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Synthesis and Crystal and Molecular Structures of 1,3-Di-p-tolyl-5-(5'-allyl 2'-ethoxybenzyl)-1,3,5-diazaphosphacyclohexane Complexes with Ni(II) and Pt(II) Salts

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An Erratum to this article was published on 31 August 2022

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Abstract

The reaction of heterocyclic phosphine ligand, 1,3-di-p-tolyl-5-(5'-allyl-2'-ethoxybenzyl)-1,3-diaza-5-diazaphosphacyclohexane (L), containing a functional substituent at phosphorus, with (1,5-cyclooctadiene)dichloroplatinum(II) and nickel(II) chloride gave complexes PtCl2L2 (I) and NiCl2L2 (II), respectively, with the cis- and trans-configurations of the central ion. The structure of the complexes was determined by X-ray diffraction (CIF files CCDC no. 2097704 (I), 2097705 (II)).

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ACKNOWLEGEMENTS

The authors are grateful to the Spectral Analytical Center for Collective Use of the Federal Research Center “Kazan Scientific Center,” Russian Academy of Sciences, for the equipment provided for investigations.

Funding

This study was supported by the Russian Foundation for Basic Research (project no. 00-03-40133).

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center,” Russian Academy of Sciences, Kazan, Russia

    A. S. Balueva, E. I. Musina, F. Z. Baimukhametov, G. N. Nikonov, A. T. Gubaidullin, I. A. Litvinov & A. A. Karasik

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  1. A. S. Balueva
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  2. E. I. Musina
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  3. F. Z. Baimukhametov
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  4. G. N. Nikonov
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  5. A. T. Gubaidullin
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  6. I. A. Litvinov
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  7. A. A. Karasik
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Correspondence to A. S. Balueva.

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Translated by Z. Svitanko

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Balueva, A.S., Musina, E.I., Baimukhametov, F.Z. et al. Synthesis and Crystal and Molecular Structures of 1,3-Di-p-tolyl-5-(5'-allyl 2'-ethoxybenzyl)-1,3,5-diazaphosphacyclohexane Complexes with Ni(II) and Pt(II) Salts. Russ J Coord Chem 48, 189–194 (2022). https://doi.org/10.1134/S1070328422030010

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  • DOI: https://doi.org/10.1134/S1070328422030010

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