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Delignification of Wood of Populus tremula by Treatment with Ozone

  • BIOPHYSICAL CHEMISTRY
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Abstract

Lignocellulose materials (LCMs) obtained after treatment of aspen (Populus tremula) wood with ozone were studied by diffuse reflectance UV spectroscopy, Raman spectroscopy, and fluorescence spectroscopy. The destruction of lignin (LG) proved most effective in the range of specific ozone consumptions of ≤1.5 mmol/g at ≥50% conversion of ozone. The destruction of syringyl and stilbene structures and other systems of conjugated double bonds of LG with ozone was highly efficient. Delignification of LCMs was accompanied by a multiple increase in the intensity of fluorescence (FL). The FL intensity was correlated with the fraction of LG destroyed by ozone. It was shown that wood treatment with ozone makes it possible to vary the luminescence spectral characteristics of LCMs, and fluorescence spectroscopy can be considered to be one of the most sensitive methods for monitoring the ozonolytic delignification of wood.

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Funding

This study was performed using the equipment of the Nanochemistry and Nanomaterials Multiaccess Center at the Faculty of Chemistry, Moscow State University, and financially supported by the Ministry of Education and S-cience of the Russian Federation within the framework of the state-budget-supported topic “Physical chemistry of   the surface. Adsorption and catalysis” АААА-А21-121011990019-4 (Ozonolytic Delignification of LCMs: UV and Raman Spectroscopy) and also using the equipment of the Arctic Multiaccess Center of the Northern (Arctic) Federal University under the government contract (project no. 121112300066-3 (Study of the Luminescence Characteristics of Wood)).

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119992, Moscow, Russia

    N. A. Mamleeva & A. N. Kharlanov

  2. Northern (Arctic) Federal University, 163002, Arkhangelsk, Russia

    M. V. Kuznetsova & D. S. Kosyakov

Authors
  1. N. A. Mamleeva
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  2. A. N. Kharlanov
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  3. M. V. Kuznetsova
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  4. D. S. Kosyakov
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Correspondence to N. A. Mamleeva.

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Translated by L. Smolina

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Mamleeva, N.A., Kharlanov, A.N., Kuznetsova, M.V. et al. Delignification of Wood of Populus tremula by Treatment with Ozone. Russ. J. Phys. Chem. 96, 2043–2052 (2022). https://doi.org/10.1134/S0036024422090229

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