Abstract
Recent work directed towards synthesizing and exploring new effective sorbents for radiocesium removal from primary coolants of pressurized water nuclear reactors of the WWER type is presented. Various sorbents synthesized on the basis of titanium hexacyanoferrate are compared with one another from the point of view of their sorption efficiency and stability. The uptake of137Cs from solutions containing boric acid and millimolar quantities of ammonium and potassium ions was studied under conditions simulating the process of purification of the coolant bled from the primary circuit of the reactor. A composite-type sorbent was selected of good mechanical properties and negligible solubility, efficiently decontamining large amounts of the solution (considerably exceeding 104 bed volumes) in the course of the column process.
Similar content being viewed by others
References
J. NARBUTT, A. BILEWICZ, E. GNIAZDOWSKA-LAREN, IAEA-SM-264/31 in Water Chemistry and Corrosion Problems in Nuclear Power Plants, IAEA, Vienna, 1983, p. 287.
P. O. ANDERSSON, NPP Ringhals (Sweden), personal information, 1982.
I. L. RYBALCHENKO, IAEA-SM-264/41, see Reference 1,, p. 241.
I. M. PLOTNIKOV et al. Desyatiletni Opyt Ekspluatatsii Novovoronezhskoj AES, Novovoronezh, 1974, p. 133.
V. KOURIM, O. VOJTECH, At. Energ. Rev., 12 (1974) 215.
J. NARBUTT, A. BILEWICZ, E. GNIAZDOWSKA, Polish Patent Appl. P-255190 1985.
Z. SZEGLOWSKI, T. BIELECKI, to be published.
J. NARBUTT, B. BARTOŚ, A. BILEWICZ, Z. SZEGLOWSKI, Polish Patent Appl., P-255191, 1985.
A. DEPTUŁA, B. BARTOŚ, A. MATYJEK, Nukleonika (Warsaw), in press.
A. BILEWICZ, J. NARBUTT, Isotopenpraxis, 20 (1984) 141.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Narbutt, J., Siwiński, J., Bartoś, B. et al. Studies on new titanium hexacyanoferrate sorbents for radiocesium removal from primary coolant of pressurized water reactors. Journal of Radioanalytical and Nuclear Chemistry, Articles 101, 41–49 (1986). https://doi.org/10.1007/BF02039391
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02039391