Data are given on the cracking of vacuum gas oil with HY zeolite catalysts on aluminum pillared natural calcium montmorillonite under vigorous cracking conditions in laboratory reactors of different volumes with a fixed catalyst bed at 500-600°C. Increasing the cracking temperature and contact time of the vacuum gas oil with the catalyst was shown to increase the yield of the gas phase. The greatest gas yield was 42%. In this case, the gas contained C2 - C4 alkenes, including 28% propylene. We concluded that it should be possible to use aluminum pillared calcium montmorillonite as a component of a zeolite cracking catalyst for petrochemical processes.
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References
A. Gil, S. A. Korilli, and M. A. Vicente, Catalysis Review, 50, 153-221 (2008).
A. Gil, L. M. Gandia, and M. A. Vicente, Catalysis Review, 42, 145-212 (2000).
A. E. Eman, Journal of Science and Technology, 3, No. 4, 356-375 (2013).
M. Kurian and S. Kavitha, Journal of Applied Chemistry, 47-54 (2016).
F. Bergaya, B. K. G Theng, G Lagaly, et al., Handbook of Clay Science, Elsevier, Amsterdam (2006).
J. T. Kloprogge, L. V. Duong, and it L. Frost, Journal of Environmental Geology, 47, No. 7, 967-981 (2005).
I. Fetiman, A. Hidayart, and K. H. Setiwan, Asian Journal of Chemistry, 22, No. 5, 3793-3801 (2010).
R. P. Silvy, Applied Catalysis A, 261, 247-252 (2004).
P. Salerno, M. B. Asenjo, and S. Mendioroz, Thermochim. Acta, 379, 101-109 (2001).
L. Ma, T. Li, Qi Tao, et al., Journal of Thermal Analysis and Calorimetry, 115, No. 1, 219-225 (2014).
C. R. Reddy, J. S. Bhat, G. Nagendrappa, et al., Catalysis Today, 141, Nos. 1-2,157-160 (2009).
M. R. Sun Kou, S. Mendioroz, and V. Mihoz, Clays and Clay Minerals, 48, 528-536 (2000).
H. J. Chae, I. S. Nam, S. W. Ham, et al., Catalysis Today, 68, 31-41 (2001).
Yu. I. Tarasevich, M. V. Sychev, and R. V. Prikhod'ko, Ukrainskii Khimicheskii Zhurnal, 68, No. 10, 88-91 (2002).
V. G. Popov and V. G. Abdrakhmanov, Ion Exchange Concept in Genetic Hydrogeochemistry [in Russian], Gilem, Ufa (2013).
P. Falaras, F. Lezou, G. Seiragakis, et al., Clays and Clay Minerals, 48, 549-556 (2000).
L. V. de Paiva, A. R. Morales, R. Francisco, et al., Applied Clay Science, 42, 8-24 (2008).
N. A. Shadin, N. A. Zakarina, and L. D. Volkova, Problems in the Innovative Development of the Petroleum and Natural Gas Industry: Reports to the Seventh International Science and Applied Science Conference, Almaty, 9-11 April 2015 [in Russian], pp. 487-490.
R. L. Van Mao, S. Melancom, C. G Campbell, et al., Catalysis Letters, 73, Nos. 2-4, 181-186 (2001).
USA Patent No. 20,030,181,323.
I. M. Gerzeliev, V. M. Kapustin, B. F. Sedgkhi Rukhi, et al., Kataliz v Promyshlennosti, No. 6, 33-38 (2012).
V. Doronin, P. V. Lipin, and T. P. Sorokina, Kataliz v Promyshlennosti, No. 1, 27-32 (2012).
OCT 38.01176-79.
This work was carried out with the support of the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (Grant AP 05132064 and Targeted Program Financing BR05236739).
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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 4, pp. 20 – 24, July – August, 2018.
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Zakarina, N.A., Shadin, N.A., Volkova, L.D. et al. Cracking of Heavy Vacuum Gas Oil on Modified HY Zeolite Catalysts. Chem Technol Fuels Oils 54, 417–424 (2018). https://doi.org/10.1007/s10553-018-0942-7
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DOI: https://doi.org/10.1007/s10553-018-0942-7