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Isomerism in metal complexes of 1,3,5-diazaphosphorinanes. Synthesis, crystal and molecular structure of conformers ofcis-bis(1,3,5-triphenyl-1,3,5-triazaphosphorinane)dichloroplatinum(II)

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Abstract

The crystal and molecular structures were determined for two individual conformers ofcis-bis(1,3,5-triphenyl-1,3,5-diazaphosphorinane)dichloroplatinum(II) differing in the rotation of the heterocyclic ligand planes around the P-Pt bond and in the orientation of the substituents at the phosphorus atoms in the ligands.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083, Kazan', Russian Federation

    A. A. Karasik, S. V. Bobrov, G. N. Nikonov, I. A. Litvinov, V. A. Naumov & A. G. Akhmadullin

Authors
  1. A. A. Karasik
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  2. S. V. Bobrov
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  3. G. N. Nikonov
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  4. I. A. Litvinov
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  5. V. A. Naumov
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  6. A. G. Akhmadullin
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1650–1655, September, 1993.

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Karasik, A.A., Bobrov, S.V., Nikonov, G.N. et al. Isomerism in metal complexes of 1,3,5-diazaphosphorinanes. Synthesis, crystal and molecular structure of conformers ofcis-bis(1,3,5-triphenyl-1,3,5-triazaphosphorinane)dichloroplatinum(II). Russ Chem Bull 42, 1587–1592 (1993). https://doi.org/10.1007/BF00699202

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  • DOI: https://doi.org/10.1007/BF00699202

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