Skip to main content
SpringerLink
Log in

An unexpected and unusual V(5+)10 cluster containing oxygen bridges as well as six bidentate acetylacetonates

  • Original Research
  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

A cluster of 10 vanadium (5+) atoms bridged by 22 oxygen atoms and having six of the vanadiums around the periphery each bound to a single bidentate acetylacetone is described. This material has no unpaired electrons since V(5+) is 3do.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Bernal I, Rieger PH (1963). Inorg Chem 2:256–262

    Article  CAS  Google Scholar 

  2. CSD = Cambridge Crystallographic Structural Database CCSD, Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK, release 1.18. They can be contacted at http://www.ccdc.cam.ac.uk

  3. Ishida T, Mitsubori S, Nogami T, Takeda N, Ishikawa M, Iwamura H (2001). Inorg Chem 40:7059–7064 ADAHOC and ADAHUI

    Article  CAS  Google Scholar 

  4. Feilong J, Anderson OP, Miller SM, Chen J, Mahroof-Tahir M, Crans DC (1998). Inorg Chem 37(21):5439–5451 BAFQOO

    Article  Google Scholar 

  5. Bruker (2009) SAINT, Version 7.23a. Bruker AXS Inc., Madison

    Google Scholar 

  6. Bruker (2009) APEX 2, Version 2.0–2. Bruker AXS Inc., Madison

    Google Scholar 

  7. Sheldrick GM (2008). Acta Cryst A64:112–122

    Article  Google Scholar 

  8. Sheldrick GM (2015). Acta Cryst A71:3–8

    Google Scholar 

  9. Sheldrick GM (2015). Acta Cryst C71:3–8

    Google Scholar 

  10. Arslan E, Bernal I, Lalancette R (2017). Struct Chem 28:201–212

    Article  CAS  Google Scholar 

  11. Baranovsky IB, Surazhskaya MD, Gulubnichaya MA (2007) Zh Neorg Khim (Russ). Russ J Inorg Chem 52(12):1983–1991 VOCLIJ & VOCLOP

    Google Scholar 

  12. Zhai H, Liu S, Peng J, Hu N, Jia H (2004). J Chem Crystal 34:541–548

    Article  CAS  Google Scholar 

  13. Ferreira da Silva JL, Fátima Minas da Piedade M, Teresa Duarte M (2003). Inorg Chim Acta 356:222–242

    Article  CAS  Google Scholar 

Download references

Funding

The authors would like to acknowledge the support by NSF-CRIF Grant No. 0443538 for part of the purchase of the X-ray diffractometer.

Author information

Authors and Affiliations

  1. Department of Chemistry, Carl A. Olson Memorial Laboratories, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA

    Evrim Arslan, Roger A. Lalancette & Ivan Bernal

  2. Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, Johannesburg, ZA, 2050, South Africa

    Ivan Bernal

Authors
  1. Evrim Arslan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Roger A. Lalancette
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ivan Bernal
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Roger A. Lalancette.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Arslan, E., Lalancette, R.A. & Bernal, I. An unexpected and unusual V(5+)10 cluster containing oxygen bridges as well as six bidentate acetylacetonates. Struct Chem 31, 1217–1222 (2020). https://doi.org/10.1007/s11224-020-01521-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11224-020-01521-z

Keywords

Search

Navigation