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Synthesis of peroxides from β,δ-triketones under heterogeneous conditions

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Abstract

Heterogeneous reactions of β,δ-triketones with ethereal hydrogen peroxide in nonpolar solvents, catalyzed by phosphomolybdic acid, afforded mixtures of stereoisomeric ozonides, tricyclic monoperoxides, and bridged tetraoxanes. The trioxolane ring is formed by the carbonyl groups located in the δ-position with respect to each other.

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Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia

    A. O. Terent’ev & I. A. Yaremenko

  2. All-Russia Research Institute of Phytopathology, Bol’shie Vyazemy, Moscow oblast, 143050, Russia

    A. P. Glinushkin & G. I. Nikishin

Authors
  1. A. O. Terent’ev
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  2. I. A. Yaremenko
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  3. A. P. Glinushkin
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  4. G. I. Nikishin
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Corresponding author

Correspondence to A. O. Terent’ev.

Additional information

Original Russian Text © A.O. Terent’ev, I.A. Yaremenko, A.P. Glinushkin, G.I. Nikishin, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 12, pp. 1716–1722.

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Terent’ev, A.O., Yaremenko, I.A., Glinushkin, A.P. et al. Synthesis of peroxides from β,δ-triketones under heterogeneous conditions. Russ J Org Chem 51, 1681–1687 (2015). https://doi.org/10.1134/S1070428015120027

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  • DOI: https://doi.org/10.1134/S1070428015120027

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