of 5-hydroxymethylfurfural (HMF) formed in some molasses types: HPLC-DAD analysis to determine effect of different storage time and temperature levels. Ind. Crops Prod. 50, 137–144 (2013)

    Article  CAS  Google Scholar 

  11. M. Maskan, Production of pomegranate (Punica granatum L.) juice concentrate by various heating methods: colour degradation and kinetic. J. Food Eng. 72, 218–224 (2006)

    Article  Google Scholar 

  12. S. Benjakul, W. Visessanguan, V. Phongkanpai, M. Tanaka, Antioxidative activity of caramelisation products and their preventive effect on lipid oxidation in fish mince. Food Chem. 90, 231–239 (2005)

    Article  CAS  Google Scholar 

  13. D.V. Čepo, A. Mornar, B. Nigovi, D. Kremer, D. Radanovi, I.V. Dragojevi, Optimization of roasting conditions as an useful approach for increasing antioxidant activity of carob powder. LWT-Food Sci. Technol. 58, 578–586 (2014)

    Article  Google Scholar 

  14. M.M. Özcan, D. Arslan, H. Gökçalik, Some compositional properties and mineral contents of carob (Ceratonia siliqua) fruit, flour and syrup. Int. J. Food Sci. Nutr. 58, 652–658 (2007)

    Article  Google Scholar 

  15. AOAC, Official Methods of Analysis of AOAC Intl, 15th edn. (Association of Official Analytical Chemists, Washington, DC, 1995)

    Google Scholar 

  16. AFNOR, Produits dérivés des fruits et des légumes, détermination des sucres. (Association Française de Normalisation, Paris, 1970)

    Google Scholar 

  17. G.L. Miller, Use of dinitrosalicilic acid reagent for determination of reducing sugars. Anal. Chem. 31, 426–428 (1959)

    Article  CAS  Google Scholar 

  18. L. Prosky, N.G. Asp, T.F. Schweizer, J.W. De Vries, I. Furda, Determination of insoluble, soluble, and total dietary fibre in food products: Interlaboratory study. J. Assoc. Off. Anal. Chem. 71, 1017–1023 (1988)

    CAS  Google Scholar 

  19. V.L. Singleton, J.A. Rossi, Colorimetry of total phenolics with phosphomolybdic-phosphotungstic acid reagent. Am. J. Enol. Vitic. 16, 144–158 (1965)

    CAS  Google Scholar 

  20. A. Haddarah, A. Ismail, A. Bassal, T. Hamieh, I. Ioannou, M. Ghoul, Morphological and chemical variability of lebanese carob varieties. Eur. Sci. J 9, 353–369 (2013)

    Google Scholar 

  21. M.C. Garau, S. Simal, C. Rossello, A. Femenia, Effect of air-drying temperature on physico-chemical properties of dietary fibre and antioxidant capacity of orange (Citrus aurantium v. Canoneta) by-products. Food Chem. 104, 1014–1024 (2007)

    Article  CAS  Google Scholar 

  22. K. Yasumatsu, K. Sawada, S. Moritaka, M. Misaki, J. Toda, T. Wada, Whipping and emulsifying properties of soybean products. Agric. Biol. Chem. 36, 719–727 (1972)

    Article  Google Scholar 

  23. N. Turkmen, F. Sari, E.S. Poyrazoglu, Y.S. Velioglu, Effects of prolonged heating on antioxidant activity and colour of honey. Food Chem. 95, 653–657 (2006)

    Article  CAS  Google Scholar 

  24. F. Abbès, M.A. Bouaziz, C. Blecker, M. Masmoudi, H. Attia, S. Besbes, Date syrup: effect of hydrolytic enzymes (pectinase/cellulase) on physicochemical characteristics, sensory and functional properties. LWT-Food Sci. Technol. 44, 1827–1834 (2011)

    Article  Google Scholar 

  25. M.A. Martín-Cabrejas, Y. Aguilera, M. Pedrosa, C. Cuadrado, T. Hernández, S. Díaz, The impact of dehydration process on antinutrients and protein digestibility of some legume flours. Food Chem. 114, 1063–1068 (2009)

    Article  Google Scholar 

  26. E.I. Mejia-Meza, J.A. Yanez, N.M. Davies, B. Rasco, F. Younce, C.M. Remsberg, Improving nutritional value of dried blueberries (Vaccinium corymbosum L.) combining microwave-vacuum, hot-air drying and freeze drying technologies. Int. J. Food Eng. 4(5), 1–6 (2008)

    Article  Google Scholar 

  27. W. Qu, Z. Pan, H. Ma, Extraction modeling and activities of antioxidants from pomegranate marc. J. Food Eng. 99, 16–23 (2010)

    Article  Google Scholar 

  28. M. Papagiannopoulos, H.R. Wollseifen, A. Mellenthin, B. Haber, R. Galensa, Identification and quantification of polyphenols in carob fruits (Ceratonia siliqua L.) and derived products by HPLC-UV-ESI/MS. J. Agric. Food Chem. 52, 3784–3791 (2004)

    Article  CAS  Google Scholar 

  29. Y. Lario, E. Sendra, J. Garcia-Pérez, C. Fuentes, E. Sayas-Barbera, J. Fernandez-Lopez, J.A. Pérez-Alvarez, Preparation of high dietary fiber powder from lemon juice by-products. Innov. Food Sci. Emerg. 5, 113–117 (2004)

    Article  CAS  Google Scholar 

  30. M. Jridi, N. Souissi, M. Ben Salem, M.A. Ayadi, M. Nasri, S. Azabou, Tunisian date (Phoenix dactylifera L.) by-products: Characterization and potential effects on sensory, textural and antioxidant properties of dairy desserts. Food Chem. 188, 8–15 (2015)

    Article  CAS  Google Scholar 

  31. M. Alpaslan, M. Hayta, Rheological and sensory properties of pekmez (grape molasses)/tahin (sesame paste) blends. J. Food Eng. 54, 89–93 (2002)

    Article  Google Scholar 

  32. B.S. Wang, L.W. Chang, Z.C. Kang, H.L. Chu, H.M. Tai, M.H. Huang, Inhibitory effects of molasses on mutation and nitric oxide production. Food Chem. 126, 1102–1107 (2011)

    Article  CAS  Google Scholar 

  33. J.B. Zhang, N.N. Wu, X.Q. Yang, X.T. He, L.J. Wang, Improvement of emulsifying properties of Maillard reaction products from ß-conglycinin and dextran using controlled enzymatic hydrolysis. Food Hydrocoll. 28, 301–312 (2012)

    Article  Google Scholar 

  34. M. Maskan, F. Göğüş, Effect of sugar on the rheological properties of sunflower oil–water emulsions. J. Food Eng. 43, 173–177 (2000)

    Article  Google Scholar 

  35. Y. Li, F. Lu, C. Luo, Z. Chen, J. Mao, C. Shoemaker, F. Zhong, Functional properties of the Maillard reaction products of rice protein with sugar. Food Chem. 117, 69–74 (2009)

    Article  CAS  Google Scholar 

  36. N. Ghanem, D. Mihoubi, N. Kechaou, N. Boudhrioua Mihoubi, Microwave dehydration of three citrus peel cultivars: effect on water and oil retention capacities, color, shrinkage and total phenols content. Ind. Crops Prod. 40, 167–177 (2012)

    Article  CAS  Google Scholar 

  37. Q.M. Chen, M.R. Fu, F.L. Yue, Y.Y. Cheng, Effect of superfine grinding on physicochemical properties, antioxidant activity and phenolic content of red rice (Oryza sativa L.). Food Nutr. Sci. 6, 1277–1284 (2015)

    Article  CAS  Google Scholar 

  38. J.H. Hu, Y.Q. Chen, D.J. Ni, Effect of superfine grinding on quality and antioxidant property of fine green tea powders. LWT-Food Sci. Technol. 4, 8–12 (2012)

    Article  Google Scholar 

  39. K.X. Zhu, S. Huang, W. Peng, H.F. Qian, H.M. Zhou, Effect of ultrafine grinding on hydration and antioxidant properties of wheat bran dietary fiber. Food Res. Int. 43, 943–948 (2010)

    Article  CAS  Google Scholar 

  40. M. Elleuch, D. Bedigian, O. Roiseux, S. Besbes, C. Blecker, H. Attia, Dietary fibre and fibre-rich by-products of food processing: characterisation, technological functionality and commercial applications: a review. Food Chem. 124, 411–421 (2011)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors would like to thank Confiserie Triki-Le Moulin (CTM, Sfax, Tunisia) for the financial support. They are also very grateful to Mr. Firas Chaker for her precious help to perform some analyzes in the industry.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Leila Tounsi.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Sirine Karra and Héla Kechaou have equally contributed to this work.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tounsi, L., Karra, S., Kechaou, H. et al. Processing, physico-chemical and functional properties of carob molasses and powders. Food Measure 11, 1440–1448 (2017). https://doi.org/10.1007/s11694-017-9523-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11694-017-9523-4

Keywords

Navigation