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Formation of a Cluster H2V10O 4–28 under the Action of Brønsted Acids and Its Catalytic Activity in Oxidation of Alkylbenzenes

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Abstract

New method was developed for the preparation of vanadium cluster of the composition {Me2NH2}4* H2V10O28 from vanadyl(IV) acetylacetonate in the presence of 2-hydroxy-2-trifluoromethylchroman-4-one or its synthetic precursor, 2′-hydroxyacetophenone. The structure of the cluster was proved by X-ray diffraction (XRD) analysis. The cluster of decavanadate catalyzes oxidation of toluene and o-xylene creating promising situation for developing new catalytic materials.

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Authors and Affiliations

  1. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi/Academicheskaya 22/20, Yekaterinburg, 620137, Russia

    M. I. Ul’yanova, M. G. Pervova, P. A. Slepukhin & A. V. Pestov

  2. Ural Federal University named after the First President of Russia B.N. Yeltsin, Yekaterinburg, 620002, Russia

    P. A. Slepukhin, T. V. Aksenova & A. V. Pestov

Authors
  1. M. I. Ul’yanova
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  2. M. G. Pervova
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  3. P. A. Slepukhin
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  4. T. V. Aksenova
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  5. A. V. Pestov
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Corresponding author

Correspondence to A. V. Pestov.

Additional information

Original Russian Text © M.I. Ul’yanova, M.G. Pervova, P.A. Slepukhin, T.V. Aksenova, A.V. Pestov, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 5, pp. 686–689.

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Ul’yanova, M.I., Pervova, M.G., Slepukhin, P.A. et al. Formation of a Cluster H2V10O 4–28 under the Action of Brønsted Acids and Its Catalytic Activity in Oxidation of Alkylbenzenes. Russ J Org Chem 54, 687–690 (2018). https://doi.org/10.1134/S1070428018050020

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  • DOI: https://doi.org/10.1134/S1070428018050020

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