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Dichlorotriethylphosphine-[N-formyl-N,N′-bis(3,4-dimethoxy)benzyl-trimethylenediamine] platinum(II)

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Abstract

By treatment of 1,3-bis(3,4-dimethoxybenzyl)-3,4,5,6-tetrahydropyrimidinium chloride (1) with KOBut and [PtCl2(PEt3)2]2 N-coordinated platinum complex (2) is obtained. The Pt atom is coordinated in square planar arrangements by two chloride ions in a trans-configuration, the N-formyl-N,N′-bisaryltrimethylenediamine nitrogen atom, and the phosphine P atom. An extensive three-dimensional network of three C-H…O hydrogen bonds, two C-H…π and one π…π interactions are responsible for the crystal stabilization. Intermolecular hydrogen bonds and C-H…π interactions produce R 22 (6), R 22 (22), R 22 (24), R 33 (23), R 44 (26), and R 44 (32) rings.

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Authors and Affiliations

  1. Scientific and Technological Research Application and Research Center, Sinop University, Sinop, Turkey

    O. Şahin

  2. Department of Chemistyr, İnönü University, Malatya, Turkey

    E. Ö. Özcan, N. Gürbüz & İ. Özdemir

  3. Department of Physics, Ondokuz Mayıs University, Samsun, Turkey

    O. Büyükgüngör

Authors
  1. O. Şahin
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  2. E. Ö. Özcan
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  3. N. Gürbüz
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  4. İ. Özdemir
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  5. O. Büyükgüngör
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Correspondence to O. Şahin.

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Original Russian Text © 2014 O. Şahin, E. Ö. Özcan, N. Gürbüz, İ. Özdemir, O. Büyükgüngör.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 4, pp. 731–736, July–August, 2014.

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Şahin, O., Özcan, E.Ö., Gürbüz, N. et al. Dichlorotriethylphosphine-[N-formyl-N,N′-bis(3,4-dimethoxy)benzyl-trimethylenediamine] platinum(II). J Struct Chem 55, 697–702 (2014). https://doi.org/10.1134/S0022476614040155

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  • DOI: https://doi.org/10.1134/S0022476614040155

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