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Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

α-Hydroxyalkyl peroxide esters and ethers containing, along with the peroxy bond, also acyloxy and alkoxy groups, are effective initiators of radical processes. The initiation efficiency is due to the capability of these molecules to generate simultaneously oxygen- and carbon-centered radicals capable of hydrogen abstraction from the substrate and of addition to 〉C=C〈 bonds. The selectivity of the synthesis of α-hydroxyalkyl peroxide esters and ethers is mainly determined by the steps of the synthesis and isolation of the intermediate α-chloroalkyl peroxides, because of their high reactivity. Experimental conditions allowing control of the synthesis of α-hydroxyalkyl peroxide esters and ethers were found.

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Authors and Affiliations

  1. Volgograd State Technical University, pr. Lenina 28, Volgograd, 400131, Russia

    T. P. Aleinikova & V. A. Navrotskii

Authors
  1. T. P. Aleinikova
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  2. V. A. Navrotskii
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Correspondence to T. P. Aleinikova.

Additional information

Original Russian Text © T.P. Aleinikova, V.A. Navrotskii, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 12, pp. 1816–1827.

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Aleinikova, T.P., Navrotskii, V.A. Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes. Russ J Appl Chem 87, 1890–1900 (2014). https://doi.org/10.1134/S1070427214120167

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  • DOI: https://doi.org/10.1134/S1070427214120167

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