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Physicochemical Properties of Lignocellulosic Materials from Ozonized Wood

  • BIOPHYSICAL CHEMISTRY AND PHYSICAL AND CHEMICAL BIOLOGY
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Abstract

Lignocellulosic materials (LCMs) obtained after an ozone treatment of pine wood are studied via diffuse reflectance ultraviolet (DRUV) spectroscopy, Raman spectroscopy, and fluorescence spectroscopy. The Raman spectra show that ozonation degrades lignin and hemicelluloses and lowers the content of amorphous cellulose. The Raman spectra of ozonized LCMs are deconvoluted to individual components for the first time. Based on results from analyzing the Raman and DRUV spectra, it is concluded that the aromatic structures of biomass with conjugated –С=С– and >С=О bonds simply degrade, while delignification with ozone is accompanied by a multiple increase in the fluorescence of the LCMs. It is shown that the luminescence spectral characteristics of LCMs are governed by the absorption of ozone, allowing us to identify the ranges of ozone consumption corresponding to the dominant degradation of lignin and polysaccharides in the biomaterial.

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ACKNOWLEDGMENTS

The authors thank Prof. N.G. Bazarnova (Altai State University) for providing our samples of wood.

Funding

This work was performed on equipment at the shared resource center “Nanochemistry and Nanomaterials” of Moscow State University’s Faculty of Chemistry. It was supported by the RF Ministry of Education and Science as part of State Task no. AAA-A21-121011990019-4 “Physical Chemistry of Surfaces, Adsorption, and Catalysis” (ozonolytic delignification of the LCMs, UV and Raman spectro-scopy); and by the shared resource center “Arktika” of Northern (Arctic) Federal University as part of State Task no. FSRU-2021-0009 “Studying the Luminescence Characteristics of Wood Components.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119992, Moscow, Russia

    N. A. Mamleeva & A. N. Kharlanov

  2. Northern (Arctic) Federal University, 163002, Arkhangelsk, Russia

    M. V. Kuznetsova & D. S. Kosyakov

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  1. N. A. Mamleeva
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  2. A. N. Kharlanov
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  3. M. V. Kuznetsova
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  4. D. S. Kosyakov
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Correspondence to N. A. Mamleeva.

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Translated by M. Timoshinina

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Mamleeva, N.A., Kharlanov, A.N., Kuznetsova, M.V. et al. Physicochemical Properties of Lignocellulosic Materials from Ozonized Wood. Russ. J. Phys. Chem. 97, 790–800 (2023). https://doi.org/10.1134/S0036024423040210

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  • DOI: https://doi.org/10.1134/S0036024423040210

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