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Main Pathways of the Transformations of Lignocellulosic Material under the Action of Ozone

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

Lignocellulose materials (LMCs) treated with ozone and different amounts of water are studied via Raman spectroscopy, thermal analysis (TA), and scanning electron microscopy (SEM). It is shown that the lignin and hemicelluloses (HCs) in pine wood are destroyed under the effect of ozone. SEM visualization of the porous structure of wood testifies to the destruction of cellulose during ozonation. It is noted that the content of water in wood helps regulate the contribution from reactions that occur on the internal surfaces of pores and result mainly in the destruction of lignin and HCs, along with the modification of lignin and the destruction of cellulose on the external surfaces of LCMs during free radical reactions.

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ACKNOWLEDGMENTS

This work was performed on equipment at the Nanochemistry and Nanomaterials shared resource center of Moscow State University’s Faculty of Chemistry and instrumentation of the Core Facility Centre “Arktika” of Northern (Arctic) Federal University.

Funding

This work was supported by the RF Ministry of Higher Education and Science as part of State Task no. AAAA-A21-121011990019-4, “Surface Physicochemistry, Adsorption, and Catalysis.”

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    N. A. Mamleeva, A. N. Kharlanov & S. Yu. Kupreenko

  2. Northern (Arctic) Federal University, 163001, Arkhangelsk, Russia

    D. G. Chukhchin

Authors
  1. N. A. Mamleeva
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  2. A. N. Kharlanov
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  3. S. Yu. Kupreenko
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  4. D. G. Chukhchin
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Correspondence to N. A. Mamleeva.

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Mamleeva, N.A., Kharlanov, A.N., Kupreenko, S.Y. et al. Main Pathways of the Transformations of Lignocellulosic Material under the Action of Ozone. Russ. J. Phys. Chem. 95, 2214–2221 (2021). https://doi.org/10.1134/S0036024421110133

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  • DOI: https://doi.org/10.1134/S0036024421110133

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