Abstract
A composite material based on magnetite and K2[CoFe(CN)6] was prepared. Structural and morphological studies of the sorbent were carried out, and the specific surface area was determined. The crystal structure of the material was studied by X-ray diffraction, and the composition was evaluated by energy-dispersive X-ray spectroscopy. Sorption of radionuclides was studied in batch experiments in relation to pH of the solution, mass of the adsorbent, and contact time. The adsorption kinetics was examined, the adsorption isotherm was constructed, and the adsorption capacity was determined. The resistance of the material to radiation to a dose of 250 kGy was evaluated. The material efficiently removes Cs and Am radionuclides from aqueous solutions. The sorbent seems to be sufficiently stable for practical use in the treatment of radioactive waste.
Similar content being viewed by others
References
Braun, T. and Ghersini, G., Extraction Chromatography, Vol. 2 of Journal of Chromatography Library, Amsterdam: Elsevier, 1975.
Amphlett, C.B., Inorganic Ion Exchangers, Monograph 2 of Topics in Inorganic and General Chemistry, Amsterdam: Elsevier, 1964.
Ion Exchange and Solvent Extraction, Sengupta, A.K., Moyer, B.A., Marinsky, J.A., and Marcus, Y., Eds., CRC, 1993–2017, vols. 11–23.
Kadirvelu, K. and Goel, J., in Ion Exchange and Inorganic Adsorption, Physics and Chemistry of Water, ch. 9 of Water Encyclopedia, Wiley, 2005, pp. 1999–2014.
Streat, M. and Jacobi, D.L., Ion Exchange Technology: Advances in Pollution Control, Lancaster: Technomic, 1995.
Kubica, B., Nukleonika, 2010, vol. 155, pp. 163–168.
Kubica, B., Tuteja-Krysa, M., Misiak, R., et al., J. Radioanal. Nuclear Chem., 2003, vol. 258, pp. 167–170.
Narbutt, J., Siwiniski, J., Bartos, B., and Bilewicz, A., J. Radioanal. Nucl. Chem., 1986, vol. 101, pp. 41–49.
Loos-Neskovic, C., Dierkes, M.H., Jackwerth, E., et al., Hydrometallurgy, 1993, vol. 32, pp. 345–363.
Loos-Neskovic, C. and Pedoroff, M., Solvent Extr. Ion Exch., 1987, vol. 5, pp. 757–780.
Szeglowski, Z., Constantinescu, O., and Hussonnois, M., IPNO-DRE Report 92-11, Orsay, 1992.
Vincent, T., Vincent, C., and Guibal, E., Molecules, 2015, vol. 20, pp. 20 582–20613.
Bilewicz, A. and Narbutt, J., Isotopenpraxis, 1984, vol. 20, pp. 141–142.
Bartos, B., Filipowicz, B., Lyczko, M., and Bilewicz, A., J. Radioanal. Nucl. Chem., 2014, vol. 302, no. 1, pp. 513–516.
Zhao, L., Dudek, J., Polkowska-Motrenko, H., and Chmielewski, A.G., Radiochim. Acta, 2016, vol. 104, pp. 423–433.
Basualto, C., Gaete, J., Molina, L., et al., Sci. Technol. Adv. Mater., 2015, vol. 16, no. 3, paper 035 010.
Mirabi, A., Dalirandeh, Z., and Rad, A.S., J. Magnet. Magnet. Mater., 2015, vol. 381, pp. 138–144.
Sadeghi, S., Azhdari, H., Arabi, H., and Moghaddam, A.Z., J. Hazard. Mater., 2012, vols. 215–216, pp. 208–216.
Das, S., Pandey, A.K., Athawale, A.A., et al., J. Hazard. Mater., 2011, vol. 186, pp. 2051–2059.
Suleiman, J.S., Hu, B., Peng, H., and Huang, C., Talanta, 2009, vol. 77, pp. 1579–1583.
Huang, S.-H. and Chen, D.-H., J. Hazard. Mater., 2009, vol. 163, pp. 174–179.
Grayson, M., Kirk–Othmer Encyclopedia of Chemical Technology, New York: Wiley, 1981, 3rd ed., p. 775.
Cao, X., Zhang, B., Zhao, F., and Feng, L., J. Nanomater., 2012, article ID 607296, doi:10.1155/2012/607296.
Petcharoen, K. and Sirivat, A., Mater. Sci. Eng. B: Solid-State Mater. Adv. Technol., 2012, vol. 177, pp. 421–427.
Zhu, B., Ma, N., Wu, D., et al., Ind. Eng. Chem. Res., 2011, vol. 50, pp. 11 698–11705.
https://doi.org/www.alibaba.com/showroom/carbonyl-iron-powder.html, accessed June 15, 2014.
Rykov, A.I., Wang, J., Zhang, T., and Nomura, K., Hyperfine Interact., 2013, vol. 218, pp. 53–58.
Sadlej-Sosnowska, N., Ocios, A., and Fuks, L., J. Mol. Struct., 2006, vols. 792–793, pp. 110–114.
Shannon, R.D., Acta Crystallogr., Sect. A, 1976, vol. 32, pp. 751–767.
Born, M., Z. Phys., 1920, vol. 1, pp. 45–48.
Dulama, M., Deneanu, N., Pavelescu, M., and Pasăre, L., Rom. J. Phys., 2009, vol. 54, pp. 851–859.
Guidelines for Drinking-Water Quality, Incorporating First Addendum, vol. 1: Recommendations, World Health Organization, 2006, 3rd ed.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Radiokhimiya, 2018, Vol. 60, No. 4, pp. 344–350.
The text was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Fuks, L., Wawszczak, D., Smolinski, T. et al. Novel Magnetic Cobalt Cyanoferrate Nanoparticles as Potential Sorbent for Solid-Phase Extraction of Radionuclides from Aqueous Samples. Radiochemistry 60, 400–408 (2018). https://doi.org/10.1134/S1066362218040094
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1066362218040094