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Synthesis and Structure of Platinum Complexes with Organyltriphenylphosphonium Chlorides and DMSO

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Abstract

Complexes [Ph3PCH2C(O)Me][PtCl3(DMSO-S)] and [Ph3PCH2CH=CH2][PtCl3(DMSO-S)] were synthesized by the reaction of organyltriphenylphosphonium chloride with potassium tetrachloroplatinate (2 : 1) in dimethyl sulfoxide. The reaction of but-2-enylbis(triphenylphosphonim) dichloride with potassium hexachloroplatinate or hexachloroplatinic acid leads to the formation of the complex [Ph3PCH2CH=CHCH2PPh3][PtCl5(DMSO-S)]2. Phosphorus atoms in the cations of the synthesized complexes have a tetrahedral surrounding, and the anions [PtCl5(DMSO-S)]− are square in shape.

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References

  1. Cotton, F.A. and Francis, R., J. Am. Chem. Soc., 1960, vol. 82, p. 2986. doi 10.1021/ja01497a003

    Article  CAS  Google Scholar 

  2. Meek D.W., Straub D.K., and Drago R.S., J. Am. Chem. Soc., 1960, vol. 82, p. 6013. doi 10.1021/ja01508a012

    Article  CAS  Google Scholar 

  3. Kukushkin, Yu.N., Koord. Khim., 1997, vol. 23, no. 3, p.163.

    Google Scholar 

  4. Kukushkin, Yu.N., Khimiya koordinatsionnykh soedinennii (Chemistry of Coordination Compounds), Moscow: Vysshaya Shkola, 1985.

    Google Scholar 

  5. Kukushkin, Yu.N. and Pan’kov, E.Yu., Zh. Obshch. Khim., 1987, vol. 57, no. 10 p. 2691.

    Google Scholar 

  6. Sotman, S.S., Fundamenskii, V.S., Kukushkin, V.Yu., and Pan’kova, E.Yu., Zh. Obshch. Khim., 1988, vol. 58, no. 10, p. 2297.

    CAS  Google Scholar 

  7. Sharutin, V.V., Senchurin, V.S., Sharutina, O.K., and Gushchin, A.V., Russ. J. Inorg. Chem., 2013, vol. 58, no. 1, p. 33. doi 10.1134/S0036023613010191

    Article  CAS  Google Scholar 

  8. Sharutin, V.V., Senchurin, V.S., Sharutina, O.K., Somov, N.V., and Gushchin, A.V., Russ. J. Coord. Chem., 2011, vol. 37, no. 11, p. 854. doi 10.1134/S1070328411100113

    Article  CAS  Google Scholar 

  9. Sharutin, V.V., Sharutina, O.K., and Senchurin, V.S., Russ. J. Gen. Chem., 2016, vol. 86, no. 9, p. 1536. doi 10.1134/S1070363216090206

    Google Scholar 

  10. Sharutin, V.V., Senchurin, V.S., and Mosunova, T.V., Vestnik YuUrGU, Ser. Khim., 2017, vol. 9, no. 4, p. 61. doi 10.14529/chem170410

    Google Scholar 

  11. Batsanov, S.S., Zh. Neorg. Khim., 1991, vol. 36, no. 12, p. 3015.

    CAS  Google Scholar 

  12. Thomas, R., Shoemaker, C.B., and Eriks, K., Acta Cryst., 1966, vol. 21, no. 1, p. 12. doi 10.1107/S0365110X66002263

    Article  CAS  Google Scholar 

  13. Calligaris, M. and Carugo, O., Coord. Chem. Rev., 1996, vol. 153, p. 83. doi 10.1016/0010-8545(95)01193-5

    Article  CAS  Google Scholar 

  14. Calligaris, M., Croat. Chem. Acta, 1999, vol. 72, nos. 2–3, p.147.

    CAS  Google Scholar 

  15. Calligaris, M., Coord. Chem. Rev., 2004, vol. 248, nos. 3–4, p. 351. doi 10.1016/j.ccr.2004.02.005

    Article  CAS  Google Scholar 

  16. SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System. Bruker AXS Inc. 1998. Madison, Wisconsin, USA.

  17. SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures From Diffraction Data. Bruker AXS Inc. 1998. Madison, Wisconsin, USA.

  18. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Cryst., 2009, vol. 42, p. 339. doi 10.1107/S0021889808042726

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. State Educational Institution South Ural Research University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina, V. S. Senchurin & A. R. Tkacheva

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. V. S. Senchurin
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  4. A. R. Tkacheva
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, V.S. Senchurin, A.R. Tkacheva, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 7, pp. 1165–1170.

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Sharutin, V.V., Sharutina, O.K., Senchurin, V.S. et al. Synthesis and Structure of Platinum Complexes with Organyltriphenylphosphonium Chlorides and DMSO. Russ J Gen Chem 88, 1456–1461 (2018). https://doi.org/10.1134/S1070363218070174

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  • DOI: https://doi.org/10.1134/S1070363218070174

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